Phosphates iron phosphate precipitation

Use of Iron from Fe3+ Phosphate. Iron phosphate precipitate was used by iron-efficient soybeans when Fe3+ was reduced to Fe2+ (19). The Fe2+ was detected in solution as Fe2+ ferrozine [Fe2+3-(2-pyridyl)-5,6-bis(4-phenylsulfonic acid)-1,2,4, trizine]. The iron-inefficient soybeans developed iron chlorosis because they did not reduce Fe3+ to Fe2+, and they could not use the iron from Fe3+ phosphate. 

Anticorrosive paints containing pigments with either chemical or electrochemical action may induce formation of protective coatings at the metal-paint interlayer (Etz-rodt, 1993). These protective coating may be metal-substituted iron oxides iron phosphate precipitates or even a green rust - Fe Fe" 0HigC03 4H2O (Chemical Week, 1988). 

Konhauser, K.O., Fyfe, W.S., Schultze-Lam, S., Ferris, F.G. Beveridge, T.J. (1994) Iron phosphate precipitation by epilithic microbial biofilms in Arctic Canada. Canadian Journal of Earth Science 31, 1320-1324. 

Hydrogenis prevented from forming a passivating layer on the surface by an oxidant additive which also oxidizes ferrous iron to ferric iron. Ferric phosphate then precipitates as sludge away from the metal surface. Depending on bath parameters, tertiary iron phosphate may also deposit and ferrous iron can be incorporated into the crystal lattice. When other metals are included in the bath, these are also incorporated at distinct levels to generate species that can be written as Zn2Me(P0 2> where Me can represent Ni, Mn, Ca, Mg, or Fe. 

Tricalcium phosphate, Ca2(P0 2> is formed under high temperatures and is unstable toward reaction with moisture below 100°C. The high temperature mineral whidockite [64418-26-4] although often described as P-tricalcium phosphate, is not pure. Whidockite contains small amounts of iron and magnesium. Commercial tricalcium phosphate prepared by the reaction of phosphoric acid and a hydrated lime slurry consists of amorphous or poody crystalline basic calcium phosphates close to the hydroxyapatite composition and has a Ca/P ratio of approximately 3 2. Because this mole ratio can vary widely (1.3—2.0), free lime, calcium hydroxide, and dicalcium phosphate may be present in variable proportion. The highly insoluble basic calcium phosphates precipitate as fine particles, mosdy less than a few micrometers in diameter. The surface area of precipitated hydroxyapatite is approximately... 

If deposits are minimized, the areas where caustic can be concentrated is reduced. To minimize the iron deposition in 6.895-12.07 x 10 Pa boilers, specific polymers have been designed to disperse the iron and keep it in the bulk water. As with phosphate precipitation and chelant control programs, the use of these polymers with coordinated phosphate—pH treatment improves deposit control. 

Beryllium is sometimes precipitated together with aluminium hydroxide, which it resembles in many respects. Separation from aluminium (and also from iron) may be effected by means of oxine. An acetic (ethanoic) acid solution containing ammonium acetate is used the aluminium and iron are precipitated as oxinates, and the beryllium in the filtrate is then precipitated with ammonia solution. Phosphate must be absent in the initial precipitation of beryllium and aluminium hydroxides. 

Localized pre-boiler scale and corrosion debris deposits. Combination of New phosphate, iron, copper, and silica deposition Old re-deposited debris Transport of Fe, Cu, Ni, Zn, Cr oxides to HP boiler section, leading to deposition, fouling, and possible tube failures Transport of minerals and debris including malachite, ammonium carbamate, basic ferric ammonium carbonate Precipitation in FW line of phosphates, iron, and silicates... 

In addition to straightforward precipitation reactions, components may dissolve and react with components already present, including atoms on colloidal surfaces. For example, phosphate may dissolve from phosphate rock and react with iron present in the soil solution or on particle surfaces to form an iron phosphate that is insoluble. 

Magnetic separation (after precipitation as iron phosphate or after adsorption to magnetite)... 

How could one distinguish between phosphate binding (ligand exchange) to a hydrous oxide surface and the precipitation of iron phosphate ... 

Bodies of Water and the Chemical Sediments ,— The chemistry of the deposition of salts from sea-water has already been made the subject of special research, and van t Hoff s results in this field are already familiar. The deposition of calcium carbonate awaits a similar thorough study. Allied questions are the formation of dolomite, the deposition of various salts from inclosed bodies of water, the deposition of phosphate rocks, the precipitation of colloidal suspensions of clay and other substances, and the origin of the great deposits of sedimentary iron ore. 

Iron. Excess iron in wines causes cloudiness, interferes with the color, and can impair flavor. The mechanism of ferric phosphate precipitation has been intensively studied, and numerous colorimetric methods have been developed. For routine purposes the color developed with thiocyanate is adequate (6,9), but many enologists prefer the orthophenanthro-line procedures (3, 4, 6, 22). Meredith et al. (Ill) obtained essentially the same results for iron using 2,4,6-tripyridyl-s-triazine (TPTZ) to develop the color. Atomic absorption spectrophotometry can be used but, as with copper, corrections for reducing sugar and ethanol are necessary (51). 

A Cameron-Plint friction machine generated tribofilms with two-layer structure a zinc polyphosphate thermal film overlying a mixed short-chain phosphate glass, containing iron sulfide precipitates. A tribochemical reaction between the zinc polyphosphate and the iron oxides species is proposed on the basis of the hard and soft acid and base HSAB principle (Martin, 1999 Martin et al., 2001). 

If the colour cannot be seen because of the presence of a precipitate or of coloured ions, filter a small portion of the mixture and test the filtrate with dilute ammonia solution as in note 1. A large excess of FeCl3 solution must be avoided since it exerts a solvent action on iron(III) phosphate and the precipitate of the latter will be incomplete. 

Pyrite formation (FeS2) is related to biologically mediated reduction of sulfate to sulfide and of Fe3+ to Fe2+ in anoxic zones. In the case of phosphate, this can be removed through precipitation reactions with Ca2+ and Fe3+ (by formation of apatite or iron phosphate, respectively), by co-precipitation, or by formation of surface complexes with Fe or Mn oxides or hydroxides. 

Phosphates can be precipitated out by forming their insoluble Al(III), Fe(III), or Ca(II) salts with alum, iron salts, and lime, respectively, as shown in equations 10.45a-c. 

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