Particulate analyzer

Equipment Climet Cl 1000 particulate analyzer Climet CI1020 batch sampler... 

Consequently, raw output from a particulate analyzer in the form of Figure 6, even when the abscissa has been calibrated, is not necessarily an accurate representation of the particulate concentration distributions. 

From Equation 2 it is apparent that there are two calibrations necessary for any particulate analyzer. First, the instrument must be calibrated to correctly determine the diameter of any particle "seen by the analyzer in order to find f d). Secondly, the dependence of the volumetric sampling rate on particle diameter must be known in order... 

Application of an Optical Exhaust Gas Particulate Analyzer, Laborato-riet for Energiteknik Report RE 76-4, Technical University of Denmark, 1976. 

The speciation scheme of Batley and Florence requires eight measurements on four samples. After removing insoluble particulates by filtration, the solution is analyzed for the concentration of anodic stripping voltammetry (ASV) labile metal and the total concentration of metal. A portion of the filtered solution is passed through an ion-exchange column, and the concentrations of ASV metal and total metal are determined. A second portion of the filtered solution is irradiated with UV light, and the concentrations of ASV metal... 

The instrumental analyzer procedure, EPA Method 3A, is commonly used for the determination of oxygen and carbon dioxide concentrations in emissions from stationary sources. An integrated continuous gas sample is extracted from the test location and a portion of the sample is conveyed to one or more instrumental analyzers for determination of O9 and CO9 gas concentrations (see Fig. 25-30). The sample gas is conditioned prior to introduction to the gas analyzer by removing particulate matter and moisture. Sampling is conducted at a constant rate for the entire test run. Performance specifications and test procedures are provided in the method to ensure reliable data. 

Air emissions at point of discharge should be monitored continuously for fluorides and particulates and aimually for ammonia and nitrogen oxides. Monitoring data should be analyzed and reviewed at regular intervals and compared with the operating standards so that any necessary corrective actions can be taken. Records of monitoring results should be kept in an acceptable format. The results should be reported to the responsible authorities and relevant parties, as required. 

The water is then pumped through series operated sand filters, which provide the final stage of suspended solids removal and protect the garnualr activated carbon (GAC) filters from particulate contamination. Series operated GAC filters are then used to remove the dissolved creosote and pesticides from the water. To achieve compliance with specifications levels, water should be sampled and analyzed after leaving the first GAC filter. The second GAC filter normally serves as a guard bed. 

Multidimensional chromatography has also been applied for the analysis of industrial chemicals and related samples. Industrial samples which have been analyzed by multidimensional chromatography include coal tar, antiknock additives in gasoline (3), light hydrocarbons (4, 5), trihaloalkanes and trihaloalkenes in industrial solvents (6-8), soot and particulate extracts, and various industrial chemicals that might be present in gasoline and oil samples. 

The condition of a hydraulic system, as well as its probable future performance, can best be determined by analyzing the operating fluid. Of particular interest are any changes in the physical and chemical properties of the fluid and excessive particulate or water contamination, either of which indicates impending trouble. 

The second difference is that particulate contamination larger than 10 microns can be separated and analyzed. Normal ferrographic analysis will capture particles up to 100 microns and provides a better representation of the total oil contamination than spectrographic techniques. 

The choice of method from available resources depends largely upon the properties of the material to be analyzed, the basic significance or physical wearing of the measurement, and the purpose for which the information is required. For example, failure to disperse the particles as discrete entities is the biggest single problem in all size analysis methods that depend on individual particulate behavior. With microscopic techniques particles must be dispersed on the slide to permit observation of individual particles, and in sedimentation techniques the material must be suspended in the fluid so that the particles behave as individuals and not as floes. 

Air samples can be analyzed by passing a known volume of air through a Teflon filter to catch air particulates followed by an activated charcoal filter to trap any gas-phase materials. The Teflon filters are extracted with hexane, concentrated, and analyzed by GC/MS. The charcoal traps are desorbed with carbon disulfide, concentrated, and analyzed by GC/MS. No performance data were reported (Dannecker et al. 1990). 

For small amounts of powder, dissolution of the particulate material can often be assessed (and compared with that of other compounds) by placing the powder in a calorimeter [68] and measuring the heat evolved as a function of time. The surface area must be assessed microscopically (or by image analyzer), and the data must be plotted by a cube root equation [39] ... 

---