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At low temperatures, using the original function/(T ) could lead to greater error. In Tables 4.11 and 4.12, the results obtained by the Soave method are compared with fitted curves published by the DIPPR for hexane and hexadecane. Note that the differences are less than 5% between the normal boiling point and the critical point but that they are greater at low temperature. The original form of the Soave equation should be used with caution when the vapor pressure of the components is less than 0.1 bar. In these conditions, it leads to underestimating the values for equilibrium coefficients for these components. [Pg.157]

In this oxidation state the titanium atom has formally lost its 3d and 4s electrons as expected, therefore, it forms compounds which do not have the characteristics of transition metal compounds, and which indeed show strong resemblances to the corresponding compounds of the lower elements (Si, Ge, Sn, Pb) of Group IV—the group into which Mendeleef put titanium in his original form of the periodic table. [Pg.370]

There is no doubt that the coefficient of the third term on the right hand side of this equation is much larger than the coefficient of the second term at the bulk diffusion limit, and this justifies our original form (5,29). However, on constructing from and using equation (5,32) and its... [Pg.44]

Therefore the second-order derivative of/ appearing in the original form of / is replaced by a term involving first-order derivatives of w and/plus a boundary term. The boundary terms are, normally, cancelled out through the assembly of the elemental stiffness equations over the common nodes on the shared interior element sides and only appear on the outside boundaries of the solution domain. However, as is shown later in this chapter, the appropriate treatment of these integrals along the outside boundaries of the flow domain depends on the prescribed boundary conditions. [Pg.78]

In 1875 Alexander M Zaitsev of the University of Kazan (Russia) set forth a gen erahzation describing the regioselectivity of p eliminations Zaitsev s rule summarizes the results of numerous experiments m which alkene mixtures were produced by p elim matron In its original form Zaitsev s rule stated that the alkene formed in greatest amount is the one that corresponds to removal of the hydrogen from the f3 carbon hav mg the fewest hydrogens... [Pg.204]

Data acquisition. The process of transforming spectrometer signals from their original form into suitable representations, with or without modification, with or without a computer system. [Pg.431]

The ratio of stress to strain in the initial linear portion of the stress—strain curve indicates the abiUty of a material to resist deformation and return to its original form. This modulus of elasticity, or Young s modulus, is related to many of the mechanical performance characteristics of textile products. The modulus of elasticity can be affected by drawing, ie, elongating the fiber environment, ie, wet or dry, temperature or other procedures. Values for commercial acetate and triacetate fibers are generally in the 2.2—4.0 N/tex (25—45 gf/den) range. [Pg.292]

Permanent Set. When an elastomer is stretched and then allowed to relax, it will not completely recover its original dimensions. This divergence from its original form is called its permanent set. It is principally affected by the affinity of the elastomer for the filler surface and is, therefore, primarily a function of the surface energy or wetting of the filler. [Pg.369]

Data-Star. This is Europe s leading on-line database service (39) and covers worldwide business news, financial information, market research, trade statistics, business analysis, healthcare / pharmaceuticals, chemicals / petrochemicals, chemical industry, biomedicine /life science, biotechnology, and technology, with an emphasis on Europe. It was originally formed as a joint venture among BRS, Predicasts, and Radio Suisse (the Swiss telecommunications company) (37). Data-Star offers access to about 300 bibliographic, abstract, directory, and fuU-text on-line databases, of which approximately 150 are also available on Dialog (40). [Pg.114]

U.S. Patents. This file, produced by Derwent, Inc., covers U.S. patents from 1971 to the present. The database iacludes all bibliographic and front page information and the text of all claims. (Prom 1971 to 1974 the claims from many patents were not available from the United States Patent and Trademark Office (USPTO) source tapes, and therefore are not iacluded.) The complete cl aim text can be searched from 1971 but can be ptinted only from 1982. Tides and patentee names are present ia their original form, aeither expanded nor standardized. There is no enhanced iadexiag. Examiner citations are directly searchable, and USPTO classification is updated when the tapes are received from the Patent Office. [Pg.125]

Deformation is the relative displacement of points of a body. It can be divided into two types flow and elasticity. Flow is irreversible deformation when the stress is removed, the material does not revert to its original form. This means that work is converted to heat. Elasticity is reversible deformation the deformed body recovers its original shape, and the appHed work is largely recoverable. Viscoelastic materials show both flow and elasticity. A good example is SiEy Putty, which bounces like a mbber ball when dropped, but slowly flows when allowed to stand. Viscoelastic materials provide special challenges in terms of modeling behavior and devising measurement techniques. [Pg.166]

Residual traces of zinc are released during vacuum sintering of cemented carbides made with recovered powders. This can be troublesome when a buildup of zinc occurs in the furnace. Teledyne Advanced Materials further developed this process on a commercial basis by achieving zinc levels in the low ppm range (<30 ppm). The fact that the materials were vacuum-sintered in their original form where certain impurities are removed leads to lower impurity levels in the recovered powders. There is a slight oxidation or loss of carbon that must be compensated, otherwise the recycled powder is not in any way inferior to the original. [Pg.285]

Whereas certain rocks of igneous origin formed by melting and recrystallization can include minerals enriched in the lanthanides (4), cerium is usually present as a trace element rather than as an essential component. Only a few minerals in which cerium is an essential stmcture-defining component occur in economically significant deposits. Two minerals supply the world s cerium, bastnasite [68909-13-7] LnFCO., and monazite [1306-41 -8] (Ln,Th)PO. ... [Pg.365]

Fig. 8. Springback behavior for alloy C260, as defined by the ratio of the original forming angle, 90° or q, divided by the final relaxed angle, The effects of temper and orientation ate shown as a function of bending radius R, normalised by the thickness of the strip t. Fig. 8. Springback behavior for alloy C260, as defined by the ratio of the original forming angle, 90° or q, divided by the final relaxed angle, The effects of temper and orientation ate shown as a function of bending radius R, normalised by the thickness of the strip t.
The egg shell is 94% calcium carbonate [471-34-17, CaCO, 1% calcium phosphate [7758-23-8] and a small amount of magnesium carbonate [546-93-0]. A water-insoluble keratin-type protein is found within the shell and in the outer cuticle coating. The pores of the shell allow carbon dioxide and water to escape during storage. The shell is separated from the egg contents by two protein membranes. The air cell formed by separation of these membranes increases in size because of water loss. The air cell originally forms because of the contraction of the Hquid within the egg shell when the temperature changes from the body temperature of the hen at 41.6°C to a storage temperature of the egg at 7.2°C. [Pg.456]

When u E, this interstitial mixing effect was considered complete, and the resistance to mass transfer in the mobile phase between the particles becomes very small and the equation again reduces to the Van Deemter equation. However, under these circumstances, the C term in the Van Deemter equation now only describes the resistance to mass transfer in the mobile phase contained in the pores of the particles and, thus, would constitute an additional resistance to mass transfer in the stationary (static mobile) phase. It will be shown later that there is experimental evidence to support this. It is possible, and likely, that this was the rationale that explains why Van Deemter et al. did not include a resistance to mass transfer term for the mobile phase in their original form of the equation. [Pg.262]

When the stress that can be bom at the interface between two glassy polymers increases to the point that a craze can form then the toughness increases considerably as energy is now dissipated in forming and extending the craze structure. The most used model that describes the micro-mechanics of crazing failure was proposed by Brown [8] in a fairly simple and approximate form. This model has since been improved and extended by a number of authors. As the original form of the model is simple and physically intuitive it will be described first and then the improvements will be discussed. [Pg.227]

In cases where the reactants involved are not present in the proper stoichiometric ratios, the limiting reactant will have to be determined and the excess amounts of the other reactants calculated. It is safe to assume that unconsumed reactants and inert components exit with the products in their original forms. Consider the following example. [Pg.372]

G. T. Seaborg (ed.), Transuranium Elements Products of Modem Alchemy, Dowden, Hutchinson Ross, Stroudsburg, 1978. This reproduces, in their original form, 122 key papers in the story of man-made elements. [Pg.1251]


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