Organometallic compounds pyrolysis

Chiu, W.S., Radiman, S., Abdullah, M.H., Khiew, P.S., Huang, N.M. and Abd-Shukor, R. (2007) One pot synthesis of monodisperse Fe304 nanocrystals by pyrolysis reaction of organometallic compounds. Materials Chemistry and Physics, 106 (2-3), 231-235. 

Pyrolysis of Alkali-Metal Organometallic Compounds Hydro-metallo-elimination... 

Pyrolysis of alkyl or aryl azides 8-18 Reaction between oxime sulfonates and organometallic compounds... 

Microwave treatment is widely used to prepare various refractory inorganic compounds and materials (double oxides, nitrides, carbides, semiconductors, glasses, ceramics, etc.) [705], as well as in organic processes [706,707] pyrolysis, esterification, and condensation reactions. Microwave syntheses of coordination and organometallic compounds, discussed in this chapter, are presented in a relatively small number of papers in the available literature. As is seen, the use of microwaves in coordination chemistry began not long ago and, due to the highly limited number of results, these works can be considered as a careful pioneer experimentation, in order to establish the suitability of this technique for synthetic coordination chemistry. 

Finally, the fact that these organoarsonic acids are released upon oil shale pyrolysis has important implications in the various synthetic fuel processes, where the role of organometallic compounds in poisoning process catalysts and contributing to environmental problems, is paramount. (32,33)... 

Pyrolysis of organometallic compounds containing cyclopentadiene and carbonyl groups to produce W2C [10.11]. 

Some other contributions of organometallic compounds to fundamental research are (a) the detection of free alkyl radicals by the pyrolysis of lead alkyls (b) the classification of hydrocarbon acidity via organoalkali compounds (c) the study of Lewis acid-base interactions with Group III alkyls (d) the development of the concept of electron-deficient compounds by the study of metal alkyls (e) the discovery of stereospecific olefin polymerization and (f) the investigation of nucleophilic additions to unsaturated organic compounds via reactive metal alkyls. 

The recent technique of nebulized spray pyrolysis (NSP) has been used to prepare aligned MWNTs bundles [62]. This technique consists in a spray generated by an ultrasonic atomizer. MWNTs with fairly uniform diameters, as well as ahgned MWNT bundles, have been obtained by using solutions of organometallic compounds, such as ferrocine, in benzene, toluene, and other hydrocarbon solvents. The advantage of NSP is the ease of scahng up to an industrial process where the reactants are fed into the furnace continuously. 

Pyrolysis of organometallic compounds with hydrocarbons Reaction of metal chloride or metal carbonyl with hydrocarbons, hydrogen, or CO by chemical vapor deposition... 

In connection with the participation of metals in the preparation of organometallic compounds, attention might be called to a reaction involving metallic thallium as a product. We have presented evidence for the formation of the phenylthallium radical by pyrolysis of triphenylthallium in xylene. 

Ziegler, K., K. Nagel, and W. Pfohl Organometallic compounds. XXXATII. Pyrolysis of aluminum trialkyls. liebigs Ann. Chem. 629, 210 (1960). 

Liquid mediitm reactions can synthesize, from mineral or organometallic compounds, precursors which by pyrolysis lead to amorphous nitrides ... 

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