Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Operation of the scheme

The electrical interlocking should preferably be provided through shunt trip releases. It must have a separate a.c. or d.c. source of control supply, such that the operation of the scheme is independent of the main source of supply. For the same reason, interlocking through undervoltage (U/V) releases is not recommended as its... [Pg.380]

Now it is clear that given an infinite binary tape t there is a free interpretation on Sn for which t - t (x). The schemes in Sn that we shall use to establish our undecidability results will actually test only expressions of the farm f Vx) far m > 2 and so for all purposes a tape t can be considered to correspond to a "unique" (unique as far as concerns operation of the schemes in question) free interpretation I such that... [Pg.191]

The scheme organizer lays down the rules for the conduct of the tests and the interpretation of the data. This is circulated to the participants so that they understand exactly how the scheme is run and how their results are assessed. The organizer should establish an expert advisory group which will address issues relating to the operation of the scheme, such as the tests and types of samples to be tested under the scheme, how the performance of participants is to be judged, technical difficulties raised by participants and the performance of participants in the scheme as a whole. [Pg.182]

Speirs and Griffin (1983) described the effect of the CTX scheme in attracting clinical studies on NCE in the first year of operation of the scheme. In 1980, there were 87 applications for CTC in 1981, the first year of the CTX scheme, there were 210 applications for CTX, of which 79 were for NCEs. Speirs et al. (1984) studied the effects of the CTX in encouraging inward investment into research in the United Kingdom 23 companies had increased their research investment by 100%. [Pg.427]

Speirs and Griffin described the effect of the clinical trial exemption scheme in attracting clinical studies on new chemical entities (NCE) in the first year of operation of the scheme. In 1980 there were 87 applications for... [Pg.598]

To illustrate the specific operations involved, the scheme below shows the first steps and the final detachment reaction of a peptide synthesis starting from the carboxyl terminal. N-Boc-glycine is attached to chloromethylated styrene-divinylbenzene copolymer resin. This polymer swells in organic solvents but is completely insoluble. ) Treatment with HCl in acetic acid removes the fert-butoxycarbonyl (Boc) group as isobutene and carbon dioxide. The resulting amine hydrochloride is neutralized with triethylamine in DMF. [Pg.232]

The additive characteristic of the scheme now has high stability and prevents the relay from operating on moderate external faults, while it is sensitive to small spill currents for all internal ground and phase faults, including winding faults. [Pg.483]

If/ , = minimum fault current through the primary (chosen on the basis of the rated full-load current of the machine or the system being protected) required to trip the relay. It may be termed the minimum primary operating current (POC) of the scheme, /pi. In term.s of the secondary... [Pg.483]

The rules of the scheme require the third party auditors to cover all elements of your system including those that go beyond the standard, if they form part of your quality system. The rationale is that the operations you declare in your quality system are those... [Pg.169]

Problems can also arise when the results of safety audits are used in a competitive manner, for example, to compare two plants. Such use is obviously closely linked to the operation of incentive schemes. However, as was pointed out earlier, there is no evidence that giving an award to the "best plant" produces any lasting improvement in safety. The problem here is that the competitive aspect may be a diversion from the aim of safety audits, which... [Pg.53]

Here AX is the acetyl compound (acetyl chloride or acetic anhydride), N is N-methylimidazole, I is the intermediate (presumably A -acetyl-A -methylimidazo-lium ion), X is the counterion (chloride or acetate), and ROH is the acetyl acceptor (alcohol or water). A general treatment of Scheme XXIII requires specification of the detailed nature of and k[ and is probably too complicated to be of practical use. However, several important special cases may arise from the operation of the ratio kxlk x, the behavior of apparent rate constants k /. and k, the relative magnitudes of k / and k, the relative concentrations of the reactants, the method of observation, and the nature of ROH. These cases are outlined in Scheme XXIV. [Pg.117]

The findings from two long term test runs in the SASOL plant relevant to catalyst life under design conditions in a commercial methane synthesis plant have already been published (3). This paper reports further test results from both demonstration units concerning the effect of certain reaction parameters which are the basis for flexibility and operability of the Lurgi methanation scheme. [Pg.123]

Nickel catalysts were used in most of the methanation catalytic studies they have a rather wide range of operating temperatures, approximately 260°-538°C. Operation of the catalytic reactors at 482°-538°C will ultimately result in carbon deposition and rapid deactivation of the catalysts (10). Reactions below 260°C will usually result in formation of nickel carbonyl and also in rapid deactivation of the catalysts. The best operating range for most fixed-bed nickel catalysts is 288°-482 °C. Several schemes have been proposed to limit the maximum temperature in adiabatic catalytic reactors to 482°C, and IGT has developed a cold-gas recycle process that utilizes a series of fixed-bed adiabatic catalytic reactors to maintain this temperature control. [Pg.134]

That is to say, the meaning of stability of scheme (21) is that a solution (21) depends continuously on the right-hand side and this dependence is uniform in the parameter h. This implies that a small change of the right-hand side results in a small change of the solution. If the scheme is solvable and stable, it is correct. Note that the uniqueness of the scheme (21) solution is a consequence of its solvability and stability and, hence, we might get rid of the uniqueness requirement in condition (1). Indeed, assume to the contrary that there were two solutions to equation (21), say and By the linearity property of the operator A, their difference = y — yf should satisfy the homogeneous equation... [Pg.127]

Some a priori estimates. We now consider several simplest a priori estimates for a solution to equation (21), the form of which depends on the subsidiary information on the operator of a scheme. These estimates are typical for difference elliptic problems. [Pg.132]

Let now // be a complex space and S be a non-self-adjoint operator. Then a necessary and sufficient condition for the stability in the space Ha with respect to the initial data of the scheme... [Pg.427]

Since the elimination method reciuires several operations at one node, the total number of which is independent of the grid step, the algorithm just established will be economical if one succeeds in showing that scheme (9)-(14) is absolutely stable. The following sections place a special emphasis on stability and convergence of the scheme concerned. [Pg.550]

For the most part, the proof is connected with further treatment of 5(w) as the transition operator of the two-layer scheme... [Pg.718]

Stability theory is the central part of the theory of difference schemes. Recent years have seen a great number of papers dedicated to investigating stability of such schemes. Many works are based on applications of spectral methods and include ineffective results given certain restrictions on the structure of difference operators. For schemes with non-self-adjoint operators the spectral theory guides only the choice of necessary stability conditions, but sufficient conditions and a priori estimates are of no less importance. An energy approach connected with the above definitions of the scheme permits one to carry out an exhaustive stability analysis for operators in a prescribed Hilbert space Hh-... [Pg.780]

For heat pumping to be economic on a stand-alone basis, it must operate across a small temperature difference, which for distillation means close boiling mixtures. In addition, the use of the scheme is only going to make sense if the column is constrained to operate either on a stand-alone basis or at a pressure that would mean it would be across the pinch. Otherwise, heat integration with the process might be a much better option. Vapor recompression schemes for distillation therefore only make sense for the distillation of close boiling mixtures in constrained situations3. [Pg.449]

Since it is necessary to represent the various quantities by vectors and matrices, the operations for the MND that correspond to operations using the univariate (simple) Normal distribution must be matrix operations. Discussion of matrix operations is beyond the scope of this column, but for now it suffices to note that the simple arithmetic operations of addition, subtraction, multiplication, and division all have their matrix counterparts. In addition, certain matrix operations exist which do not have counterparts in simple arithmetic. The beauty of the scheme is that many manipulations of data using matrix operations can be done using the same formalism as for simple arithmetic, since when they are expressed in matrix notation, they follow corresponding rules. However, there is one major exception to this the commutative rule, whereby for simple arithmetic ... [Pg.6]

In the critical area of (1-mannoside synthesis [317-321], the evidence strongly suggests that a-mannosyl triflate serves as a reservoir for a transient contact ion pair (CIP), which is the glycosylating species (Scheme 4.37), although the possibility of an SN2-like mechanism with an exploded transition state cannot be completely excluded [135]. In view of the probable operation of the contact ion-pair mechanism... [Pg.251]

Thus, p(f + 8f) is a sum of contributions with the phase factors (( >ab t)< b t)), the weight factors w t)Wb t)), and phase-space distributions Pb t) which appear with a probability Tab t). Associating M(f) with the Liouville operator 1 — the scheme becomes somewhat more involved. In addition to... [Pg.293]

This scheme of steps reflects the ability of some metals, like the trivalent actinides and lanthanides, to vary their coordination number since the trivalent Ln and An may go from 9 to 8 and, finally, back to 9. The last step reflects the operation of the third mechanism proposed for synergism. [Pg.125]

The laboratory top management establishes communication channels within the laboratory departments that ertsure effective and efficient operation of the laboratory. Activities that help corrrmrmication include for example, meetings, irrformation on notice boards, a laboratory jotrmal , e-mails and web sites, employee strrveys and suggestion schemes etc. [Pg.53]

Besides having smaller oxidation potential values than substituted benzyl alcohols (E° > 1.4 V/NHE), the DMAs have larger energy values (90-92 kcalmoD ) for the NC—H bond with respect to C—H bond energies around 75-85 kcalmoD of the benzyl alcohols (Scheme 12). Both factors disfavour the operation of the radical HAT route for PINO with the DMAs, and cause a mechanistic changeover to the ET route, as opposed to the reactions with the benzylic substrates listed in Table 4. [Pg.723]


See other pages where Operation of the scheme is mentioned: [Pg.57]    [Pg.218]    [Pg.332]    [Pg.57]    [Pg.218]    [Pg.332]    [Pg.348]    [Pg.41]    [Pg.72]    [Pg.417]    [Pg.460]    [Pg.8]    [Pg.690]    [Pg.441]    [Pg.330]    [Pg.8]    [Pg.174]    [Pg.411]    [Pg.765]    [Pg.350]    [Pg.83]    [Pg.165]    [Pg.95]    [Pg.231]    [Pg.231]    [Pg.477]   


SEARCH



Operational schemes

© 2024 chempedia.info