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Of fatty acid derivatives

Fatty acids normally occur naturally as esters fats oils phospholipids and waxes all are unique types of fatty acid esters There is however an important class of fatty acid derivatives that exists and carries out its biological role m the form of the free acid This class of fatty acid derivatives is described m the following section... [Pg.1079]

Scheme 9.12 Soybean lipoxygenase (SBLO)-mediated oxygenation of fatty acid derivatives. Scheme 9.12 Soybean lipoxygenase (SBLO)-mediated oxygenation of fatty acid derivatives.
For the activation of PE prior to liposome formation, it is best to employ a highly purified form of the molecule. While egg PE is abundantly available, it consists of a range of fatty acid derivatives—many of which are unsaturated—and is highly susceptible to oxidation. Synthetic PE, by contrast, can be obtained having a discrete fatty acid composition and is much more stable to oxidative degradation. [Pg.872]

O. Morin, in Recent Developments in the Synthesis of Fatty Acid Derivatives,... [Pg.271]

Bergman AM, et al. Antiproliferative activity and mechanism of action of fatty acid derivatives of gemcitabine in leukemia and solid tumor cell lines and in human xenografts. Nucleosides Nucleotides Nucleic Acids 2004 23 1329. [Pg.59]

Increased fatty acid oxidation The oxidation of fatty acids derived from adipose tissue is the major source of energy in hepatic tis sue in the postabsorptive state (see Figure 24.11, ). [Pg.328]

In tile application of surfactants, physical and use properties, precisely specified, are of primary concern. Chemical homogeneity is of little significance in practice. In fact, surfactants are generally polydisperse mixtures, such as the natural fats as precursors of fatty acid-derived surfactant structures e.g., coconut oil contains glycerol esters of Cc-Qa fatly acids. Nonionic surfactants of die alcohol edioxylate type are polydisperse not only with respect to the hydrophobe but also in the number of edivlene oxide units attached. [Pg.1583]

The mobile phases usually used for HPLC separation of fatty acid derivatives are acetonitrile-water, methanol-water, and acetonitrile-methanol-water. Elution with methanol-water mobile phase only failed to resolve linolenic (18 3) and myristic (14 0) acids. [Pg.179]

On comparing the chemical composition of hydrocarbons and fatty oils, a certain parallelism between these two groups of products is found. Actually the difference is only due to the presence of a relatively small amount of oxygen in the esters. Thus, in principle, the structural analysis of fatty acid derivatives can be carried out by removing the oxygen and transforming the products into saturated hydrocarbons of... [Pg.87]

Yet another variant for the metabolism of arachi-donic acid is the formation of leukotrienes, a series of fatty acid derivatives with a conjugated triene functionality, and first isolated from leukocytes. In a representative pathway (others have... [Pg.58]

The brown algal genus Dictyopteris shows extraordinary chemical diversity and contains examples both of fatty-acid-derived hydrocarbons and of products from terpene metabolism. The... [Pg.82]

The CM of fatty acids and derived compounds also has been used for the production of fine chemicals that are difficult to obtain by other synthetic approaches. Some examples include the synthesis of a plant growth stimulant, an insect pheromone precursor, the sex pheromone of the peach twig borer moth, and others [28]. Furthermore, the conjugation of fatty acid derivatives, sugars, and amino acids via CM was shown by Vemall and Abell [41]. C4 with a catalyst loading of 20 mol% was used to perform the CM of either Ai-Boc-L-ly sine or N-Boc-L-cysteine bearing a 10-undecenoic chain with methyl 10-undecenoate or a sugar olefin. [Pg.14]

Scheme 6 Synthesis of renewable oc, Scheme 6 Synthesis of renewable oc,<D-difunctional compounds via CM of fatty acid-derived compounds with methyl acrylate or allyl chloride [41—44]...
Scheme 9 Ethenolysis-enyne CM sequence for the synthesis of fatty acid-derived conjugated dienes [48]... Scheme 9 Ethenolysis-enyne CM sequence for the synthesis of fatty acid-derived conjugated dienes [48]...
The ene-yne CM of fatty acid-derived terminal alkenes with several alkyne derivatives was shown by Bruneau et al. [75], These reactions, which led to renewable conjugated dienes, were performed in a one-pot two-step procedure. In the first step, the ethenolysis of methyl oleate was performed in the presence of the first-generation Hoveyda-Grubbs catalyst (2.5 mol%) using dimethyl carbonate as solvent at room temperature. After completion of the ethenolysis (90% conversion), C4 (1 mol%) and the corresponding alkyne (0.5 equivalents with respect to olefins) were added and the reaction was run at 40°C for 2 h (Scheme 9). The desired dienes were thus obtained in high yields close to the maximum theoretical value (50%). Moreover, in order to maximize the formation of functional dienes, the same reaction sequence was applied to the diester obtained by SM of methyl oleate. In this way, the yield of functional dienes was increased up to 90% depending on the... [Pg.18]

Dow also developed polyurethane foams from polyols via hydroformylation of fatty acids. The foams have properties which are comparable to foams from petrochemicals in terms of density and flexibility. The advantages of using sustainable feedstocks in viscoelastic foams are increased load bearings and tensile and tear properties [39, 40]. The hydroformylation and consecutive hydrogenation of fatty acids derived from seed oil can also be used to form low viscosity polyester polyols. Therefore, fatty acid methyl esters are transesterified with diols, e.g., glycol (Scheme 12). The polymer contains chemically active hydroxy groups which can be used for polyurethanes in coating applications [41]. [Pg.114]

Jurenka, R. A. and Roelofs, W.L. (1993). Biosynthesis and endocrine regulation of fatty acid derived sex pheromones in moths. In Insect Lipids Chemistry, Biochemistry and Biology, ed. D. W. Stanley-Samuelson and D. R. Nelson. Lincoln, NE University of Nebraska Press, pp. 353-388. [Pg.200]

Generally the inclusion reaction is described to take place in a thermal gradient ranging from 90°C to room temperature. The complexes formed are often insoluble and can be separated as precipitates (21, 22). Inclusion complexes such as these often form under normal food processing conditions. The complexing of free starch due to the addition of fatty acid derivatives during production to potato flakes for instant mashed potatoes is a case in point. In this case the desired effect is related to taste due to a perceptible change in texture. [Pg.181]

M. Riisch gen. Klass and S. Warwel in G. Knothe and J. T. P. Derksen, eds., Recent Developments in the Synthesis of Fatty Acid Derivatives, AOCS Press, Champaign, Illinois. 1999, pp. 157-167. [Pg.86]


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See also in sourсe #XX -- [ Pg.23 , Pg.218 ]




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