Nuclear reactors uranium requirements

For physics reasons, uranium in the form of metal rods was extensively employed as fuel for the first generation of nuclear reactors. The requirement for metallic fuel for a natural uranium graphite-moderated reactor is based on the need for a high fuel density and a fuel rod of sufficiently large diameter to reduce the resonance capture to a level where criticality may be achieved. Only uranium in metalhc form has sufficiently high thermal conductivity to permit adequate heat removal from rods of the required diameter. 

Several components are required in the practical appHcation of nuclear reactors (1 5). The first and most vital component of a nuclear reactor is the fuel, which is usually uranium slightly enriched in uranium-235 [15117-96-1] to approximately 3%, in contrast to natural uranium which has 0.72% Less commonly, reactors are fueled with plutonium produced by neutron absorption in uranium-238 [24678-82-8]. Even more rare are reactors fueled with uranium-233 [13968-55-3] produced by neutron absorption in thorium-232 (see Nuclear reactors, nuclear fuel reserves). The chemical form of the reactor fuel typically is uranium dioxide, UO2, but uranium metal and other compounds have been used, including sulfates, siUcides, nitrates, carbides, and molten salts. 

Carbide-based cermets have particles of carbides of tungsten, chromium, and titanium. Tungsten carbide in a cobalt matrix is used in machine parts requiring very high hardness such as wire-drawing dies, valves, etc. Chromium carbide in a cobalt matrix has high corrosion and abrasion resistance it also has a coefficient of thermal expansion close to that of steel, so is well-suited for use in valves. Titanium carbide in either a nickel or a cobalt matrix is often used in high-temperature applications such as turbine parts. Cermets are also used as nuclear reactor fuel elements and control rods. Fuel elements can be uranium oxide particles in stainless steel ceramic, whereas boron carbide in stainless steel is used for control rods. 

Large quantities of uranium oxide are required for nuclear reactor fuel. The uranium ore must be carefully purified and processed to desired shapes, causing high energy expenditure. 

Canada, are examples. These reactors do not use ordinai y water for the moderator. Most nuclear fission reactors use ordinaiy water for a moderator which requires that the fuel he about 3 percent and about 97 percent U. Achieving this enrichment requires that the solid uranium compounds in the yellow cake be converted to gaseous uranium hexafluoride (UF,). Following enrichment, gaseous UF is converted to solid uranium oxide (UO,) for fabrication of fuel elements for a nuclear reactor. 

Nuclear fission power plants were at one time thought to be the answer to diminishing fossil fuels. Although the enriched uranium fuel was also limited, an advanced nuclear reactor called breeders would be able to produce more radioactive fuel, in the form of plutonium, than consumed. This would make plutonium fuel renewable. Although plutonium has been called one of the most toxic elements known, it is similar to other radioactive materials and requires careful handling since it can remain radioactive for thousands of years. 

The development of thorium-based nuclear power cycles still faces various problems and requires much more R D to be commercialised. As a nuclear fuel, thorium could play a more important role in the coming decades, partly as it is more abundant on Earth than uranium and also because mined thorium has the potential to be used completely in nuclear reactors, compared with the 0.7% of natural uranium. Its future use as a nuclear source of energy will, however, depend greatly on the technological developments currently investigated in various parts of the world and the availability of and access to conventional uranium resources. 

A single kilogram of radioactive metallic plutonium-238 produces as much as 22 million kilowatt-hours of heat energy. Larger amounts of Pu-238 produce more heat. However, Pu-238 is not fissionable, and thus it cannot sustain a chain reaction. However, plutonium-239 is fissionable, and a 10-pound ball can reach a critical mass sufficient to sustain a fission chain reaction, resulting in an explosion, releasing the equivalent of over 20,000 tons of TNT. This 10-pound ball of Pu-239 is only about one-third the size of fissionable uranium-235 required to reach a critical mass. This makes plutonium-239 the preferred fissionable material for nuclear weapons and some nuclear reactors that produce electricity. 

The most common use of plutonium is as a fuel in nuclear reactors to produce electricity or as a source for the critical mass required to sustain a fission chain reaction to produce nuclear weapons. Plutonium also is used to convert nonfissionable uranium-238 into the isotope capable of sustaining a controlled nuclear chain reaction in nuclear power plants. It takes only 10 pounds of plutonium-239 to reach a critical mass and cause a nuclear explosion, as compared with about 33 pounds of fissionable, but scarce, uranium-235. 

A modelling and experimental effort has identified a new uranium thermochemical cycle (UTC) for the production of hydrogen from water. The peak temperature within the cycle is below 700°C - a temperature achievable with existing high temperature nuclear reactors and some solar systems using commercially auailable materials. This paper describes the new process and some of the experimental work. It is an early report of chemical feasibility. Much work will be required to determine engineering and economic viability. 

Uranium-235 Enrichment. The enrichment of uranium is expressed as the weight percent of 235U in uranium. For natural uranium the enrichment level is 0.72%. Many applications of uranium require enrichment levels above 0.72%, such as nuclear reactor fuel (56,57). Normally for lightwater nuclear reactors (LWR), the 0.72% natural abundance of 235U is enriched to 2—5% (9,58). There are special cases such as matetials-testing reactors, high flux isotope reactors, compact naval reactors, or nuclear weapons where 235U enrichment of 96—97% is used. 

It should be noted that breeders would not reduce the demand for uranium ore for many decades because several LWR and/or HWR converters (which produce fissionable material, but less than consumption) are required during the run-in of a breeder cycle to equilibrium. The doubling time of a breeder (the time required for the breeder to produce sufficient fissionable material to start up a second breeder reactor) might be a significant part of its operating life. Furthermore, natural uranium will be required for the thorium cycle, if it is used, and for startup of the fusion cycle. The tritium for the fusion cycle will be made in nuclear reactors, as it now is for nuclear weapons. The nuclear industry will always be dependent on a continuing supply of uranium from ore. 

Natural uranium contains close to 0.72% by weight of the only fissionable isotope and more than 99% non-fissionable U, and a trace quantity of U. For uranium to be useful as the fuel to the nuclear reactor, the level needs to reach 1 to 5% (more often 3 to 5%) while most of the nuclear weapons and submarines require a concentration of at least 90% The separation of those uranium isotopes, very similar in properties, can not be effected by chemical means. 

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