Mond nickel process

Nickel. Nickelite, millerite, peiitlandite. xMetaliurgy of nickel. Mond process, nickel carbonyl. Nickel iViating from ammoniacal solution of ammonium nickel sulfate. Nickel sulfate, nickelous hydroxide, nickel chloride, nickelous oxide. Nirkelit oxide. Edisr>n storage cell. 

Transition metal atoms may also form complexes via dative hond formation. The extraction of nickel involves the formation and thermal decomposition of a transition metal complex. Nickel is usually extracted from its sulfide ore. This is roasted in air to give nickel(ii) oxide, NiO, which is then reduced by carbon to the impure metal. Refinement (purification) can be achieved by reaction with carbon monoxide at about 50 °C and normal pressure, which results in the formation of tetracarbonylnickel(O), NifCO). This complex is easily thermally decomposed to form extremely pure nickel (Mond process). 

Nickel Purification. The Mond process for nickel purification is based on the formation of volatile nickel carbonyl, Ni(CO)4, which is stable... 

Easily decomposed, volatile metal carbonyls have been used in metal deposition reactions where heating forms the metal and carbon monoxide. Other products such as metal carbides and carbon may also form, depending on the conditions. The commercially important Mond process depends on the thermal decomposition of Ni(CO)4 to form high purity nickel. In a typical vapor deposition process, a purified inert carrier gas is passed over a metal carbonyl containing the metal to be deposited. The carbonyl is volatilized, with or without heat, and carried over a heated substrate. The carbonyl is decomposed and the metal deposited on the substrate. A number of papers have appeared concerning vapor deposition techniques and uses (170—179). 

On the basis of the 18-electron rule, the d s configuration is expected to lead to carbonyls of formula [M(CO)4] and this is found for nickel. [Ni(CO)4], the first metal carbonyl to be discovered, is an extremely toxic, colourless liquid (mp —19.3°, bp 42.2°) which is tetrahedral in the vapour and in the solid (Ni-C 184pm, C-O 115 pm). Its importance in the Mond process for manufacturing nickel metal has already been mentioned as has the absence of stable analogues of Pd and Pt. It may be germane to add that the introduction of halides (which are a-bonded) reverses the situation [NiX(CO)3] (X = Cl, Br, I) are very unstable, the yellow [Pd"(CO)Cl2]n is somewhat less so, whereas the colourless [Pt (CO)2Cl2] and [PtX3(CO)] are quite stable. 

About 70% of the western world s supply of nickel comes from iron and nickel sulfide ores that were brought close to the surface nearly 2 billion years ago by the violent impact of a huge meteor at Sudbury, Ontario. The ore is first roasted (heated in air) to form nickel(II) oxide, which is reduced to the metal either elec-trolytically or by reaction with hydrogen gas in the first step of the Mond process ... 

Mond process The purification of nickel by the formation and decomposition of nickel carbonyl, monomer A small molecule from which a polymer is formed. Examples CH2=CH2 for polyethylene NH2(CH2)6NH2 for nylon, monoprotic acid A Bronsted acid with one acidic hydrogen atom. Example CH COOI I. monosaccharide An individual unit from which carbohydrates are considered to be composed. Example C6H(206, glucose, multiple bond A double or triple bond between two atoms. 

According to the free energy change associated with the pertinent reaction, nickel will form nickel tetracarbonyl at low temperatures, and this carbonyl will become unstable and revert back to nickel and carbon monoxide at moderate temperatures. The Mond process for refining nickel is based on these features. In this process, impure nickel is exposed to carbon monoxide gas at 50 °C, whereby volatile nickel tetracarbonyl (Ni(CO)4) forms. No impurity present in the crude nickel reacts with carbon monoxide. Since formation of the... 

Mond nickel A process for extracting nickel from its ores by the intermediary of the volatile nickel tetracarbonyl. Sulfide ores are first roasted to convert sulfides to oxides and... 

Figure 17.9 also indicates that hydrogen gas can be an effective reductant for CU2O, PbO, NiO, and CoO but not for FeO, ZnO, etc. Indeed, as noted in Section 17.4, NiO can be reduced with hydrogen (at 400 °C) to give crude nickel for the Mond process the gas used is actually water-gas (Section 9.3), and the CO content is used in making the tetracarbonylnickel. 

Trace the steps in the production of high purity nickel metal from crude sulfide ore (a) by the Sherritt Gordon ammonia leach process, (6) by the Mond process, and (c) by acid leaching. 

Nickel tetracarbonyl is a highly toxic volatile colorless liquid that is shipped in cylinders pressurized with carbon monoxide.8 Its vapor is about six times as dense as air. Purification of nickel by the Mond process is based on the decomposition of Ni(CO)4, the reverse of Eq. 15.3. The yellow-red iron pentacarbonyl slowly decomposes in air and is sensitive to light and heal. In feet. Fe-jfCOJy, an orange solid, is prepared by photolysis of Fe(CO). ... 

The Mond process separates nickel from other metals by passing CO over the hot metal mixture. The nickel reacts to form a volatile compound (called nickel carbonyl), which is then swept away by the gas stream. The reaction is... 

In (1) the electrolytic process, a nickel of 99.9% purity is produced, along with slimes which may contain gold, silver, platinum, palladium, rhodium, iridium, ruthenium, and cobalt, which are subject to further refining and recovery. In (2) the Mond process, the nickel oxide is combined with carbon monoxide to form nickel carbonyl gas, Ni(CO)4. The impurities, including cobalt, are left as a solid residue. Upon fuitlier heating of the gas to about 180°C, the nickel carbonyl is decomposed, the freed nickel condensing on nickel shot and the carbon monoxide recycled. The Mond process also makes a nickel of 99.9% purity. 

As mentioned earlier, nickel carbonyl is a volatile intermediate in the Mond process for nickel refining. This compound also is used for vapor plating of nickel in the semiconductor industry, and as a catalyst in the chemical and petrochemical industries. The toxicity of the compound has been known for many years Exposure of laboratory animals to the compound has induced a number of ocular anomalies, including aiioplidialiiiiaandinicrophtlialmia, and has been shown to be a carcinogenic for rats. 

Although nickel carbonyl is intensely poisonous, it is used in the Mond process for the refinement of nickel (see Section 16.3). Complex formation is also responsible for carbon monoxide s toxicity it attaches more strongly than oxygen to the iron in hemoglobin and prevents it from accepting oxygen from the air in the lungs. As a result, the victim suffocates. 

The Mond process for purifying nickel involves the reaction of impure nickel with carbon monoxide at about 150°C to give nickel tetracarbonyl. The nickel tetracar-bonyl then decomposes to pure nickel at about 230°C ... 

In the Mond process for purifying nickel, the volatile nickel carbonyl, Ni(CO)4, is produced by the reaction below. How much CO is used up per kilogram of nickel ... 

Although the hydrogenation of hydrogen cyanide to methylamine was achieved as early as 1863 (Debus, 1), the history of modern catalytic hydrogenation began in 1897 with the discovery by Paul Sabatier and R. Senderens of the vapor phase hydrogenation of unsaturated compounds over a nickel catalyst (Sabatier and Senderens, 2). Sabatier has said that his interest in the action of nickel was provoked by the newly discovered Mond process for the purification of nickel by the formation and decomposition of nickel carbonyl. The capacity of nickel... 

Space will not be devoted here to emphasis of the vast technological importance of iron and the steels nor to the discussion of ferrous metallurgy. However, typical processes for obtaining cobalt and nickel from natural sources are outlined in Table 24-1. The process for cobalt is somewhat oversimplified, for cobalt ores often contain, in addition to iron and arsenic, nickel, silver, or copper, which must also be removed. Note that nickel is conveniently purified by conversion to its volatile carbonyl, Ni(CO)4, unstable at high temperatures Mond process). 

The Mond Process 3 is based upon the fact that nickel readily combines with carbon monoxide at 50-80° C. to form a volatile carbonyl compound of composition Ni(CO)4, which decomposes at higher tem-... 

Mond nickel A process for extracting nickel from its ores by the intermediary of the volatile nickel tetracarbonyl. Sulfide ores are first roasted to convert sulfides to oxides, and then reduced by heating in hydrogen and carbon monoxide (water gas). The crude metal is caused to react with carbon monoxide at 50°C, producing Ni(CO)4, which is subsequently decomposed at 180 to 200°C. Invented by L. Mond and C. Langer in 1889, piloted at the works of Henry Wiggin Company in Smethwick, Scotland in 1892, and subsequently commercialized on a large scale in Swansea, South Wales, where it still operates (under the ownership of CVRD Inco). A new plant was built in Canada in 1986. 

The metal carbonyls, complexes of metals with carbon moijoxide, are interesting substances of some practical importance. In the Mond process of obtaining pure nickel from iron-nickel ores the ore is re duced with hydrogen to metallic nickel under conditions such that the... 

Nickel occurs, with iron, in meteorites. Its principal ores are nickelite, NiAs, millerite, NiS, and pentlandite, (Ni,Fe)S. The metal is produced, as an alloy containing iron and other elements, by roasting the ore and reducing with carbon. In the purification of nickel by the Mond process the gaseous compound nickel carbonyl, Ni(CO)4, is man ufactured and then decomposed. 

Ni(C0)4 is a volatile, extremely toxic liquid that must be handled with great caution. It was first observed in Mond s study of the reaction of CO with nickel valves. Because the reaction can be reversed at high temperature, coupling of the forward and reverse reactions has been used commercially in the Mond process for obtaining purified nickel from ores. Other binary carbonyls can be obtained from direct reaction of metal powders with CO, but elevated temperatures and pressures are necessary. 

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