Nickel elements

Performance Criteria Platinum Element Nickel Element Digital Output Analog Output (4—20 mA DC)... 

A new reaction observed with 7r-allylnickel methyl, alkoxides and halides is disproportionation. 7r-Allylnickel methyl decomposes spontaneously in solution even at — 60°C. to bis (7r-allyl) nickel, elemental nickel, and presumably transient methyl radicals. The reaction proceeds quantitatively accordingly to the reaction shown below since after removal of elemental nickel by filtration, exactly half of the nickel is found in the filtrate in the form of bis (7r-allyl) nickel. 

Alcan 756 C.l. 77775 Carbonyl nickel powder CCRIS 427 EINECS 231-111-4 EL12 Fibrex Fibrex P HSDB 1096 Ni 0901-S Ni 270 Ni 4303T Nichel Nickel 200 Nickel 201 Nickel 205 Nickel 207 Nickel 270 Nickel catalyst Nickel compounds Nickel, elemental Nickel, elemental/metal Nickel particles Nickel sponge NP 2 Raney alloy Raney nickel RCH 55/5. Metallic element, used in electroplating, as a hydrogenation catalyst and in iron- and copper-based alloys. Metal mp = 1453° bp (calc) = 2732° d= 8.908. Atomergic Chemetals Inco, Europe Lancaster Synthesis Co. Sigma-Aldrich Fine Chem. 

SYNONYMS (nickel) elemental nickel, nickel catalyst, nickel metal, raney alloy, raney nickel (nickel carbonate) basic nickel carbonate, carbon acid nickel salt (1 1), nickelous carbonate (nickel sulfide) mononickel monosulfide, nickel (II) sulfide, nickel monosulfide, nickelous sulfide. 

The petroleum industry faces the need to analyze numerous elements which are either naturally present in crude oil as is particularly the case for nickel and vanadium or those elements that are added to petroleum products during refining. 

The FCC structure is illustrated in figure Al.3.2. Metallic elements such as calcium, nickel, and copper fonu in the FCC structure, as well as some of the inert gases. The conventional unit cell of the FCC structure is cubic with the lengdi of the edge given by the lattice parameter, a. There are four atoms in the conventional cell. In the primitive unit cell, there is only one atom. This atom coincides with the lattice pomts. The lattice vectors for the primitive cell are given by... 

For example,copper has relatively good corrosion resistance under non-oxidizing conditions. It can be alloyed with zinc to yield a stronger material (brass), but with lowered corrosion resistance. Flowever, by alloying copper with a passivating metal such as nickel, both mechanical and corrosion properties are improved. Another important alloy is steel, which is an alloy between iron (>50%) and other alloying elements such as carbon. 

Note. The electronic configuratioa of any element can easily be obtained from the periodic table by adding up the numbers of electrons in the various quantum levels. We can express these in several ways, for example electronic configuration of nickel can be written as ls 2s 2p 3s 3d 4s. or more briefly ( neon core ) 3d 4s, or even more simply as 2. 8. 14. 2... 

Like iron and the next transition element, nickel, cobalt is not generally found in any oxidation state above + 3, and this and + 2 are the usual states. The simple compounds of cobalt(III) are strongly oxidising ... 

Nickel forms yellow anhydrous halides NiXjlX = F. Cl. Br) and a black iodide Nil2 all these halides are made by direct combination of the elements, and the chloride by reaction of sulphur dichloride oxide with the hydrated salt. All dissolve in water to give green solutions from which the hydrates can be crystallised the solutions contain the ion [NifHjOls], and the chloride crystallises as NiCl2.6H2O, nickel(II) chloride hexahydrate. 

A rather more specific mechanism of microbial immobilization of metal ions is represented by the accumulation of uranium as an extracellular precipitate of hydrogen uranyl phosphate by a Citrobacter species (83). Staggering amounts of uranium can be precipitated more than 900% of the bacterial dry weight Recent work has shown that even elements that do not readily form insoluble phosphates, such as nickel and neptunium, may be incorporated into the uranyl phosphate crystallites (84). The precipitation is driven by the production of phosphate ions at the cell surface by an external phosphatase. 

Common alloying elements include nickel to improve low temperature mechanical properties chromium, molybdenum, and vanadium to improve elevated-temperature properties and silicon to improve properties at ordinary temperatures. Low alloy steels ate not used where corrosion is a prime factor and are usually considered separately from stainless steels. 

Analysis of Trace or Minor Components. Minor or trace components may have a significant impact on quaHty of fats and oils (94). Metals, for example, can cataly2e the oxidative degradation of unsaturated oils which results in off-flavors, odors, and polymeri2ation. A large number of techniques such as wet chemical analysis, atomic absorption, atomic emission, and polarography are available for analysis of metals. Heavy metals, iron, copper, nickel, and chromium are elements that have received the most attention. Phosphoms may also be detectable and is a measure of phosphoHpids and phosphoms-containing acids or salts. 

Cobalt, copper, molybdenum, iodine, iron, manganese, nickel, selenium, and zinc are sometimes provided to mminants. Mineral deficiency or toxicity in sheep, especially copper and selenium, is a common example of dietary mineral imbalance (21). Other elements may be required for optimal mminant performance (22). ExceUent reviews of trace elements are available (5,22). 

Nickel fluoride is used in marking ink compositions (see Inks), for fluorescent lamps (4) as a catalyst in transhalogenation of fluoroolefins (5), in the manufacture of varistors (6), as a catalyst for hydrofluorination (7), in the synthesis of XeF (8), and in the preparation of high purity elemental fluorine for research (9) and for chemical lasers (qv) (10). 

K [14881-07-3], Rb [72151 -96-3], and Cs [72138-72-8]), are prepared by reaction of elemental fluorine, chlorine trifluoride, or xenon difluoride and a mixture of nickel fluoride and alkaH metal fluorides or other metal haHdes (16,17). If the fluorination is carried out using mixed fluorides, a lower temperature can be used, yields are quantitative, and the final products are of high purity. Bis(tetrafluoroammonium) hexafluoronickelate [6310540-8], (NE 2N iF6> prepared from Cs2NiF3 and NE SbE by a metathesis in anhydrous HE, is also known (18). 

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