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Nature of Interactions

The friction from the repulsive pinning center is of particular interest because it is contrary to the common belief that friction must result from attractive interactions between sliding surfaces. The results presented in Fig. 17(a) demonstrate that friction can be created by purely repulsive interactions. What really matters is the instability of the sliding body and energy dissipation, rather than the attractive or repulsive nature of interactions. This may also shed a light on the efforts to explore the correlation between friction and adhesion. [Pg.175]

Step 3. Correction factors are responsible for deviations from simple group additivity. In most cases correction factors reflect internal (electronic, steric and H-bonding) interactions between polar functional groups. Figure 14.2 describes them as two-way arrows between any two functional groups, thereby reflecting the bidirectional nature of interactions (interaction between the ith and jth fragments separated by the kth type of skeleton) as expressed in ... [Pg.369]

Nature of interactions with, and processing by, dendritic cells and other antigen... [Pg.611]

The nature of the adsorbed species can be inferred from the usual chemical parameters, i.e. chemical shifts, linewidths and relaxation times. These latter allow the study of the mobility on the surfaces. As an analytical tool, C-NMR spectroscopy can also be used to determine the concentration of reactants or products as a function of time and hence kinetic constants can easily be determined. As a conclusion, a rather complete kinetic study can be carried out involving the nature of interaction between the admolecule and the surface and eventually the nature of the surface active centers. One can finally arrive at the proposition of a reaction mechanism. [Pg.124]

Madsen, F., Eberth, K., and Smart, J.D., A rheological assessment of the nature of interactions between mucoadhesive polymers and a homogenised mucus gel. Biomaterials, 19 1083-1092 (1998). [Pg.189]

Interest in the nature of interactions between shortchain organic surfactants and large molecular weight macromolecules and ions with hydroxyapatite extends to several fields. In the area of carles prevention and control, surfactant adsorption plays an important role in the Initial states of plaque formation (1-5) and in the adhesion of tooth restorative materials ( ). Interaction of hydroxyapatite with polypeptides in human urine is important in human biology as hydroxyapatite has been found as a major or minor component in a majority of kidney stones ( 7). Hydroxyapatite is used in column chromatography as a material for separating proteins (8-9). The flotation separation of apatite from... [Pg.311]

The behaviour of ternary systems consisting of two polymers and a solvent depends largely on the nature of interactions between components (1-4). Two types of limiting behaviour can be observed. The first one occurs in non-polar systems, where polymer-polymer interactions are very low. In such systems a liquid-liquid phase separation is usually observed each liquid phase contains almost the total quantity of one polymer species. The second type of behaviour often occurs in aqueous polymer solutions. The polar or ionic water-soluble polymers can interact to form macromolecular aggregates, occasionally insoluble, called "polymer complexes". Examples are polyanion-polycation couples stabilized through electrostatic interactions, or polyacid-polybase couples stabilized through hydrogen bonds. [Pg.72]

As may be seen from the indications above the interpretation of magnetic anomalies as caused by magnetic interactions is not at all quite clear-cut. Fortunately neutron diffraction simplifies matter as it provides a definite proof of those interactions that are cooperative all over the crystal structure and detectable therefore because of spin alignment within magnetic sublattices. Such proofs are missing up to now for the higher fluorides, however. The break-down of Hund s rule for the 4d-and 5i-ions, in most fluorides of which even the weak-field ligand fluorine causes low-spin behaviour, may account for this as well as the different nature of interactions assumed instead. [Pg.73]

Clearly, UV and EB radiation have a great deal in common, as shown above. However, there are also differences. Besides the nature of interacting with matter, where high-energy electrons penetrate, and photons cause only surface effects, there are issues concerning the capital investment and chemistry involved. [Pg.2]

Measurement of the static structure factor using scattering techniques also provides us with a nonintrusive method to probe the structure of dispersions and the nature of interaction forces in colloids. Structural changes in colloids are particularly of interest in colloid-based techniques for fabrication of structural and special-purpose ceramics. [Pg.228]

The primary condition for a bimolecular process is close approach of two molecules, which in normal terminology is called a collision. The closeness of approach is a variable term and depends on the nature of interaction between the two colliding partners. For ground state molecules, the collisions are defined by gas kinetic theory based on a hard sphere model. The number of collision per second between unlike molecules A and B and between molecules of the same kind are, respectively,... [Pg.165]


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