N-Phenyl acetamide

When acetophenone oxime (1) is thermically treated with acidic solids in "dry media" under soft experimental conditions, two main products are obtained the rearrangement one acetanilide (N-phenyl acetamide) (2) obtained by Beckmann rearrangement with migration of the phenyl group, and the hydrolysis one acetophenone (3), obtained by the hydrolysis of the imino group (C=N) (eqn.2). 

N-Methyl-N-phenyl acetamide, 114 N-Methyl-N-phenylformamide, 113 Methyl phenyl glyoxalate, 327 N-Methyl-N-phenyl propionamide, 114 N-Methylpiperidone, 117 Methyl 2,3,4,6-tetra-0-acetyl-6-D-glucopyranoside, 85... 

Reduziert man z.B. N-Methyl-N-phenyl-acetamid mit Natrium/fl. Ammoniak/Atha-nol, so erhalt man in 56%-iger Ausbeute Acetaldehyd2. Hexansaure-diathylamid wird durch Natrium/fl. Ammoniak/Essigsaure in 53%-iger Ausbeute zu Hexanal reduziert3 und 1-Acetyl- bzw. l-(3-Phenyl-propanoyl)-2-carboxy-pyrrolidin bilden bei Reduktion mit Lithium/Methylamin/-70°2-Carboxy-pyrrolidin (Prolin)4 ... 

N-[2,4-Dimethyl-5-[[(trifluoromethyl)-sulfonyl]aniino] phenyl]acetamide] [53780-34-0]... 

Chemical Name N-[4-[2-hydroxy-3-[(1-methylethyl)amino] propoxy) phenyl] acetamide... 

Finally there has been a growing interest in the development of selective leukotriene inhibitors. Bay Y 1015 (R-(-)-2-cycloheptyl-N-methylsulfonyl-(4-(2-quinolinyl-methoxy) phenyl)-acetamide) is a quinoline-type 5-lipoxygenase-activating protein inhibitor which was effective in inhibiting inflammation in a dextran sulfate model of mouse colitis [112]. Whether these compounds can also exert their anti-inflammatory action through inhibition of endothelial cell activation needs to be established. 

Benzyloxy-phenyl)-1-nitro-ethen mit Lithium-N,N-dimethyl-acetamid 3-(2-Benzyl-oxy-phenyl)-4-nitro-butansaure-dimethylamid (99%) ... 

PHENYL ACETAMIDE, N-HYDROXYL-N-PHENYL- (1795-83-1), 67, 187 ACETYLTRIMETHYLSILANE Silane, acetyltrimethyl (13411-48-8), 68, 25... 

Moreover, the formation of enoxy-silanes via silylation of ketones127 by means of N-methyl-N-TMS-acetamide (1 72) in presence of sodium trimethylsilanolate (173) was reported in 1969 and since then, the use of silylating reagents in presence of a catalyst has found wide appreciation and growing utilization as shown in recent papers128-132 (Scheme 27). Diacetyl (181) can be converted by trifluoromethylsul-fonic acid-TMS-ester (182) into 2,3-bis(trimethylsiloxy)-l, 3-butadiene (7treatment with ethyl TMS acetate (7 5)/tetrakis(n-butyl)amine fluoride l-trimethylsiloxy-2-methyl-styrene (i<56)130. Cyclohexanone reacts with the combination dimethyl-TMS-amine (18 7)/p-toluenesulfonic acid to 1-trimethylsiloxy-l-cyclohexene (iSS)131. Similarly, acetylacetone plus phenyl-triethylsilyl-sulfide (189) afford 2-triethylsiloxy-2-pentene-4-one (790)132. ... 

Zaleplon was determined in the presence of its alkaline degradation product namely N-[4-(3-cyano-pyrazolo[l,5-fl]pyridin-7-yl)-phenyl]-N-ethyl-acetamide by measuring its D2 (second derivative) and aDD (first... 

So the N-[2-hydroxy-5-[4-(hydroxymethyl)-l,3,2-dithiarsolan-2-yl]phenyl] acetamide, melting point 163°-166°C is obtained. 

CijH NjOj 90357-51-0) see Bicalutarnide 4 -cyano-3 -trifluoromethylmethacrylanilidc (Cl2H,7F7N20 90357-53-2) sec Bicalutarnide AL[4-cyano-2-(trifluoromethyl)phenyl (acetamide (C 0H7F,N () 175277-96-0) see Mabutcrol /V-(4-cyano-3-trifluoromethylphenyl)-3-(fluorophenyl-sulfanyl)-2-hydroxy-2-methylpropionamide (C,hH14F4N202S 90356-78-8) see Bicalutarnide 2-cyano-3-(3,4,5-trimethoxyphenyl)-2-propcnoic acid ethyl ester... 

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