N- acetamid

Brian and Lamberton [13] accomplished the synthesis of methylenedinitramine with methylene-bis-N-acetamide (III) ... 

Deoxy-D-ribose, AE75 2-Deoxy-L-ribose, AE76 Di-N-acetamide, AD07 Diacetic acid diselenide, AC90 Diacetone alcohol, AI00 2-Diacetoxymethyl-5-ni trofuran,... 

N-Debenzylation.1 The P-D-glucopyranoside 1, when dissolved in DMSO containing KOC(CH3)3, is rapidly converted into the N-acetamide derivative 2 when air is passed into the stirred solution. This conversion of an N-benzylacetamido group into an acet-amido group is a general reaction. It can also be used to prepare acetylated amines. Thus... 

Reactions of [MCls-xMe,] (x = 1, 2 or 3) with heterocumulenes have led to insertions into the M—C bond. lV,lV -Dialkylacetamidinato derivatives were obtained (equation 33). N-Acetamides or N-thioacetamides were formed with isocyanates or isothiocyanates, respectively (equation 34). The rate of insertion varied in the order [MCl4Me] > [MCl3Me2] > [MCl2Me3], following the established order of acceptor properties of the methylmetal chlorides, the isocyanates being more reactive than the isothiocyanates. Hexa- or hepta-coordinated species were obtained. 

The student should carry out the following simple experiments with acetamide or with any other ahphatic amide, e.g., n-caproamide they illustrate some of the general reactions of primary ahphatic amides. 

N,N -Dihexyl-2-phenylindole-3-acetamide from 3-phenyl-3-oxopropanoic Acid[4]... 

N-[2,4-Dimethyl-5-[[(trifluoromethyl)-sulfonyl]aniino] phenyl]acetamide] [53780-34-0]... 

ANTTBIOTTCS - NUCLEOSIDES AND NUCLEOTIDES] (Vol 3) 2-(formylamino)-N-(5-0-phosphono-b-d-ribofuranosyl acetamide [349-34-8]... 

ANTIBACTERIALAGENTS SYNTTiETIC - NITROFURANS] (Vol 2) N[4-(5-Nitro-2-furanyl)-2-thiazolyl] acetamide... 

N,N- dimethyl- aceto acetamide [2044-64-6] bp 75-77 (0.2 kPa) insecticides, polyester curing... 

Furium. N[4-(5-Nitro-2-furanyl)-2-thia2olyl]acetamide, has demonstrated activity against baciUi and pathogenic enterobacteria (24). The product, prepared from thiourea and 2-bromo-l-(5-nitro-2-furanyl)ethanone followed by acetylation of the intermediate aminothia2ole with acetic anhydride in pyridine (25), is marketed in several countries for both human and veterinary use. 

Aqueous salt solutions such as saturated 2inc chloride [7646-85-7] or calcium thiocyanate [2092-16-2] can dissolve limited amounts of cellulose (87). Two non-aqueous salt solutions are ammonium thiocyanate [1762-95-4]— uoamonia. and lithium chloride /744Z-4/A/—dimethyl acetamide [127-19-5]. Solutions up to about 15% can be made with these solvents. Trifluoroacetic acid [76-05-17—methylene chloride [75-09-2] and /V-methy1morpho1ine N-oxide [7529-22-8]—(92—94) are two other solvent systems that have been studied (95). 

Acetamide, af,Q, Q -trifluoro-N,N-dimethyl-trifluoromethyl ketones from, 4, 833-834... 

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