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Mode mixing

The fitting parameters in the transfomi method are properties related to the two potential energy surfaces that define die electronic resonance. These curves are obtained when the two hypersurfaces are cut along theyth nomial mode coordinate. In order of increasing theoretical sophistication these properties are (i) the relative position of their minima (often called the displacement parameters), (ii) the force constant of the vibration (its frequency), (iii) nuclear coordinate dependence of the electronic transition moment and (iv) the issue of mode mixing upon excitation—known as the Duschinsky effect—requiring a multidimensional approach. [Pg.1201]

The stored strain energy can also be determined for the general case of multiaxial stresses [1] and lattices of varying crystal structure and anisotropy. The latter could be important at interfaces where mode mixing can occur, or for fracture of rubber, where f/ is a function of the three stretch rations 1], A2 and A3, for example, via the Mooney-Rivlin equation, or suitable finite deformation strain energy functional. [Pg.380]

Fig. 13 Contamination patterns identified (MCR-ALS resolved loading profiles) in the Ebro River delta from May to August 2005. On the left loadings in the second mode (normalized for variables to unit norm) describing the composition of the contamination patterns. Variable identification in Table 1. On the right loadings in the first and third modes (mixed) describing spatial and temporal distribution of the contamination patterns. Sampling sites ordered from North to South, for the four analyzed months displayed consecutively (May 1-11 June 12-22 July 23-33 August 34 4)... Fig. 13 Contamination patterns identified (MCR-ALS resolved loading profiles) in the Ebro River delta from May to August 2005. On the left loadings in the second mode (normalized for variables to unit norm) describing the composition of the contamination patterns. Variable identification in Table 1. On the right loadings in the first and third modes (mixed) describing spatial and temporal distribution of the contamination patterns. Sampling sites ordered from North to South, for the four analyzed months displayed consecutively (May 1-11 June 12-22 July 23-33 August 34 4)...
The use of a few of the most isotopically sensitive frequencies to estimate the 180 EIE can be problematic. In large molecules, the presence of matrix effects as well as mode mixing can cause several vibrational frequencies to be affected by isotope... [Pg.430]

However, it should be noted that the effect of distortion and mode mixing (i.e., Duschinsky effect) of potential surfaces has been studied [30,37]. [Pg.147]

Perhaps the simplest case displaying geometrical mode mixing... [Pg.193]

The foci are separated by a distance a along the z axis. See Morse and Feshback (25) for details. Eccentricity of form is found to effect profoundly autonomous current patterns. This geometric mode mixing phenomenon leads to patterns that can be controlled by the chemical kinetics in a manner not found for simple, highly symmetric geometries... [Pg.194]

Introduced, then mode mixing will not occur if the 1... [Pg.196]

Manganese bronzes Susceptible to SCC in NH3, but less than Cu-Zn alloys minimum cracking time at 5-6% Mn alloys with 4.94% Mn failed by intergranular SCC 21.38, 24.5% Mn alloys fail by transgranular mode mixed mode SCC observed with 10.64% Mn alloys... [Pg.243]

Not only are accurate data for trace metals in rivers sparse, there are complications that exist at the river-sea interface. The increase in salinity occurring at the river-sea water interface, with its concomitant increase in the concentrations of the major seawater cations, can lead to flocculation and sedimentation of trace metals such as iron (Boyle et al., 1978 Sholkovitz and Copeland, 1983) or to desorption from suspended riverine particles of trace metals such as barium (Edmond et al., 1978). In organic-rich rivers a major fraction of dissolved trace metals can exist in physiochemical association with colloidal humic acids. Sholkovitz and Copeland (1983) used product-mode mixing experiments on filtered Scottish river water, and observed that iron removal was almost complete due to the flocculation of strongly associated iron-humic acid colloids in the presence of the increased... [Pg.2887]

Migration of vacancies, V , in the dense material and transfer of electronic species, e, either in the dense material or in an external circuitry, depending on the conduction mode (mixed ionic-electronic or purely ionic). [Pg.152]

If it is assumed that (a) the force constants are the same in both ground and the excited states, (b) the potential surfaces are harmonic, (c) the transition dipole moment, n, is constant and (d) the normal coordinates are not mixed in the excited state, then the overlaps, << in absorption and ( < (t)> in Raman, have simple forms (Sections III.A and III.B). None of these assumptions are requirements of the time-dependent theory. Assumption (a) introduces at most an error of 10% if the distortions are very large [25]. When the vibrational frequencies in the excited state are not known, this assumption must be used but does not introduce serious error. The harmonic approximation is used because the number of parameters to be fitted is thereby reduced and because it allows the simple expression for the overlap to be used. Because there is no distinct evidence of normal mode mixing in the molecules studied in this chapter, all of the fits were done without including... [Pg.130]

Global Regenerator Mode) Mixing cell framework. [Pg.275]


See other pages where Mode mixing is mentioned: [Pg.353]    [Pg.374]    [Pg.174]    [Pg.174]    [Pg.566]    [Pg.168]    [Pg.244]    [Pg.13]    [Pg.13]    [Pg.247]    [Pg.115]    [Pg.775]    [Pg.44]    [Pg.206]    [Pg.641]    [Pg.192]    [Pg.193]    [Pg.196]    [Pg.196]    [Pg.197]    [Pg.241]    [Pg.246]    [Pg.31]    [Pg.6255]    [Pg.6260]    [Pg.77]    [Pg.140]    [Pg.681]    [Pg.288]    [Pg.132]    [Pg.168]    [Pg.343]    [Pg.189]    [Pg.75]    [Pg.250]    [Pg.136]    [Pg.325]   
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See also in sourсe #XX -- [ Pg.32 ]

See also in sourсe #XX -- [ Pg.57 , Pg.94 , Pg.97 , Pg.99 , Pg.101 , Pg.162 , Pg.228 , Pg.233 , Pg.245 ]




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Acclaim Mixed-Mode WAX

Acclaim Mixed-Mode WCX

Acclaim Mixed-Mode silica columns

Applications of Ion Chromatography on Mixed-Mode Stationary Phases

Belousov-Zhabotinskii reaction mixed mode oscillations

Calculations, mixed mode

Chemical oscillators mixed-mode oscillations

Chemically bonded phases mixed mode

Chromatography mixed-mode

Chromatography mixed-mode liquid

Diffusion mixed mode

Fracture criteria, mixed mode

Fracture mixed mode

Ion exchange mixed mode

Lubrication modes mixed

Mixed Anchoring Modes

Mixed Mode of Particle Nucleation Mechanisms

Mixed growth mode

Mixed mode

Mixed mode

Mixed mode applications

Mixed mode state

Mixed mode test

Mixed-Mode Bonded Phases

Mixed-mode columns

Mixed-mode cracking

Mixed-mode deformation

Mixed-mode failure

Mixed-mode joint geometry

Mixed-mode mechanism

Mixed-mode oscillations

Mixed-mode retention

Mixed-mode stationary phase

Mixed-mode twisted nematic (MTN) cells

Mixing acoustic modes

Mode mix

Mode mix

Mode mixing Subject

Oscillations mixed mode type

Phases mixed-mode

Polymer-Based Mixed-Mode Columns

Proteins mixed-mode interactions

Quantum-classical mixed mode equations

Separator Acclaim Mixed-Mode silica columns

Separator mixed-mode

Silica-Based Mixed-Mode Columns

Solid mixed-mode

Solid phase extraction mixed-mode sorbents

Solving a pseudo-steady state mixed mode

Sorption mixed mode

Spin-orbit coupling mode mixing

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