1- Methyl-2,6-dinitro-benzene

Answer The nitro groups must be put in by nitration but the orientation is wrong. The methyl group cannot be disconnected as a Friedel-Crafts alkylation would never work on the available but extremely unreactive m-dinitro benzene. The solution (guideline 5) is to introduce a dummy amino group in such a position that it can activali... 

Synonyms AI3-15342 BRN 1912834 CCRIS 268 2,4-DNT 2,4-Dinitromethylbenzene Dinitrotoluol 2,4-Dinitrotoluol DNT 2,4-DNT EINECS 204-450-0 l-Methyl-2,4-dinitro-benzene NCI-C01865 NSC 7194 RCRA waste number U105 UN 2038. 

Benzene, 2-ethyl-5-isooctyl-4-methoxy-l, 3-dinitro Benzene, l-isoheptyl-2-methoxy-4-methyl-3, 5-dinitro Benzene, l-isooctyl-2-methoxy-4-methyl-3, 5-dinitro Ethanone, 1- [3-(l,l-dimethylethyl)-2-methoxy-5-nitrophenyl Benzene, 1,3-dibromo-2-isopropyl-5-methoxy-4-nitro Benzene, 1,3-BIS- (1, l-dimethylethyl)-5-nitro Benzaldehyde, 5 (l,l-dimethylethyl)-2-methoxy-3-nitro Benzene, 1, 5-BIS- (1, l-dimethylethyl)-2 methoxy-4 methyl... 

Benzene, 1, 3-Bis (l,l-dimethylethyl)-5-methyl-2,4,6-trinitro Benzene, 3-(l,l-dimethylethyl)-l-fluoro-5-methyl-2, 4, 6-trinitro Benzene, 2-hexyl-4-methyl-l, 3, 5- trinitro Benzene, 2-methyM- (l-methylethyl)-l, 3, 5-trinitro Benzene, l-(l,l-dimethylethyl)-2-ethoxy-3, 5-dinitro Benzene, l-(l,l-dimethylethyl)-2-ethoxy-4 ethyl 3, 5-dinitro Benzene, l-(l,l-dimethylpropyl)-4 ethyl-2-methoxy- 3, 5-dinitro Benzene, 1,3-Bis (l,l-dimethylethyl)-4-methoxy-6-methyl-2,... 

Dinitro 3 chloro 4 trifluoro methyl chloro benzene fluazinam... 

Dinitro-ethyl-p-toluene Sulfonate or 3,5 Dinitro-4-methyl-ethy[benzene Sulfonate,... 

Trinitro-N-methyl-diphenylamine or l-(2 -Nitro-N-methylanilino)-(2,6-dinitro-benzene), 0,N.C,H .N(CH,).C,H,(NO,), yel ndls, mp 221 3° Was obtained on prolonged heating of a mtxt of 2,6-dinitrochloro-benzene, N-methyl-o-nitraniline, K,S04, Cul and amyl alcohol... 

With regard to radical polymerization some controversial results have also been obtained. Thus Mondvai and co-workers [138] have shown that o-dinitro benzene was a stronger retardant of radical polymerization of methyl methacrylate than other isomers. On the contrary Hammond and Bartlett [139] found that o-6initrobenzcne was a weaker retardant than other isomers of polymerization of allyl acetate. 

Beilstein Handbook Reference) Aceto-phenone, 4 -t-butyl-2, 6 -dimethyl-3, 5 -dinitro- 2-Acetyl-5-l-butyl-4,6-clinitroxylene AI3-02440 BRN 2062638 4-t-Butyl-3,5-dinitro-2,6-dimethylaceto-phenone 4 -t-Butyl-2, 6 -dimethyl-3, 5 -dinitroaceto-phenone CCRIS 4677 1-(4-(1,1-Dimethylethyl)-2,6-dimethyl-i5-dinitrophenyl)-ethanone 2,6-Dinitro-3,5-di-methyl-4-acetyl-t-butyl-benzene 3, Dinitro-2,6-di-methyl-4-t-butylacetophen-one EINECS 201-328-9 Ethanone, 1-(4-(1,1-dimethyl-ethyl)-2,6-dimethyl-3,5-Musk ketone NSC 15339 Acetophenone, 4 -t-butyl-2, 6 -dimethyl-3, 5 -dinitro- 1-Acetyl-4-t-butyl-2,6-dimethyl-3,5-dinitro-benzene 4-t-Butyl-2,6-dimethyi-3,5-dinitro-acetophen-one 4 -t-Butyl-2, 6 -dimethyl-3, 5 -dinitro-acetophenone 1-[4-(1,1-Dimethylethyl)-2,6-dimethyl-3,5-dinitrophenyl]-ethanone. An artificial musk perfume. Solid mp = 138-140°. AM Aromatics Pvt, Ltd. Zhejiartg Winsun Imp. And Exp. Co., Ltd. 

Benzene, 1-(1,1-dimethylethyl)-3,5-dimethyl-2,4,6-trinitro-. See Musk xylene Benzene, 1-(1,1-dimethylethyl)-2,6-dinitro-3,4,5-trimethyl-. See Musk tibetene Benzene, 1-(1,1-dimethylethyl)-2-methoxy-4-methyl-3,5-dinitro-. See Musk ambrette Benzene, 1,3-dinitro- Benzene, m-dinitro-. See... 

Dichloro- 2 5-dinitro-p-t rmene (3 6-Dichloro-2 5- dinitro 1. methyl isopropyU benzene)... 

Benzene, 2-methyl-1,3-dinitro-Benzene, 2-methyl-l,4-dinitro-... 

Compounds containing two primary amino groups attached to a benzene ring can be prepared by the reduction of dinitro compounds and of nitroanilines, usually with tin or stannous chloride and hydrochloric acid or with iron and very dilute hydrochloric acid. / ara-diamines may also be obtained by the reduction of aromatic amino-azo compounds (e.g., p-aminodimethylanihne from methyl orange, see Section IV,78). p-Phenylenediamine may also be prepared from p-nitroacetanilide reduction with iron and acid yields p-amino-acetaniUde,.which may be hydrolysed to the diamine. 

However, other studies on the nitration of a series of 3-methyl- and 3-ethyl-1,2-benzisoxazoles have shown that a mixture of the 5-nitro and 5,7-dinitro derivatives is formed (77IJC(B)1058, 77IJC(B)1061). The effect of substituents in the benzene ring is also of interest. If the 5-position is blocked, e.g. by a chloro group or by alkyl groups, nitration then occurs at the 4-position. 3-Alkyl-7-chloro and 3,7-dialkyl derivatives result in the formation of the appropriate 5-nitro derivative. The isomeric 3-alkyl-6-chloro- and 3,6-dialkyl-1,2-benzisoxazoles yield a mixture of the 5-nitro and 5,7-dinitro compounds. Both H NMR measurements and alternate syntheses were used in establishing the structures of these substitution products. 

Dinitro-mesitylene (2,4-Dinitro-l, 3,5-tri-methyl benzene). C9H10N2O4, mw 210.21,... 

Dinitro-1,3,5-tri methyl benzene Di-(P-nitroxyethyl) ammonium nitrate a, a -Di-(nitroxyl) methylether... 

AI3-00040, see Cyclohexanol AI3-00041, see Cyclohexanone AI3-00045, see Diacetone alcohol AI3-00046, see Isophorone AI3-00050, see 1,4-Dichlorobenzene AI3-00052, see Trichloroethylene AI3-00053, see 1,2-Dichlorobenzene AI3-00054, see Acrylonitrile AI3-00072, see Hydroquinone AI3-00075, see p-Chloro-rrr-cresol AI3-00078, see 2,4-Dichlorophenol AI3-00085, see 1-Naphthylamine AI3-00100, see Nitroethane AI3-00105, see Anthracene AI3-00109, see 2-Nitropropane AI3-00111, see Nitromethane AI3-00118, see ferf-Butylbenzene AI3-00119, see Butylbenzene AI3-00121, see sec-Butylbenzene AI3-00124, see 4-Aminobiphenyl AI3-00128, see Acenaphthene AI3-00134, see Pentachlorophenol AI3-00137, see 2-Methylphenol AI3-00140, see Benzidine AI3-00142, see 2,4,6-Trichlorophenol AI3-00150, see 4-Methylphenol AI3-00154, see 4,6-Dinitro-o-cresol AI3-00262, see Dimethyl phthalate AI3-00278, see Naphthalene AI3-00283, see Di-rj-butyl phthalate AI3-00327, see Acetonitrile AI3-00329, see Diethyl phthalate AI3-00399, see Tributyl phosphate AI3-00404, see Ethyl acetate AI3-00405, see 1-Butanol AI3-00406, see Butyl acetate AI3-00407, see Ethyl formate AI3-00408, see Methyl formate AI3-00409, see Methanol AI3-00520, see Tri-ocresyl phosphate AI3-00576, see Isoamyl acetate AI3-00633, see Hexachloroethane AI3-00635, see 4-Nitrobiphenyl AI3-00698, see IV-Nitrosodiphenylamine AI3-00710, see p-Phenylenediamine AI3-00749, see Phenyl ether AI3-00790, see Phenanthrene AI3-00808, see Benzene AI3-00867, see Chrysene AI3-00987, see Thiram AI3-01021, see 4-Chlorophenyl phenyl ether AI3-01055, see 1.4-Dioxane AI3-01171, see Furfuryl alcohol AI3-01229, see 4-Methyl-2-pentanone AI3-01230, see 2-Heptanone AI3-01231, see Morpholine AI3-01236, see 2-Ethoxyethanol AI3-01238, see Acetone AI3-01239, see Nitrobenzene AI3-01240, see I idine AI3-01256, see Decahydronaphthalene AI3-01288, see ferf-Butyl alcohol AI3-01445, see Bis(2-chloroethoxy)methane AI3-01501, see 2,4-Toluene diisocyanate AI3-01506, see p,p -DDT AI3-01535, see 2,4-Dinitrophenol AI3-01537, see 2-Chloronaphthalene... 

NONM Benzene, 2-Methoxy 1-methyl-1 -(4-methylpentyl)-3,5-dinitro... 

NONM Benzene, l-bromo-4 butyl-2-methyl-3, 5-dinitro... 

NONM Benzene, 1-(1, l-dimethylbutyl)-2-methoxy-4-methyl-3-5-dinitro... 

Benzene, 2-methyl-4- (2-methylpropyl)-1,3,5-trinitro Benzene, 5-(l,l-dimethylethyl)-2-ethyl-l, 3-dinitro-Ethanone, l-(2-butyl-3-methyl-4, 6-dinitrophenyl)-Benzene, l-(l,l-dimethylethyl)-2-methoxy-3, 5-dimethyl-4, 6-dinitro... 

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