Maxwell mechanical model

Figure 8.1. Diagram showing Maxwell mechanical model of viscoelastic behavior of connective tissues. In this model an elastic element (spring) with a stiffness Em is in series with a viscous element (dashpot) with viscosity T m. This model is used to represent time dependent relaxation of stress in a specimen bold of fixed length.

Equation (21.10) is the general equation for the Maxwell mechanical model analogy for viscoelastic behavior. 

In the case of a stress relaxation experiment using the Maxwell mechanical model, if an initial strain is imposed and the change in the stress is followed as a function of time, the resulting expression is as follows ... 

It is also common that polymers are subjected to forces, or stresses, such as mechanical vibration in that case, the strain will also be sinusoidal in the same frequency but not in the same phase. In that sense, it is possible to model the responses to a periodic strain using the Maxwell mechanical model analogy. The response to an applied sinusoidal strain... 

These equations are often used in terms of complex variables such as the complex dynamic modulus, E = E + E", where E is called the storage modulus and is related to the amount of energy stored by the viscoelastic sample. E" is termed the loss modulus, which is a measure of the energy dissipated because of the internal friction of the polymer chains, commonly as heat due to the sinusoidal stress or strain applied to the material. The ratio between E lE" is called tan 5 and is a measure of the damping of the material. The Maxwell mechanical model provides a useful representation of the expected behavior of a polymer however, because of the large distribution of molecular weights in the polymer chains, it is necessary to combine several Maxwell elements in parallel to obtain a representation that better approximates the true polymer viscoelastic behavior. Thus, the combination of Maxwell elements in parallel at a fixed strain will produce a time-dependent stress that is the sum of all the elements ... 

The Maxwell model is also called Maxwell fluid model. Briefly it is a mechanical model for simple linear viscoelastic behavior that consists of a spring of Young s modulus (E) in series with a dashpot of coefficient of viscosity (ji). It is an isostress model (with stress 5), the strain (f) being the sum of the individual strains in the spring and dashpot. This leads to a differential representation of linear viscoelasticity as d /dt = (l/E)d5/dt + (5/Jl)-This model is useful for the representation of stress relaxation and creep with Newtonian flow analysis. 

The simplest model that can show the most important aspects of viscoelastic behaviour is the Maxwell fluid. A mechanical model of the Maxwell fluid is a viscous element (a piston sliding in a cylinder of oil) in series with an elastic element (a spring). The total extension of this mechanical model is the sum of the extensions of the two elements and the rate of extension is the sum of the two rates of extension. It is assumed that the same form of combination can be applied to the shearing of the Maxwell fluid. 

The meaning of "model" was to become far less concrete in the next couple of decades. In 1929, Irving Langmuir criticized mechanical models, like those of Lord Kelvin and Maxwell, on the grounds that the relationships of their parts are restricted to what is already known in mechanics, electricity, or magnetism, limiting the possibility of new insights into new phenomena. "Mathematical relationships are far more flexible," he claimed, and "the mathematical theory is a far better model of the atom than any of the mechanical... 

Another approach that has physical merit is to model the behavior of viscoelastic materials as a series of springs (elastic elements) and dashpots (viscous elements) either in series or parallel (see Figure 8.1). If the spring and dashpot are in series, which is described as a Maxwell mechanical element, the stress in the element is constant and independent of the time and the strain increases with time. 

When the examination was over and the report submitted, a new tumult was raised. Kelvin opposed the theory in general. He could -understand nothing, he said, which could not be translated into a mechanical model. For this reason he had likewise rejected Maxwell s electromagnetic theory of light. Only the Dane submitted an enthusiastic judgment of the... 

Fig. 11-16. Simple mechanical models of viscoelastic behavior, (a) Voigt or Kelvin element and (b) Maxwell element.

If the creep experiment is extended to infinite times, the strain in this element does not grow indefinitely but approaches an asymptotic value equal to tq/G. This is almost the behavior of an ideal elastic solid as described in Eq. (11 -6) or (11 -27). The difference is that the strain does not assume its final value immediately on imposition of the stress but approaches its limiting value gradually. This mechanical model exhibits delayed elasticity and is sometimes known as a Kelvin solid. Similarly, in creep recovery the Maxwell body will retract instantaneously, but not completely, whereas the Voigt model recovery is gradual but complete. 

Neither simple mechanical model approximates the behavior of real polymeric materials very well. The Kelvin element does not display stress relaxation under constant strain conditions and the Maxwell model does not exhibit full recovery of strain when the stress is removed. A combination of the two mechanical models can be used, however, to represent both the creep and stress relaxation behaviors... 

This chapter is devoted to describe the impact of metallic nanosphere to the multi-photon excitation fluorescence of Tryptophan, and little further consideration to multi-photon absorption process will be given, as the reader can find several studies in [11-14]. In section II, the nonlinear light-matter interaction in composite materials is discussed through the mechanism of nonlinear susceptibilities. In section III, experimental results of fluorescence induced by multi-photon absorption in Tryptophan are reported and analyzed. Section IV described the main results of this chapter, which is the effect of metallic nanoparticles on the fluorescent emission of the Tryptophan excited by a multi-photon process. Influence of nanoparticle concentration on the Tryptophan-silver colloids is observed and discussed based coi a nonlinear generalization of the Maxwell Garnett model, introduced in section II. The main conclusion of the chapter is given in secticHi IV. 

The application of the Maxwell-Stefan theory for diffusion in microporous media to permeation through zeolitic membranes implies that transport is assumed to occur only via the adsorbed phase (surface diffusion). Upon combination of surface diffusion according to the Maxwell-Stefan model (Eq. 20) with activated-gas translational diffusion (Eq. 12) for a one-component system, the temperature dependence of the flux shows a maximum and a minimum for a given set of parameters (Fig. 15). At low temperatures, surface diffusion is the most important diffusion mechanism. This type of diffusion is highly dependent on the concentration of adsorbed species in the membrane, which is calculated from the adsorption isotherm. At high temperatures, activated-gas translational diffusion takes over, causing an increase in the flux until it levels off at still-higher temperatures. 

The simplest mechanical model which can describe a viscoelastic solution is called Maxwell element. It consists of a spring and a viscous element (dashpot) connected in series. The spring corresponds to a shear modulus Gq and the dashpot to a viscosity r). The behavior of the Maxwell element under harmonic oscillations can be obtained from the following equations ... 

To describe the combined bulk and Knudsen diffusion flrrxes the dusty gas model can be used [44] [64] [48] [49]. The dusty gas model basically represents an extension of the Maxwell-Stefan bulk diffusion model where a description of the Knudsen diffusion mechanisms is included. In order to include the Knudsen molecule - wall collision mechanism in the Maxwell-Stefan model originally derived considering bulk gas molecule-molecule collisions only, the wall (medium) molecules are treated as an additional pseudo component in the gas mixture. The pore wall medium is approximated as consisting of giant molecules, called dust, which are uniformly distributed in space and held stationary by an external clamping force. This implies that both the diffusive ffrrx and the concentration gradient with respect to the dust particles vanish. 

On the other hand, the more rigorous Maxwell-Stefan equations and the dusty gas model are seldom used in industrial reaction engineering applications. Nevertheless, the dusty gas model [64] represents a modern attempt to provide a more realistic description of the combined bulk and Knudsen diffusion mechanisms based on the multicomponent Maxwell-Stefan model formulation. Similar extensions of the Maxwell-Stefan model have also been suggested for the surface diffusion of adsorbed molecular pseudo-species, as well as the combined bulk, Knudsen and surface diffusion apparently with limited success [48] [49]. 

If the creep experiment described before is performed on the basis of this model, with a constant stress applied to the Maxwell mechanical element, the strain will be function of time, as indicated in Equation (21.11). 

The inadequacy of the mechanical model of light first became apparent when the electromagnetic equation of motion was seen to violate Galileo s principle of relative motion. As derived by Maxwell, electromagnetic motion is described by a wave equation ... 

IV. MECHANICAL MODELS FOR LINEAR VISCOELASTIC RESPONSE A. MAXWELL MODEL... 

The behavior of a polymer system is so complicated that we cannot represent it with the response time of a single Maxwell element. In other words, the simple model described above cannot approach the behavior of a real system. In 1893, Weichert showed that stress-relaxation experiments could be represented as a generalization of Maxwell s equation. The mechanical model according to Weichert s formulation is shown in Figure 3.11 it consists of a large number of Maxwell elements coupled in parallel. 

FIGURE 13.12 Stress-strain (a-e) behavior of two simple mechanical models (a) the Maxwell model and (b) the Voigt-Kelvin model. 

The rheological behavior of a viscoelastic material can be investigated by applying a small-amplitude sinusoidal deformation. The behavior can be described by a mechanical model, called the Maxwell model [33], consisting of an elastic spring with the Hookean constant, G , and a dashpot with the viscosity, r/<,. The variation of storage modulus (G ) and loss modulus (G") with shear frequency, O), are given by the equations... 

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