Magnesium applications

Barbour HM, Davidson W. Studies on measurement of plasma magnesium application of magon dye method to the Monarch centrifugal analyzer. Clin Chem 1988 34 2103-5. 

Anderson MW, Hrenak LA, Snyder DA. Advances in no cement colloidal silica bonded monolithic refractories for aluminium and magnesium applications. 13th Biennial Congress on Refractories, UMTECR. 2013 13 1177-82. 

Anhydrous magnesium sulphate. This is an excellent, neutral desiccating agent and is inexpensive. It is rapid in its action, chemically inert and fairly efficient, and can be employed for most compounds including those (esters, aldehydes, ketones, nitriles, amides, etc.) to which calcium chloride is not applicable. 

Alternative methods for its generation have made it possible to use benzyne as an intermediate m a number of synthetic applications One such method involves treating o bromofluorobenzene with magnesium usually m tetrahydrofuran as the solvent... 

Another sol—gel abrasive, produced by seeding with a-ferric oxide or its precursors, has been patented (30). A magnesium-modified version of this abrasive, also called Cubitron, is being produced as a replacement for the earlier type. Yttria [1314-36-91-vnc>A V eA sol—gel abrasives have also been patented (31), as well as rare earth oxide modified materials (32). These abrasives are all produced by 3M Corporation they have performed very well ia various applications such as ia coated abrasives for grinding stainless steel and exotic alloys. 

Magnesium Properties and Applications for Automobiles, SP962, Society of Automotive Engineers, Warrendale, Pa., 1993. 

Other Applications. Among other industrial uses of lime are causticizing agent in kraft (sulfate) paper (qv) plants recovery of ammonia (qv) from NH4CI (Solvay process) recovery of magnesium (qv) from seawater and brines via precipitation of Mg(OH)2 production of pesticides such as... 

S. Eu, R. C. Medmd, and 1. Y. Chan, "The Identification and Characterization of Calcium Magnesium Acetate," in Abstracts, International Symposium on Calcium Magnesium Acetate, An Emerging Bulk Chemicalfor Environmental Applications, May 14—16, Northeastern University, Boston, Mass., 1991. 

The transmetallation of lithio derivatives with either magnesium bromide or zinc chloride has been employed to increase further their range of synthetic application. While the reaction of l-methyl-2-pyrrolyllithium with iodobenzene in the presence of a palladium catalyst gives only a poor yield (29%) of coupled product, the yield can be dramatically improved (to 96%) by first converting the lithium compound into a magnesium or zinc derivative (Scheme 83) (81TL5319). 

MI Cables (mineral insulated cables. Fig. 10-181) are the electric heat tracers of choice for high-temperature applications. High-temperature applications are generally considered to maintain temperatures above 250°F or exposure temperatures above 420°F where self-regulating heaters cannot be used. MI cable consists of one or two heating wires, magnesium oxide insulation (from whence it gets its... 

COMBINED APPLICATION OF COMPOSITION AND STRUCTURE ANALYSIS METHODS TO THE DETERMINATION OF MAGNESIUM CONCENTRATION AND LOCATION IN BONE... 

Concentration limits of the diphosphate-ion, admissible to determination of magnesium and cobalt, manganese and cobalt, zinc and cobalt by spectrophotometric method with application of the l-(2-pyridylazo)-resorcinol (PAR) are presented. Exceeding maintenance of the diphosphate-ion higher admissible supposes a preliminary its separation on the anionite in the H+-form. The optimum conditions of cobalt determination and amount of the PAR, necessary for its full fastening are established on foundation of dependence of optical density of the cobalt complex with PAR from concentration Co + and pH (buffer solutions citrate-ammoniac and acetate-ammoniac). 

No fewer than 14 pure metals have densities se4.5 Mg (see Table 10.1). Of these, titanium, aluminium and magnesium are in common use as structural materials. Beryllium is difficult to work and is toxic, but it is used in moderate quantities for heat shields and structural members in rockets. Lithium is used as an alloying element in aluminium to lower its density and save weight on airframes. Yttrium has an excellent set of properties and, although scarce, may eventually find applications in the nuclear-powered aircraft project. But the majority are unsuitable for structural use because they are chemically reactive or have low melting points." ... 

The factor a varies considerably with individual alloys and is also dependent on the application conditions. It varies between wide limits from about 0.98 for zinc to below 0.5 for magnesium anodes. The a values given in Tables 6-1 to 6-4 apply to cold seawater. Deviations in application (i.e., cooling water) temperature and loading can lead to considerable changes. 

In the application of magnesium anodes for enamelled boilers, the consumption rate of the anodes is determined less by current supply than by self-corrosion. The calculation of life from data on protection current requirement, /, and anode mass, m, is difficult because the a value is so low. 

The range of applications for magnesium anodes includes the internal protection of boilers, feedwater tanks, filter tanks, coolers, pipe heat exchangers and condensers. They are mainly used in conjunction with coatings and where impressed current equipment is too expensive or cannot be installed. 

Fig. 22-1 Economic application range for cathodic protection with magnesium anodes or with impressed current.

For electrical insulation china clay is commonly employed whilst various calcium carbonates (whiting, ground limestone, precipitated calcium carbonate, and coated calcium carbonate) are used for general purpose work. Also occasionally employed are talc, light magnesium carbonate, barytes (barium sulphate) and the silicas and silicates. For flooring applications asbestos has been an important filler. The effect of fillers on some properties of plasticised PVC are shown in Figure 12.21 (a-d). 

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