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Liquid water medium

Fig. 1. Instantaneous configuration of a silver atom dark gray ball) in liquid water. Medium gray balls Oxygen atoms white balls hydrogen atoms. A isocontour of the 5 s electron of the silver atom is shown in light gray. The center of that orbital is 0.5 A away from the silver nucleus (for visualizing purposes this orbital center is displayed as a small light gray ball)... Fig. 1. Instantaneous configuration of a silver atom dark gray ball) in liquid water. Medium gray balls Oxygen atoms white balls hydrogen atoms. A isocontour of the 5 s electron of the silver atom is shown in light gray. The center of that orbital is 0.5 A away from the silver nucleus (for visualizing purposes this orbital center is displayed as a small light gray ball)...
Elevated pressures are required to keep water in the Hquid state. Liquid water cataly2es oxidation so that reactions proceed at relatively lower temperatures than would be required if the same materials were oxidi2ed in open flame combustion. At the same time, water moderates oxidation rates by providing a medium for heat transfer and removing excess heat by evaporation. [Pg.383]

Boilers are heat-transfer devices, wherein water, in the form of either liquid water or gaseous steam, is commonly employed as a medium for the transport of heat to some distant point of use. Although other heat-transfer mediums are sometimes utilized, water is particularly suitable because of its relative abundance, low cost, and high heat capacity. It is generally the medium of choice in most boiler applications, whether for domestic, commercial, institutional, or industrial purposes. [Pg.990]

The magnitude of the copigmentation is influenced by pH value, pigment and copigment concentrations, chemical structure of anthocyanin, temperature, and ionic strength of the medium. As to the effect of the solvent, the important issue is the hydrogen-bonded molecular structure of the liquid water, not the polarity of the medium. ... [Pg.265]

Sn/V/Nb/Sb/0 catalysts were prepared with the co-precipitahon technique, developed for the synthesis of ratile Sn02-based systems claimed by Rhodia (8). The preparation involved the dissoluhon of SnCl45H20, VO(acac)2, SbCh and NbCls in absolute ethanol, and by dropping the soluhon into a buffered aqueous soluhon maintained at pH 7. The precipitate obtained was separated from the liquid by filtrahon. The solid was then dried at 120°C and calcined in air at 700°C for 3 hours. The V/Sb/0 catalyst was prepared by means of the slurry method that consists in a redox reachon between Sb203 and NH4VO3 in water medium, for 18h at 95°C. The... [Pg.358]

Solids of different densities can be separated by immersing them in a fluid of intermediate density. The heavier solids sink to the bottom and the lighter float to the surface. Water suspensions of fine particles are often used as the dense liquid (heavy-medium). The technique is used extensively for the benefication (concentration) of mineral ores. [Pg.406]

An acoustic wave (sound) is a propagation of pressure oscillation in medium such as air or liquid water with the sound velocity [1]. Ultrasound is inaudible sound and its frequency of pressure oscillation is above 20 kHz (20,000 oscillations per second) [2]. For convenience, an acoustic wave above 10 kHz in frequency is sometimes called an ultrasonic wave. [Pg.1]

The hot liquid agar medium was mixed by magnetic stirring and cooled to 45 °C in a temperature-controlled water bath. Then the agar was poured into three Petri dishes and solidified by cooling to room temperature. [Pg.359]

What happens upon equilibration with liquid water instead of water vapor According to Equation (6.13), the capillary radius would go to infinity for PVP —> 1. Thus, in terms of external conditions, swelling would be thermodynamically unlimited, corresponding to the formation of an infinitely dilute aqueous solution of ionomer. However, the self-organized polymer is an effectively cross-linked elastic medium. Under liquid-equilibrated conditions, swelling is not controlled by external vapor... [Pg.378]

Liquid water arrives in the CCL via transport through the PEM or it is generated in the electrochemical reaction. Invariably, PEECs require a medium that is highly effective in transforming liquid water into water vapor otherwise, liquid water will clog pores and channels in gas diffusion layers and flow fields that are needed for the gaseous supply of reactants. [Pg.414]

To determine the saturation for any of the models, the capillary pressure must be known at every position within a diffusion medium. Hence, the two-phase models must determine the gas and liquid pressure profiles. In typical two-phase flow in porous media, the movement of both liquid and gas is determined by Darcy s law for each phase and eq 47 relates the two pressures to each other. Many models utilize the capillary pressure functionality as the driving force for the liquid-water flow... [Pg.460]

Processes (I) and (II) account for H20, whereas processes (I), (III), and (IV) describe the fate of e . According to Kaplan et al. [11], process (I) produces water molecules in high vibrational levels of their electronic ground state. The remaining H2O reacts with water to form H+q and OH in process (II). This ion-molecule reaction is known to occur in the gas phase with a rate constant of 8x10 dm mol sec [12], which, when extrapolated to liquid water, sets the lifetime of H20 in this medium at less than 10 " sec. However, Hamill [13] pointed out that H2O initially has the structure of a neutral water molecule so that it may migrate rapidly over distances of a few molecular diameters by resonant electron transfer with a succession of neighboring water molecules. [Pg.335]


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