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Light electric field

A renewed interest in this research field may lead to the construction of functional immobilized biocatalysts that surpass the conventional definition, or usually credited advantages, of immobilized biocatalysts with regard to their capabilities as catalysts [22-24], i.e. immobilized enzyme systems in which, for example, an enzymatic process can be controlled by externally applied stimuli such as light, electric fields, pH, temperature, and mechanical force. In such cases, what is crucial in system construction is not to rely on a possible... [Pg.159]

Use of this form for the polarizability tensor in equation (4.10) leads to the result that the dipole will not be oriented parallel to the incident electric field, as it is when the polarizability is isotropic. Additionally, inserting the resulting expression for the dipole into equation (4.8) will produce a much more complex angular dependence for the scattered light electric field. [Pg.56]

Figure 4.44 Illustration of energy- and angle-resolved two-electron emission following direct double photoionization in helium at 80 eV photon energy using linearly polarized light (electric field vector along the x-axis). Both electrons are detected in a plane perpendicular to the photon beam direction, the direction of one electron (ea) is fixed at a = 180°, = 150° and a = 90° (first, second and third columns in the figure), while... Figure 4.44 Illustration of energy- and angle-resolved two-electron emission following direct double photoionization in helium at 80 eV photon energy using linearly polarized light (electric field vector along the x-axis). Both electrons are detected in a plane perpendicular to the photon beam direction, the direction of one electron (ea) is fixed at a = 180°, = 150° and a = 90° (first, second and third columns in the figure), while...
A light quantum of appropriate energy can be absorbed by a molecule fixed in space only if the light electric field vector has a component parallel to the molecular transition moment. If the directions of the transition moment and of the electric field vector form an angle q), the absorption probability is proportional to cos tp. (Cf. Section 1.3.5.) The light quanta of luminescence are also polarized, with the intensity again proportional to cos (p. [Pg.272]

A considerable amount of work has been canied out on the fast decomposition of azides. This was initiated by heat, friction, impact, shock, light, electric field and atomic particles. [Pg.251]

As mention above, Eq. 3 is similar to the equation describing the transmittance of a Fabiy-Perot, except for the cosine at the numerator. As in Fabry-Perot filters, the multiple internal reflections in OLEDs induce, at some specific wavelengths, a resonance of the light electric-field intensity (or more accurately, the irradiance) distribution inside the OLED. [Pg.129]

Assuming that the amplitude of the light electric field changes during propagation in the x direction, then the electric field of the light, E, emitted by the forced oscillation of the nonlinear dielectric polarization is given by... [Pg.186]

Substituents on an aromatic ring induce a distortion in the -electron system, mostly via mesomeric effects. These induce changes in the light electric field and, consequently, influence the dielectric polarization P. In general terms, P can be expressed by Eq. (5.24). [Pg.189]

The material in this section is presented in terms of initiation by heat, friction, impact, shock, light, electric field, atomic particles, and so-called spontaneous processes. For many of these stimuli similar initiation mechanisms have been proposed. To avoid repetition in the various subsections, the more general mechanisms will be described first. In the case of initiation by the rapid collapse of gas pockets or voids, recent work on this topic will be described in some detail. [Pg.383]

Stationary hanging mercury drop electrodes (h.m.d.e.) are suitable for evaluating a slow equilibrium of adsorption and subsequent reduction. Solid metal or graphite electrodes are used mainly for oxidation. From the molecular biophysical point of view such measurements are performed for characterization of structural and conformational transitions caused by physical and electrochemical influences, such as heat, light, electrical fields, solvents, ions, and other ligands. In all cases, one can distinguish between reversible (allosteric and conformational modifications) and irreversible (denaturation, strand break, enzyme reactions) processes. Besides these investigations, biochemical analysis, clinical tests, and electrochemical synthesis are fruitful applications. [Pg.190]

Kumar and coworkers proposed a mechanism on the basis of the observation that an electric field component in the direction of mass flow was required (Yang et ah, 2006 Bian et al., 2000 Viswanathan et ah, 1999a Kumar et ah, 1998). This force is essentially an optical gradient force (Chaumet and Nieto-Vesperinas, 2000 Ashkin, 1997, 1970). Spatial variation of light (electric field intensity and orientation) leads to a variation of the material susceptibility, %, at the sample surface. The electric field then polarizes the material. The induced polarization is related to the light intensity and local susceptibility ... [Pg.162]

Smart polymers are macromolecular materials that change their properties and/or shape depending on their enviromnent and their surroundings. Some examples of environmental changes that can affect polymers are temperature, the presence of water, chemicals or analytes, pH changes, the presence/intensity of light, electrical fields, mechanical forces etc. [Pg.379]

Classically, the interaction of light with matter is described as the induction of dipoles by the light electric field, E ... [Pg.385]

The collapse consists in a strong decrease of the gel volume (by a factor of several tens or hundreds) in response to a small change in the enviroirmental conditions such as temperature, pH, various additives (thermodynamically poor solvent, surfactant, linear polymer), light, electric field, and magnetic field. [Pg.349]

Temperature Ionic strength Radiations/Light Electric field Mechanical stress Pressure Magnetic field Sonic radiation Solvents... [Pg.261]

Keywords Smart polymers Stimuli pH Light Electric field Magnetic field Ultrasound Temperature Ion Enzyme Glucose Hydrogels Nanotubes Films Membranes Nanoparticles Microparticles Micelles ... [Pg.341]

For light electric field along or perpendicular to Z, we need two and seven (i )pSTuv. ... [Pg.543]

What other impurities degrade BHJ function under the conditions of heat, light, electric field, and mechanical stress. [Pg.226]

The dipole strength of an induced electric dipole transition is proportional to the square of the matrix element in the dipole operator and therefore also to the square of the electric field at the lanthanide site. However, in intensity studies, the lanthanide ions are not in a vacuum, but embedded in a dielectric medium. The lanthanide ion in a dielectric medium not only feels the radiation field of the incident light, but also the field from the dipoles in the medium outside a spherical surface. The total field consisting of the electric field E of the incident light (electric field in the vacuum), plus the electric field of the dipoles is called the effective field eff> i e. the field effective in inducing the electric dipole transition. The square of the matrix element in the electric dipole operator has to be multiplied by a factor E fflEf. In a first approximation, ( efr/ = ( + 2) /9. The factor (n + 2fl9 is the Lorentz local field correction and accounts for dipole-dipole corrections. [Pg.117]

Dielectric constant Rotational diffusion coefficient Translational diffusion coefficient Mean value in the moment-ratio notation Electric field of light Electric field Geometric term in OPC Conductivity... [Pg.346]


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See also in sourсe #XX -- [ Pg.387 ]

See also in sourсe #XX -- [ Pg.167 ]




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