Layer laminar boundary

In the immediate vicinity of the solid wall, the turbulent fluctuations will be damped even in fully turbulent flow. In this thin layer adjacent to the wall, also known as the viscous sublayer, the viscous effect of the fluid outweighs that of its turbulent viscosity. 

We will now focus on heat and mass transfer in the laminar boundary layer of parallel flow on a plate. The flow is steady, dissipation is negligible and we will 

3 Convective heat and mass transfer. Single phase flow 

With regard to mass transfer we will restrict ourselves to a binary mixture with components that have approximately the same specific heat capacities, so that the energy equation remains valid in the form given above. In addition the continuity equation for a component holds 

As the material properties have been presumed to be independent of the temperature and composition, the velocity field is independent of the temperature and concentration fields, so the continuity and momentum equations can be solved independently of the energy and component continuity equations. 

Statement of the Blasius problem. We consider the steady-state problem on the longitudinal zero-pressure-gradient flow (VP = 0) past a half-infinite flat plate (0 X oo). We assume that the coordinates X and Y are directed along the plate and transverse to the plate, respectively, and the origin is placed at the front edge of the plate. The velocity of the incoming flow is U.  

Let us write out the final system of boundary layer equations for an incompressible fluid 

Equations (1.7.2) are written in a dimensional form, since there is no natural characteristic length in the problem. 

Exact solution. Friction coefficient. Following Blasius [43], we express the fluid velocity components via the stream function L according to (1.1.6) and substitute them into (1.7.2). Then we seek the stream function in the form 

We obtain the following boundary value problem for the function f(rj)  

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The phenomenon of concentration polarization, which is observed frequently in membrane separation processes, can be described in mathematical terms, as shown in Figure 30 (71). The usual model, which is weU founded in fluid hydrodynamics, assumes the bulk solution to be turbulent, but adjacent to the membrane surface there exists a stagnant laminar boundary layer of thickness (5) typically 50—200 p.m, in which there is no turbulent mixing. The concentration of the macromolecules in the bulk solution concentration is c,. and the concentration of macromolecules at the membrane surface is c. 

At any point within the boundary layer, the convective flux of the macromolecule solute to the membrane surface is given by the volume flux,/ of the solution multipfled by the concentration of retained solute, c. At steady state, this convective flux within the laminar boundary layer is balanced by the diffusive flux of retained solute in the opposite direction. This balance can be expressed by equation 1 ... 

I. Turbulent, local flat plate, natural convection, vertical plate Turbulent, average, flat plate, natural convection, vertical plate Nsk. = — = 0.0299Wg=Ws = D x(l + 0.494W ) )- = 0.0249Wg=W2f X (1 + 0.494WE )- [S] Low solute concentration and low transfer rates. Use arithmetic concentration difference. Ncr > 10 " Assumes laminar boundary layer is small fraction of total. D [151] p. 225... 

However, the transition Reynolds number depends on free-stream turbulence and may range from 3 X 10 to 3 X lO ". The laminar boundary layer thickness 8 is a function of distance from the leading edge ... 

Cylindrical Boundary Layer Laminar boundary layers on cylindrical surfaces, with flow parallel to the cylinder axis, are described by Glauert and LighthiU Proc. R. Soc. [London], 230A, 188-203 [1955]), Jaffe and Okamura (Z. Angety. Math. Phys., 19, 564—574 [1968]) and Stewartson ((J. Appl Math., 13, 113-122 [1955]). For a turbulent boundaiy layer, the total drag may be estimated as... 

Continuous Flat Surface Boundaiy layers on continuous surfaces drawn through a stagnant fluid are shown in Fig. 6-48. Figure 6-48 7 shows the continuous flat surface (Saldadis, AIChE J., 7, 26—28, 221-225, 467-472 [1961]). The critical Reynolds number for transition to turbulent flow may be greater than the 500,000 value for the finite flat-plate case discussed previously (Tsou, Sparrow, and Kurtz, J. FluidMech., 26,145—161 [1966]). For a laminar boundary layer, the thickness is given by... 

The laminar boundary layer on deforming continuous surfaces with velocity varying with axial position is discussed by Vleggaar... 

In a laminar boundary layer, no mixing takes place and the flow is parallel. In this case the heat transfer occurs mainly by conduction through the boundary layer. 

The preceding discussion has attempted to formulate the situation for laminar boundary layer flow as accurately as possible and to obtain precise correlation between the heat transfer and mass transfer factors. 

Wetted wall column An experimental apparatus used to determine the mass transfer that takes place through laminar boundary layers. 

This form of attack, especially as affecting copper alloys in sea water, has been widely studied since the pioneer work of Bengough and May . Impingement attack of sea water pipe and heat exchanger systems is considered in Sections 1.6 and 4.2. In such engineering systems the water flow is invariably turbulent and the thickness of the laminar boundary layer is an important factor in controlling localised corrosion. 

Equation 11.12 corresponds closely to experimentally determined velocity profiles in a laminar boundary layer. 

Collatz, G. Ball, J. T., Grivet, C. and Berry, J. A. (1991). Physiological and environmental regulation of stomatal conductance, photosynthesis, and transpiration a model that includes a laminar boundary layer, Agric. For. Meteorol. 54,107-136. 

To describe the velocity profile in laminar flow, let us consider a hemisphere of radius a, which is mounted on a cylindrical support as shown in Fig. 2 and is rotating in an otherwise undisturbed fluid about its symmetric axis. The fluid domain around the hemisphere may be specified by a set of spherical polar coordinates, r, 8, , where r is the radial distance from the center of the hemisphere, 0 is the meridional angle measured from the axis of rotation, and (j> is the azimuthal angle. The velocity components along the r, 8, and (j> directions, are designated by Vr, V9, and V. It is assumed that the fluid is incompressible with constant properties and the Reynolds number is sufficiently high to permit the application of boundary layer approximation [54], Under these conditions, the laminar boundary layer equations describing the steady-state axisymmetric fluid motion near the spherical surface may be written as ... 

The application of RHSE is primarily in the laminar boundary layer flow regime of Re < 15000, where the edge effect is negligible and the mass transfer theory has been confirmed by experimental investigations. An important consideration in the design of a practical RHSE system is to conform to the theoretical requirement that the boundary layer thickness be thin in comparison to the radius of the RHSE (<5 a). 

Fig. 4. Migration contribution to the limiting current in acidified CuS04 solutions, expressed as the ratio of limiting current (iL) to limiting diffusion current (i ) r = h,so4/(( h,so, + cCuS(>4). "Sulfate refers to complete dissociation of HS04 ions. "bisulfate" to undissociated HS04 ions. Forced convection" refers to steady-state laminar boundary layers, as at a rotating disk or flat plate free convection refers to laminar free convection at a vertical electrode penetration to unsteady-state diffusion in a stagnant solution. [F rom Selman (S8).]...

Quite new ideas for the reactor design of aqueous multiphase fluid/fluid reactions have been reported by researchers from Oxeno. In packed tubular reactors and under unconventional reaction conditions they observed very high space-time yields which increased the rate compared with conventional operation by a factor of 10 due to a combination of mass transfer area and kinetics [29]. Thus the old question of aqueous-biphase hydroformylation "Where does the reaction takes place " - i.e., at the interphase or the bulk of the liquid phase [23,56h] - is again questionable, at least under the conditions (packed tubular reactors, other hydrodynamic conditions, in mini plants, and in the unusual,and costly presence of ethylene glycol) and not in harsh industrial operation. The considerable reduction of the laminar boundary layer in highly loaded packed tubular reactors increases the mass transfer coefficients, thus Oxeno claim the successful hydroformylation of 1-octene [25a,26,29c,49a,49e,58d,58f], The search for a new reactor design may also include operation in microreactors [59]. 

The boundary layer thickness gradually increases until a critical point is reached at which there is a sudden thickening of the boundary layer this reflects the transition from a laminar boundary layer to a turbulent boundary layer. For both types, the flow outside the boundary layer is completely turbulent. In that part of the boundary layer near the leading edge of the plate the flow is laminar and consequently this is known as a... 

Figure 4 Hydrodynamic boundary layer development on the semi-infinite plate of Prandtl. <5D = laminar boundary layer, <5t = turbulent boundary layer, /vs = viscous turbulent sub-layer, <5ds = diffusive sub-layer (no eddies are present solute diffusion and mass transfer are controlled by molecular diffusion—the thickness is about 1/10 of <5vs)> B = point of laminar—turbulent transition. Source From Ref. 10.

In terms of hydrodynamics, the boundary layer thickness is measured from the solid surface (in the direction perpendicular to a particle s surface, for instance) to an arbitrarily chosen point, e.g., where the velocity is 90-99% of the stream velocity or the bulk flow ((590 or (599, respectively). Thus, the breadth of the boundary layer depends ad definitionem on the selection of the reference point and includes the laminar boundary layer as well as possibly a portion of a turbulent boundary layer. 

Apart from the nature of the bulk flow, the hydrodynamic scenario close to the surfaces of drug particles has to be considered. The nature of the hydrodynamic boundary layer generated at a particle s surface may be laminar or turbulent regardless of the bulk flow characteristics. The turbulent boundary layer is considered to be thicker than the laminar layer. Nevertheless, mass transfer rates are usually increased with turbulence due to the presence of the viscous turbulent sub-layer. This is the part of the (total) turbulent boundary layer that constitutes the main resistance to the overall mass transfer in the case of turbulence. The development of a viscous turbulent sub-layer reduces the overall resistance to mass transfer since this viscous sub-layer is much narrower than the (total) laminar boundary layer. Thus, mass transfer from turbulent boundary layers is greater than would be calculated according to the total boundary layer thickness. 

As mentioned, a laminar boundary layer separates a greater distance from the surface of a curved body than a turbulent one. The laminar boundary layer in the upper photograph of Figure 5 is shown separating from the crest... 

There are several resistances which may hinder the movement of a molecule of adsorbate from the bulk fluid outside a pellet to an adsorption site on its internal surface, as shown in Figure 17.15. Some of these are sequential and have to be traversed in series, whilst others derive from possible parallel paths. In broad terms, a molecule, under the influence of concentration gradients, diffuses from the turbulent bulk fluid through a laminar boundary layer around a solid pellet to its external surface. It then diffuses, by various possible mechanisms, through the pores or the lattice vacancies in the pellet until it is held by an adsorption site. During desorption the process is reversed. 

There have been many studies of the effect of boundary films on mass and heat transfer to single pellets and in packed beds, including the work of Ranz and Marshall 27 and Dwivedi and Upadhey(28). Other theories of mass and heat transfer are discussed in Volume 1, Chapter 10, although only the steady-state film-theory is considered here. It is assumed that the difference in concentration and temperature between the bulk fluid and the external surface of a pellet is confined to a narrow laminar boundary-layer in which the possibility of accumulation of adsorbate or of heat is neglected. 

Reactions carried in aqueous multiphase catalysis are accompanied by mass transport steps at the L/L- as well as at the G/L-interface followed by chemical reaction, presumably within the bulk of the catalyst phase. Therefore an evaluation of mass transport rates in relation to the reaction rate is an essential task in order to gain a realistic mathematic expression for the overall reaction rate. Since the volume hold-ups of the liquid phases are the same and water exhibits a higher surface tension, it is obvious that the organic and gas phases are dispersed in the aqueous phase. In terms of the film model there are laminar boundary layers on both sides of an interphase where transport of the substrates takes place due to concentration gradients by diffusion. The overall transport coefficient /cl can then be calculated based on the resistances on both sides of the interphase (Eq. 1) ... 

FIGURE7-1 Schematic of flow in daughter brandies of bifurcation model for steady inspiratory flow with flat profile in parent bran<. Velocity profiles in plane of bifurcation (—) and in normal plane (—) are indicated in right branch. Orientation of secondary flows and position of laminar boundary layer are shown in left branch. Redrawn wifo permisnon from Bdl. ... 

The burner in the test facility, shown in Fig. 18.1, is an axisymmetric nozzle, which is concentrically placed into the circular suction collar. To achieve a top-hat velocity profile with laminar boundary layer at the nozzle exit, a fourth order polynomial with a large contraction ratio of 31.6 1 and an exit diameter of D = 10.16 mm is used in the design. The suction collar assembly is connected to a vacuum pump through a series of solenoid valves so that a counterflow, which is in the opposite direction of the fuel-air mixture flow, can be established... 

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