Radioactive isotope, number

An isotope of hydrogen a stable, non-radioactive isotope atomic number 1 atomic mass 2.014 molecular weight (for the diatomic heavy hydrogen molecule) 4.028. 

Symbol Pu atomic number 94 atomic weight 244 an actinide series transuranium element a man-made radioactive element electron configuration [Rn]5/ 7s2 partially filled f suhsheU valence states +3, +4, -i-5, +6 eighteen isotopes in the mass range 228-230, 232-246 aU isotopes radioactive the longest lived isotope Pu-244, ti/2 8.2x10 year the shortest hved isotope Pu-233, ti/2 20.9 minute. 

In this chapter, we introduced the constituents and structure of the atom and showed that elements typically have several isotopes (same number of protons but different numbers of neutrons). Using the Chart of the Nuclides, we briefly discussed the distribution and stability of the isotopes. Radioactive isotopes were introduced, and we mentioned that they can be used for dating of geological and cosmochemical events. We then discussed the periodic... 

BERKELIUM. [CAS 7440-40-6]. Chemical element, symbol Bk, at. no. 97, at wt. 247 (mass number of the most stable isotope), radioactive metal of the Actinide series, also one of the Transuranium elements. All isotopes of berkelium are radioactive all must be produced synthetically. The element was discovered by G.T. Seaborg and associates at the Metallurgical Laboratory of the University of Chicago in 1949. At that time, the dement was produced by bombarding 241 Am with helium ions. 4i Bk is an alpha-emitter and may be obtained by alpha-bombardment of ,4Cm. 245Cm. or 246Ciu. Ollier nuclides include those of mass numbers 243—246 and 248-250. Probable electronic configuration ... 

EINSTENIUM. CAS 7429-92-71. Chemical element symbol Es, at. no. 99. at. wt. 254 (mass number of the most stable isotope), radioactive metal of the Actinide series, also one of the Transuranium elements. Both einsteinium and fermium were formed tit a thermonuclear explosion that occurred in the South Pacific in 1952. The elements were identified by scientists from the University of California s Radiation Laboratory- the Argonnc National Laboratory, and the I. os Alamos Scientific Laboratory. It was observed that very heavy uranium isotopes which resulted from the action of the instantaneous neutron dux on uranium (contained in the explosive device) decayed to form Es and Fm. The probable electronic configuration of Es is... 

NEPTUNIUM. [CAS 7439-99-8]. Chemical element, symbol Np, at. no, 93, at. wt, 237,0482 (predominant isotope), radioactive metal of the Actinide series, also one of the Transuranium elements. Neptunium was the first of [he Transuranium elements [o be discovered and was first produced by McMillan and Abelson (1940) at the University of California at Berkeley. This was accomplished by bombarding uranium with neutrons. Neptunium is produced as a by-pruduct from nuclear reactors. 237Np is the most stable isotope, with a half-life of 2.20 x 106 years, The only other very long-lived isotope is that of mass number 236. with a half-life of 5 x 10- years. 

Chromium has the atomic number 24. Of the 13 known isotopes (mass numbers 45-57), four are stable, giving chrominm the relative atomic mass 51.9961 ( C = 12.0000). Table 1 lists the properties of some isotopes. Cr may be used for NMR spectroscopy however, its relative receptivity (8.62 x 10 , H= 1.00), quadmpole moment (4.1 x 10 ° m ), and low resonance frequency (16.956MHz, H = 300MHz) pose experimental difficulties. Radioactive Cr is used in medical tracer studies. 

When you write nuclear equations, it is important to indicate which isotopes of the given elements you are dealing with. For example, the element carbon has natural isotopes with three different atomic masses carbon-12, carbon-13, and carbon-14. Two of these, carbon-12 and carbon-13, are stable isotopes and are not radioactive. However, carbon-14 is unstable and radioactive. There must be some way to distinguish between these isotopes in nuclear equations. To do this, you write the mass number as a superscript and atomic number as a subscript in the symbol for an isotope. These numbers are both placed to the left of the symbol for the element. So, the three isotopes of carbon are represented as C, C, and... 

Q1, Americium Am at. wt (most stable isotope) 243 at no. 95 valence 3 4, 5, 6, Completely man-made element. Isotopes (mass numbers) 237-246 all are radioactive, First isotope prepared (Tw 458 years a-emit ... 

The radioactive decay of an unstable nucleus is a random process. In any given interval of time, there is a well-defined probability that a given nucleus will decay. This probability is independent of time and is the same for aU nuclei of a given type, but is different for different isotopes. The number of nuclei decaying per unit time is the rate of nuclear decay (or activity), which can be measured using devices, such as the Geiger-Mueller counter (Figure 17.4). 

Some atomic masses of elements in the periodic table are in parentheses. These elements are radioactive, and there is no atomic mass in the sense that we have defined it. Instead, parentheses enclose the mass number of the most stable isotope. Radioactivity is discussed in Chapter 20, Nuclear Chemistry. 

All elements of atomic number greater than 83 exhibit radioactive decay K, Rb, Ir and a few other light elements emit p particles. The heavy elements decay through various isotopes until a stable nucleus is reached. Known half-lives range from seconds to 10 years. 

Atoms with the same number of protons but a different number of neutrons are called isotopes. To identify an isotope we use the symbol E, where E is the element s atomic symbol, Z is the element s atomic number (which is the number of protons), and A is the element s atomic mass number (which is the sum of the number of protons and neutrons). Although isotopes of a given element have the same chemical properties, their nuclear properties are different. The most important difference between isotopes is their stability. The nuclear configuration of a stable isotope remains constant with time. Unstable isotopes, however, spontaneously disintegrate, emitting radioactive particles as they transform into a more stable form. 

The most important types of radioactive particles are alpha particles, beta particles, gamma rays, and X-rays. An alpha particle, which is symbolized as a, is equivalent to a helium nucleus, fHe. Thus, emission of an alpha particle results in a new isotope whose atomic number and atomic mass number are, respectively, 2 and 4 less than that for the unstable parent isotope. 

The time required for half of the initial number of a radioactive isotope s atoms to disintegrate (ti/2). 

Direct Analysis of Radioactive Analytes The concentration of a long-lived radioactive isotope is essentially constant during the period of analysis. As shown in Example 13.6, the sample s activity can be used to calculate the number of radioactive particles that are present. 

Other isotopes can be used to determine the age of samples. The age of rocks, for example, has been determined from the ratio of the number of radioactive atoms to the number of stable gfPb atoms produced by radioactive decay. For rocks that do not contain uranium, dating is accomplished by comparing the ratio of radioactive fgK to the stable fgAr. Another example is the dating of sediments collected from lakes by measuring the amount of g Pb present. 

Isotopes of an element are formed by the protons in its nucleus combining with various numbers of neutrons. Most natural isotopes are not radioactive, and the approximate pattern of peaks they give in a mass spectrum can be used to identify the presence of many elements. The ratio of abundances of isotopes for any one element, when measured accurately, can be used for a variety of analytical purposes, such as dating geological samples or gaining insights into chemical reaction mechanisms. 

Natural radioactive processes in themselves give rise to changes of one element into another. Emission of an alpha particle reduces the atomic number of an element by two units, and emission of a beta particle increases the atomic number by one unit. Thus, for isotopes of elements near... 

Ratios of lead isotopes depend on the source of the lead. They vary because lead is an end product of radioactive decay from elements of greater atomic number. 

Plutonium (Pu) is an artificial element of atomic number 94 that has its main radioactive isotopes at 2 °Pu and Pu. The major sources of this element arise from the manufacture and detonation of nuclear weapons and from nuclear reactors. The fallout from detonations and discharges of nuclear waste are the major sources of plutonium contamination of the environment, where it is trapped in soils and plant or animal life. Since the contamination levels are generally very low, a sensitive technique is needed to estimate its concentration. However, not only the total amount can be estimated. Measurement of the isotope ratio provides information about its likely... 

Each of the elements has a number of isotopes (2,4), all radioactive and some of which can be obtained in isotopicaHy pure form. More than 200 in number and mosdy synthetic in origin, they are produced by neutron or charged-particle induced transmutations (2,4). The known radioactive isotopes are distributed among the 15 elements approximately as follows actinium and thorium, 25 each protactinium, 20 uranium, neptunium, plutonium, americium, curium, californium, einsteinium, and fermium, 15 each herkelium, mendelevium, nobehum, and lawrencium, 10 each. There is frequently a need for values to be assigned for the atomic weights of the actinide elements. Any precise experimental work would require a value for the isotope or isotopic mixture being used, but where there is a purely formal demand for atomic weights, mass numbers that are chosen on the basis of half-life and availabiUty have customarily been used. A Hst of these is provided in Table 1. 

Lead, atomic number 82, is a member of Group 14 (IVA) of the Periodic Table. Ordinary lead is bluish grey and is a mixture of isotopes of mass number 204 (15%), 206 (23.6%), 207 (22.6%), and 208 (52.3%). The average atomic weight of lead from different origins may vary as much as 0.04 units. The stable isotopes are products of decay of three naturally radioactive elements (see Radioactivity, natural) comes from the uranium series (see Uraniumand... 

Plutonium [7440-07-5] Pu, element number 94 in the Periodic Table, is a member of the actinide series and is metaUic (see Actinides and transactinides). Isotopes of mass number 232 through 246 have been identified. AH are radioactive. The most important isotope is plutonium-239 [15117-48-3] Pu also of importance are Pu, Pu, and Pu. 

AH of the 15 plutonium isotopes Hsted in Table 3 are synthetic and radioactive (see Radioisotopes). The lighter isotopes decay mainly by K-electron capture, thereby forming neptunium isotopes. With the exception of mass numbers 237 [15411-93-5] 241 [14119-32-5] and 243, the nine intermediate isotopes, ie, 236—244, are transformed into uranium isotopes by a-decay. The heaviest plutonium isotopes tend to undergo P-decay, thereby forming americium. Detailed reviews of the nuclear properties have been pubUshed (18). 

Any radioactive nucUde or isotope of an element can be used as a radioactive tracer, eg, chromium-51 [14392-02-0] cobalt-60 [10198-40-0] tin-110 [15700-33-1] and mercury-203 [13982-78-0],hut the preponderance ofuse has been for carbon-14 [14762-75-5],hydj ogen-3 [10028-17-8] (tritium), sulfur-35 [15117-53-0], phosphoms-32, and iodine-125 [14158-31 -7]. More recendy phosphoms-33 has become available and is used to replace sulfur-35 and phosphoms-32 in many appUcations. By far the greater number of radioactive tracers produced are based on carbon-14 and hydrogen-3 because carbon and hydrogen exist in a large majority of the known natural and synthetic chemical compounds. 

Decay products of the principal radionuclides used in tracer technology (see Table 1) are not themselves radioactive. Therefore, the primary decomposition events of isotopes in molecules labeled with only one radionuclide / molecule result in unlabeled impurities at a rate proportional to the half-life of the isotope. Eor and H, impurities arising from the decay process are in relatively small amounts. Eor the shorter half-life isotopes the relative amounts of these impurities caused by primary decomposition are larger, but usually not problematic because they are not radioactive and do not interfere with the application of the tracer compounds. Eor multilabeled tritiated compounds the rate of accumulation of labeled impurities owing to tritium decay can be significant. This increases with the number of radioactive atoms per molecule. 

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