Isotopes ocean water

SMOW. standard mean ocean water (a standard for oxygen and hydrogen isotopes)... 

Eig. 4. The bulk oxygen isotopic composition of different meteorite classes where (—) is the terrestial fractionation line. The 5 notation refers to the normalized difference between or ratios to those in standard mean ocean water (SMOW) in relative units of parts per thousand. The... 

Thorinm-232 is the only non-radiogenic thorium isotope of the U/Th decay series. Thorinm-232 enters the ocean by continental weathering and is mostly in the particulate form. Early measurements of Th were by alpha-spectrometry and required large volume samples ca. 1000 T). Not only did this make sample collection difficult, but the signal-to-noise ratio was often low and uncertain. With the development of a neutron activation analysis " and amass spectrometry method " the quality of the data greatly improved, and the required volume for mass spectrometry was reduced to less than a liter. Surface ocean waters typically have elevated concentrations of dissolved and particulate 17,3 7,62... 

The amounts of the standard isotopic species and the tracer isotopic species are represented by X and X for the sample and the reference material. The reference substance is chosen arbitrarily, but is a substance that is homogeneous, available in reasonably large amounts, and measurable using standard analytical techniques for measuring isotopes (generally mass spectrometry). For instance, a sample of ocean water known as Standard Mean Ocean Water (SMOW) is used as a reference for and 0. Calcium carbonate from the Peedee sedimentary formation in North Carolina, USA (PDB) is used for C. More information about using carbon isotopes is presented in Chapter 11. 

The global atmospheric circulation acts as an enormous filtration system, which depletes high-latitude precipitation of heavy isotope-bearing water molecules. Because of this system, measurements of the stable isotopic composition of the ice sheets and of ocean-floor sediments reveal very important paleo-environmental information (see Sections 18.2.2,18.3.2, and 18.3.3). Here we examine this filtration system at a physical level. This system was first understood by a great Danish geochemist named Willi Dansgaard (Dansgaard, 1964). 

Min GR, Edwards RL, Taylor FW, Recy J, Gallup CD, Beck JW (1995) Annual cycles of U/Ca in corals and U/Ca thermometry. Geochim Cosmochim Acta. 59 2025-2042 Moore WS (1981) The thorium isotope content of ocean water. Earth Planet Sci Lett 53 419-426 Moran SB, Hoff JA, Edwards RL, Landing WM (1997) Distribution of Th-230 in the Laborador Sea and its relation to ventilation. Earth Planet Sci Lett 150 151-160 Muhs DR, Simmons KR, Steinke B (2002) Timing and warmth of the Last Interglacial period new U-series evidence from Hawaii and Bermuda and a new fossil compilation for North America. Qrrat Sci Rev 21 1355-1383... 

Kharkar DP, Thomson J, Turekian KK, Forster WO (1976) Uranium and thorium series nuclides in plankton from the Caribbean. Limnol Oceanogr 21 294-299 Krishnaswami S, Lai D, Somayajulu BLK, Weiss R, Craig H (1976) Large-volume in situ filtration of deep Pacific waters mineralogical and radioisotope studies. Earth Planet Sci Lett 32 420-429 Livingston HD, Cochran JK (1987) Determination of transuranic and thorium isotopes in ocean water in solution and in filterable particles. J Radioanal Nucl Chem 115 299-308 Masque P, Sanchez-Cabeza JA, Braach JM, Palacios E, Canals M (2002) Balance and residence times of °Pb and 4 o in surface waters of the northwestern Mediterranean Sea. Cont Shelf Res 22 2127-2146 Matsumoto E (1975) Th-234-U-238 radioactive disequilibrium in the surface layer of the oceans. Geochim Cosmochim Acta 39 205-212... 

As a guide to the evolutionary history of the continents, Patterson decided to measure the lead isotope ratios of Earth s crust as a whole. As rocks erode, their minerals are collected and mixed in the oceans, where they eventually settle in layers of sediment. Patterson organized a formidable series of experiments to measure the lead isotopes on land, in various layers of ocean water, and in sediments on the sea floor. 

SMOW Acronym for Standard Mean Ocean Water, used as a chemical and isotopic reference standard, for example, when studying oxygen isotope ratios. soap A cleaning agent made by the reaction of an oil or fat with an alkali such as soda. 

Elderfield and Greaves [629] have described a method for the mass spectromet-ric isotope dilution analysis of rare earth elements in seawater. In this method, the rare earth elements are concentrated from seawater by coprecipitation with ferric hydroxide and separated from other elements and into groups for analysis by anion exchange [630-635] using mixed solvents. Results for synthetic mixtures and standards show that the method is accurate and precise to 1% and blanks are low (e.g., 1() 12 moles La and 10 14 moles Eu). The method has been applied to the determination of nine rare earth elements in a variety of oceanographic samples. Results for North Atlantic Ocean water below the mixed layer are (in 10 12 mol/kg) 13.0 La, 16.8 Ce, 12.8 Nd, 2.67 Sm, 0.644 Eu, 3.41 Gd, 4.78 Dy, 407 Er, and 3.55 Yb, with enrichment of rare earth elements in deep ocean water by a factor of 2 for the light rare earth elements, and a factor of 1.3 for the heavy rare earth elements. 

Sharama et al. [479] compared results obtained in the determination of cobal-amins in ocean waters by radioisotope dilution and bioassay techniques. These workers showed that the isotopic methods measured both biologically active and inactive cobalamins indiscriminately when porcine factor was used as the B12-specific binder. 

When our measured, listed, and published, isotope measurements, referred to wood of 1712 - 1714, are referred instead to ocean water (smow), then 6Dsmow and S- g(smow) are related to each... 

Oxygen isotopes were analyzed using the technique of Clayton and Mayeda (69). Data are presented using the standard 6 notation relative to Standard Mean Ocean Water (SMOW). 

Although ocean water is well mixed with respect to Li, and many laboratories measure Li isotopes in seawater, the range in values reported in the literature (8 Li = +29.3 to +33) cast some uncertainty on this reservoir. As precision of analytical methods improves, a check of the viability of the seawater standard should be carried out. 

Bruland KW, Odonat JR, Hutchins DA (1991) Interactive influences of bioactive trace metals on biological production in oceanic waters. Limnol Oceanography 36 1555-1577 Bullen TD, White AE, Childs CW, Vivet DV, Schultz MS (2001) Demonstration of significant abiotic iron isotope fractionation in nature. Geology 29 699-702... 

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