Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Ion improved

The withdrawn hquid-phase samples were analyzed with an HPLC (Biorad Aminex HPX-87C carbohydrate coluttm. 1.2 ttiM CaS04 in deionized water was used as a mobile phase, since calcium ions improve the resolution of lactobionic acid [17]). Dissolved metals were analysed by Direct Current Plasma (DCP). The catalysts were characterized by (nitrogen adsorption BET, XPS surface analysis, SEM-EDXA, hydrogen TPD and particle size analysis). [Pg.105]

The secondary ion yield depends both on the energy and the nature of the primary ions. It has been demonstrated that the use of clusters instead of monoatomic ions improves the secondary yield. Classical primary ions, like Ga+ and Cs+, are increasingly replaced by Au3+, Bi3+ or C60+ which has permitted great progress in organic ToF-SIMS studies [Kollmer 2004, Touboul et al. 2004, Winograd 2005]. [Pg.434]

II) complexes. This method was also successfully applied to chemically derivatized GAGs that cannot be depolymerized by enzymes [62]. Similarly, capillary electrophoresis (CE) can be used for digested GAGs that are then detected by ultraviolet spectroscopy or mass spectrometry. Complexation of GAGs using copper (II) ions improved the sensitivity. However, complete separation of intact GAGs was not feasible by CE and most methods still rely on enzymatic or chemical depolymerization prior to analysis [46]. [Pg.321]

A Rh on Si02 catalyst promoted with V and Sm showed similar improvements in catalyst performance.522 Sm3+ ions improve the dispersion of Rh and increase CO and H2 uptakes, enhancing the formation of acetaldehyde and acetic acid. Lower-valence V ions have a good H2 storage capacity, thereby increasing the hydrogenation ability of the catalyst and promoting the formation of ethanol. [Pg.127]

Age thickening is a common defect of UHT sterile milk concentrate, which has received less drastic heat treatment than conventionally sterilized evaporated milk (Harwalker 1982). Age thickening is promoted by high milk solids content, addition of alkali to raise the pH, and addition of citrate, phosphate, and other anions that lower the Ca ion activity. Conversely, addition of Ca ions improves stability of the product against age thickening. [Pg.755]

The resulting fit, with the nearest 1355 ions, improved considerably on earlier efforts, and was especially good for the zero field splitting (within 0.01cm 1) and the 2E components (within 10 cm-1). Table 1 presents a comparison of calculated and experimental values for the transitions within the (t2g)3 configuration. [Pg.127]

Release cells with 0.25% trypsin in PBS or BSS (the divalent ions improve plating efficiency) and disperse by gently pipetting up and down the minimum number of times. Trypsinisation at 4°C for 2-10 min has been recommended especially for cloning cells in low serum. [Pg.118]

Table I represents the weight variation in each experimental step and dehumidification efficiencies of the adsorbent-impregnated ceramic sheets. The interesting thing was that the dehumidification efficiency increased in a sequence of silica, magnesium silicate, aluminum silicate and titanium silicate-impregnated ceramic sheets. It is evident that the incorporation of aluminum and titanium ions improved the dehumidification efficiency of silica gel-based adsorbent, but the incorporation of Mg ions doesn t affect the dehumidification efficiency of silica gel-based adsorbent. Table I represents the weight variation in each experimental step and dehumidification efficiencies of the adsorbent-impregnated ceramic sheets. The interesting thing was that the dehumidification efficiency increased in a sequence of silica, magnesium silicate, aluminum silicate and titanium silicate-impregnated ceramic sheets. It is evident that the incorporation of aluminum and titanium ions improved the dehumidification efficiency of silica gel-based adsorbent, but the incorporation of Mg ions doesn t affect the dehumidification efficiency of silica gel-based adsorbent.
Electrodialysis has been examined [26] at the Japan Atomic Energy Research Institute (JAERI) for the removal of radioactive ions from low- and intermediate-level radioactive liquid waste using inactive coexisting salts as ionic carriers of very small amounts of radioactive ions. It has been found that the nature and the concentration of the existing salt species generally do not influence the decontamination factor obtained for radioactive ions. The efficiency for the decontamination of radioactive ions has been found to be higher for lower valence cations. It has also been observed that addition of inactive coexisting salt ions improves the decontamination factor but lowers the extent of volume reduction achievable. [Pg.838]

Pihko, P. M., Sale, T. M. Excess sodium ions improve Z selectivity in Horner-Wadsworth-Emmons olefinations with the Ando phosphonate. Tetrahedron Lett. 2003, 44,4361-4364. [Pg.604]

Fig. 3 shows the DNB mass spectrum for using femtosecond laser pulses. Throughout our studies, the use of ultrafast ionization produces mass spectra with fragmentation patterns characteristic of individual molecules being investigated. In addition, the presence of the parent molecular ion improves the prospects for molecule-specific identification. [Pg.419]

The ability of metal ions to modify the texture of fruit and vegetable tissue has been studied since 1939, when Kertesz (l) found that calcium ions improved the firmness of tomatoes. A very simplified generalization of the effects of metal ions on fruit and vegetable texture is that monovalent cations, usually Na+ and K, cause tissue softening. Examples of this softening effect include results with peas (2.31, dried peas (4), carrots (5), potatoes (6) and green beans (7). On the other hand calcium, a divalent cation,... [Pg.125]

As with the penicillins, various molecular changes in the cephalosporin can improve in vitro stability, antibacterial activity, and stability toward 3-lactamases. The addition of an amino and a hydrogen to the a and a position, respectively, results in a basic compound that is protonated under the acidic conditions of the stomach. The ammonium ion improves the stability of the P-lactam of the cephalosporin, leading to orally active drugs. [Pg.1610]

The most popular mobile phases for the separation of the leukotrienes all contain methanol for example, a mobile phase of methanol-water-acetic acid-ammonium hydroxide (67 33 0.08 0.04), pH 6.2 in combination with an ODS column was used to resolve leukotrienes B4, C4, W-trans-C and D4 in the elution order given (Metz et al., 1982) (Fig. 11.5.4). Under these conditions, the major leukotrienes were well resolved from the diHETEs which are often co-synthesised in in vitro test systems. The addition of acetic acid and ammonium hydroxide to the mobile phase is reported to maximise the sharpness of the eluting peaks and enhance the reproducibility of k and a values (Metz et al., 1982). The mechanisms by which the ammonium and acetate ions improve chromatography was postulated to be through ion-pairing of the free carboxyl and amino functions on leukotrienes C4 and D4. [Pg.240]

As mentioned earlier, antimony ions are incorporated into the structure of Pb02 particles. Most probably, these ions enter the gel zones of the particles and contribute to binding the polymer chains to one another. Antimony ions improve the connections between the linear chains that form a network. A schematic representation of these connections is presented in Fig. 10.28 [38]. [Pg.476]

Metal Ions Improve Cell Adherence for Efficient MES... [Pg.156]

The addition of sensitizer ions improves optical pumping efficiency those actually used for glass lasers are noted in table 35.6. Many additional ions have been used to sensitize rare earth fluorescence, such as Cr - Nd, Cr - Yb, and Mo - Er (see Young, 1969, for references). Energy transfer and sensitization schemes for rare earths in glasses are discussed by Reisfeld (1973). [Pg.303]

In the presence of 286 ppm CaCOj the onset of the adsorption isotherm starts at much lower equilibrium concentrations, reaching a fivefold higher plateau value (Fig. 6). As a result, calcium ions improve the adsorption of anionic surfactant molecules on the kaolin surface. However, under these circumstances the precipitation of Ca-surfactant complexes is noticeable. The adsorption... [Pg.180]

ICP-AES has already exerted a major impact on analytical spectroscopy, as more multi-element determinations are presently done by this technique than by any other. ICP-MS could exert a similar impact in the near future, particularly for applications requiring detectability as the main figure of merit. There are some weaknesses and room for improvement in both ICP techniques, however. The main problems in ICP-AES for rare earths are spectral interferences and detection limits that are not quite good enough for many applications. In ICP-MS, suppression of oxide ions, improvements in precision, and alleviation of matrix interference effects are desirable. Nevertheless, both techniques represent substantial improvements upon what was available previously for multi-element determinations, and both are likely to be used for some time to come. [Pg.420]

Ruofinated solvent Mixtures of alkyl carbonates or alkyl carbonates with ethers, UPFj Inaeases diffusivity of LI Ions, improves load performance 170... [Pg.54]


See other pages where Ion improved is mentioned: [Pg.22]    [Pg.155]    [Pg.274]    [Pg.40]    [Pg.240]    [Pg.2]    [Pg.101]    [Pg.426]    [Pg.47]    [Pg.165]    [Pg.144]    [Pg.240]    [Pg.641]    [Pg.524]    [Pg.215]    [Pg.118]    [Pg.730]    [Pg.156]    [Pg.1131]    [Pg.283]    [Pg.749]    [Pg.54]    [Pg.749]   
See also in sourсe #XX -- [ Pg.45 ]




SEARCH



Ion-selective electrodes biocompatibility improvement

Metal Ions Improve Cell Adherence for Efficient MES

Use of Halide Ions to Improve Selectivity

© 2024 chempedia.info