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Interference element

Advantages High analysis rate 3-4 elements per hour Applicable to many more metals than voltammetric methods Superior to voltammetry for mercury and arsenic particularly in ultratrace range Disadvantages Nonspecific absorption Spectral interferences Element losses by molecular distillation before atomisation Limited dynamic range Contamination sensitivity Element specific (or one element per run) Not suitable for speciation studies in seawater Prior separation of sea salts from metals required Suspended particulates need prior digestion About three times as expensive as voltammetric equipment Inferior to voltammetry for cobalt and nickel... [Pg.266]

In FAES and FAAS, the analytical results will be totally degraded if there is a spectral overlap of an analyte transition. This can result from an interfering matrix element with a transition close to that of the analyte. This table presents a list of those overlaps that have been observed and those that are predicted to happen. In many cases the interferant element has been present in great excess when compared to the analyte species. Therefore, if the predicted interferant element is a major component of the matrix, a careful investigation for spectral overlap should be made. Excitation sources other than flames were not covered in this study. [Pg.489]

The contribution of interference elements can be estimated by performing spectral line interference corrections. Calibrators are prepared in which mutually interferent elements are not present in the same solution. These solutions are then used to calibrate the system. Apparent concentrations are obtained by analyzing the ultrapure single element solutions (or solids). The interference coefficients are calculated by dividing the apparent concentration by the concentration of the interferent. In ICP-AES, the corrections are generally linear and thus a single element solution suffices to determine the correction factor. In spark and DC arc emission spectrometry, several samples are required. In practice, the determination of an element may be influenced by several other sample concomitants, and the final corrected concentration must be the summation of all the in-terferents. To complicate matters further, an iterative procedure must be used to deal with mutual interferences. [Pg.212]

Acid/Solvent/Fusion Mixture Interference Element/Isotope... [Pg.141]

High concentrations of a matrix constituent (element) can cause a suppression of the ion current of analyte species. This interference is not necessarily specific in nature and is usually not limited to a single interferent element. However, in general, more serious effects are observed with higher... [Pg.137]

This test method covers the determination of mercaptan sulfur in gasolines, kerosines, aviation turbine fuels, and distillate fuels containing from 0.0003 to 0.01 mass % of mercaptan sulfur (Note 4). Organic sulfur compounds such as sulfides, disulfides, and thiophene do not interfere. Elemental sulfur in amounts less than O.OOOS mass % does not interfere. Hydrogen sulfide will interfere, if not removed as described in 9.2. [Pg.498]

Interferences Elements or chemical compounds that have similar properties to the analyte that prevent its direct measurement. [Pg.4]

The more stable the metal complex, the lower the pH at which it can be quantitatively formed. Elements in the first group may be titrated with EDTA at pH 1 to 3 without interference from cations of the last two groups, while cations of the second group may be titrated at pH 4 to 5 without interference from the alkaline earths. [Pg.1167]

Minimizing Chemical Interferences The quantitative analysis of some elements is complicated by chemical interferences occurring during atomization. The two most common chemical interferences are the formation of nonvolatile compounds containing the analyte and ionization of the analyte. One example of a chemical interference due to the formation of nonvolatile compounds is observed when P04 or AP+ is added to solutions of Ca +. In one study, for example, adding 100 ppm AP+ to a solution of 5 ppm Ca + decreased the calcium ion s absorbance from 0.50 to 0.14, whereas adding 500 ppm POp to a similar solution of Ca + decreased the absorbance from 0.50 to 0.38. These interferences were attributed to the formation of refractory particles of Ca3(P04)2 and an Al-Ca-O oxide. [Pg.419]

A major advantage of this hydride approach lies in the separation of the remaining elements of the analyte solution from the element to be determined. Because the volatile hydrides are swept out of the analyte solution, the latter can be simply diverted to waste and not sent through the plasma flame Itself. Consequently potential interference from. sample-preparation constituents and by-products is reduced to very low levels. For example, a major interference for arsenic analysis arises from ions ArCE having m/z 75,77, which have the same integral m/z value as that of As+ ions themselves. Thus, any chlorides in the analyte solution (for example, from sea water) could produce serious interference in the accurate analysis of arsenic. The option of diverting the used analyte solution away from the plasma flame facilitates accurate, sensitive analysis of isotope concentrations. Inlet systems for generation of volatile hydrides can operate continuously or batchwise. [Pg.99]

Organics produce no useful positive ions, but the ions produced by inorganic samples are remarkably free from background interference, and the resulting mass spectra are relatively simple. The ion currents derived from the positive sample ions at each m/z value, being free from background ions, represent an accurate measure of the amount of each element. [Pg.389]

For several reasons — including the complete breakdown of sample into its substituent elements in the plasma and the use of an unreactive monatomic plasma gas (argon) — background interferences in the resulting mass spectra are of little importance. Since there are no or very few background overlaps with sample ions, very precise measurements of sample ion abundances can be made, which facilitate the determination of precise isotope ratios. [Pg.395]

Orga.nic Carbon. Organic materials interfere with plant operation because these compounds react with sulfuric acid under furnace conditions to form sulfur dioxide. There is a reducing atmosphere in the furnace which may reduce sulfur dioxide to elemental sulfur, which results in sulfur deposits in the gas handling system. [Pg.196]

Two methods are used to measure pH electrometric and chemical indicator (1 7). The most common is electrometric and uses the commercial pH meter with a glass electrode. This procedure is based on the measurement of the difference between the pH of an unknown or test solution and that of a standard solution. The instmment measures the emf developed between the glass electrode and a reference electrode of constant potential. The difference in emf when the electrodes are removed from the standard solution and placed in the test solution is converted to a difference in pH. Electrodes based on metal—metal oxides, eg, antimony—antimony oxide (see Antimony AND ANTIMONY ALLOYS Antimony COMPOUNDS), have also found use as pH sensors (8), especially for industrial appHcations where superior mechanical stabiUty is needed (see Sensors). However, because of the presence of the metallic element, these electrodes suffer from interferences by oxidation—reduction systems in the test solution. [Pg.464]


See other pages where Interference element is mentioned: [Pg.641]    [Pg.41]    [Pg.4991]    [Pg.290]    [Pg.641]    [Pg.41]    [Pg.4991]    [Pg.290]    [Pg.97]    [Pg.1391]    [Pg.1410]    [Pg.1756]    [Pg.416]    [Pg.521]    [Pg.94]    [Pg.105]    [Pg.107]    [Pg.114]    [Pg.115]    [Pg.366]    [Pg.292]    [Pg.377]    [Pg.212]    [Pg.108]    [Pg.193]    [Pg.200]    [Pg.373]    [Pg.329]    [Pg.334]    [Pg.451]    [Pg.201]    [Pg.392]    [Pg.311]    [Pg.317]    [Pg.319]    [Pg.388]    [Pg.517]    [Pg.392]    [Pg.168]    [Pg.201]   
See also in sourсe #XX -- [ Pg.144 ]




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