Inorganic forms, metals

Aromatic amines form addition compounds and complexes with many inorganic substances, such as ziac chloride, copper chloride, uranium tetrachloride, or boron trifluoride. Various metals react with the amino group to form metal anilides and hydrochloric, sulfuric, or phosphoric acid salts of aniline are important intermediates in the dye industry. 

Feed Ga.s Purifica.tion. Because nickel-based reforming catalysts are quite sensitive to sulfur, halogen, and heavy metal poisons which may be found ia natural gas, a feedstock purification system is normally required. Sulfur compounds, ia both organic and inorganic forms, are the most common... 

Inorganic heavy metals are usually removed from aqueous waste streams by chemical precipitation in various forms (carbonates, hydroxides, sulfide) at different pH values. The solubiUty curves for various metal hydroxides, when they are present alone, are shown in Figure 7. The presence of other metals and complexing agents (ammonia, citric acid, EDTA, etc) strongly affects these solubiUty curves and requires careful evaluation to determine the residual concentration values after treatment (see Table 9) (38,39). 

Crown ethers (Fig. 3.57) and cryptands (Fig. 3.58) can solubilize organic and inorganic alkali metal salts even in nonpolar organic solvents they form a complex with the cation (see Fig. 3.57c), and thus act as an organic mask (Gates, 1992). 

Inorganic or metal-containing medicinal compounds may contain either (a) chemical elements essential to life forms—iron salts used in the treatment of anemia—or (b) nonessential/toxic elements that carry out specific medicinal purposes—platinum-containing compounds as antitumor agents or technetium... 

Dissolved inorganic trace metal (e.g., Hg, Ag, Cd, Ni, Zn) speciation and the tendency to form stable soluble complexes in saline water was considered by Turner... 

Tensile Strengths of Inorganic and Metallic Materials as a Function of Form... 

The tensile strength of materials is dependent on the treatment and form of the material. Thus, the tensile strength of isotropic bulk nylon-6,6 is less than that of anisotropic oriented nylon-6,6 fiber. Inorganics and metals also form fibers and whiskers with varying tensile strengths (Table 14.1). Fibers are generally less crystalline and larger than whiskers. 

Tin is anther ancient metal that continues to have a variety of uses. The inorganic form is used in food packaging, solder, brass, and as an alloy with other metals. The organic forms of tin, triethyltin and trimethyltin, are used as fungicides, bactericides, and generally as antifouling agents for boats. 

Polyacrylic acid Hybrid organic/inorganic network polymers were formed via the reaction of polyacrylic acid with tin(IV). titanium(IV), and silicon (IV) alkoxides and subsequent hydrolysis to form mesoporous materials. Treatment by nitric acid removed the polyacrylate template and produced microporous inorganic hydrous metal oxides Surface areas characterized by BET measurements 130... 

Unlike metalloporphyrins, the nonporphyrinic metal compounds are poorly characterized with respect to molecular structure and properties. Examining the nature of the nickel and vanadium in these compounds is important from the standpoint that often most of the Ni and V in a petroleum is nonporphyrinic, as shown in Table II. Sugihara et al. (1970) suggested that the nonporphyrin metal compounds comprise a wide variety of coordinated complexes resulting from the reaction of inorganic forms of the metals with polar organic molecules. Larson and Beuther (1966) speculated that the nonporphyrinic metal complexes are simply... 

Saxena J, Howard PH. 1977. Environmental transformation of alkylated and inorganic forms of certain metals. In Perlman D, ed. Advances in applied microbiology. Vol. 21, New York, NY Academic Press, 185-226. 

Biomethylation of Elements. The biomethylation of elements is carried out principally by microorganisms and is important in environmental toxicology, particularly in the case of heavy metals, because the methylated compounds are absorbed through the membranes of the gut, the blood-brain barrier, and the placenta more readily than are the inorganic forms. For example, inorganic mercury can be methylated first to monomethylmercury and subsequently, to dimethylmercury ... 

Some investigators have produced organic chelate complexes from the metals after they have been separated in the inorganic form on the column, but before entry into the detector, ie post-column derivatisation, while other investigators form the organic complexes before the sample is applied to the separation column, ie pre-column derivatisation. 

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