Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

4-hydroxyphenyl

Example 86 A 0.10 mole amount of the starting 3-(4-hydroxyphenyl) propylene, 0.25 mole of methyl nitrite, 0.5 liter of methyl alcohol, and 0.006 mole of a palladium chloride catalyst were charged into a reaction vessel. Then, the reaction was carried out at a temperature of 20.degree. C. for 1.5hours."... [Pg.83]

Triethylene glycol-bis[3-tert-butyl-5-methyl-4-hydroxyphenyl]propionate [36443-68-2]... [Pg.1016]

Reduction. These hydroxybenzaldehydes can be reduced by catalytic hydrogenation over palladium or platinium to yield the corresponding hydroxybenzyl alcohols, but the electrolytic reduction in an alkaline medium gives the coupling product l,2-bis(4-hydroxyphenyl)ethane-l,2-diol in very good yield from 4-hydroxybenzaldehyde (49—51). [Pg.505]

Chemical off—on switching of the chemiluminescence of a 1,2-dioxetane (9-benzyhdene-10-methylacridan-l,2-dioxetane [66762-83-2] (9)) was first described in 1980 (33). No chemiluminescence was observed when excess acetic acid was added to (9) but chemiluminescence was recovered when triethylamine was added. The off—on switching was attributed to reversible protonation of the nitrogen lone pair and modulation of chemically induced electron-exchange luminescence (CIEEL). Base-induced decomposition of a 1,2-dioxetane of 2-phen5l-3-(4 -hydroxyphenyl)-l,4-dioxetane (10) by deprotonation of the phenoHc hydroxy group has also been described (34). [Pg.264]

Transesterification reactions between the methyl propionate and various alcohols produce another family of stabili2ers. Stearyl alcohol yields octadecyl 3-(3,5-di-/ f2 -butyl-4-hydroxyphenyl)propionate (27) (16), pentaerythritol gives the tetrakis ester (28) (17), and trishy dr oxyethyl isocyanurate gives (29) (18). [Pg.61]

Methylphenol is converted to 6-/ f2 -butyl-2-methylphenol [2219-82-1] by alkylation with isobutylene under aluminum catalysis. A number of phenoHc anti-oxidants used to stabilize mbber and plastics against thermal oxidative degradation are based on this compound. The condensation of 6-/ f2 -butyl-2-methylphenol with formaldehyde yields 4,4 -methylenebis(2-methyl-6-/ f2 butylphenol) [96-65-17, reaction with sulfur dichloride yields 4,4 -thiobis(2-methyl-6-/ f2 butylphenol) [96-66-2] and reaction with methyl acrylate under base catalysis yields the corresponding hydrocinnamate. Transesterification of the hydrocinnamate with triethylene glycol yields triethylene glycol-bis[3-(3-/ f2 -butyl-5-methyl-4-hydroxyphenyl)propionate] [36443-68-2] (39). 2-Methylphenol is also a component of cresyHc acids, blends of phenol, cresols, and xylenols. CresyHc acids are used as solvents in a number of coating appHcations (see Table 3). [Pg.67]

A large number of hindered phenoHc antioxidants are based on the Michael addition of 2,6-di-/ f2 -butylphenol and methyl acrylate under basic catalysis to yield the hydrocinnamate which is a basic building block used in the production of octadecyl 3-(3,5-di-/ f2 butyl-4-hydroxyphenyl)propionate, [2082-79-3], tetrakis(methylene-3(3,5-di-/ f2 butyl-4-hydroxylphenyl)propionate)methane [6683-19-8], and many others (63,64). These hindered phenolic antioxidants are the most widely used primary stabilizers in the world and are used in polyolefins, synthetic and natural mbber, styrenics, vinyl polymers, and engineering resins. 2,6-Di-/ f2 -butylphenol is converted to a methylene isocyanate which is trimerized to a triazine derivative... [Pg.69]

Acetarsone. Acetarsone (3-acetamido-4-hydroxyphenyl arsonic acid) (13), also known as acetarsol, stovarsol, and Ehrlich 594, forms white prisms from water. [Pg.314]

A Methylamino)phenol. This derivative, also named 4-hydroxy-/V-methy1ani1ine (19), forms needles from benzene which are slightly soluble in ethanol andinsoluble in diethyl ether. Industrial synthesis involves decarboxylation of A/-(4-hydroxyphenyl)glycine [122-87-2] at elevated temperature in such solvents as chlorobenzene—cyclohexanone (184,185). It also can be prepared by the methylation of 4-aminophenol, or from methylamiae [74-89-5] by heating with 4-chlorophenol [106-48-9] and copper sulfate at 135°C in aqueous solution, or with hydroquinone [123-31 -9] 2l. 200—250°C in alcohoHc solution (186). [Pg.315]

A (4-Hydroxyphenyl)glycine. This derivative (23) forms aggregate spheres or shiny leaflets from water. It turns brown at 200°C, begins to melt at 220°C, and melts completely with decomposition at 245 —247°C. The compound is soluble in alkaU and mineral acid and sparingly soluble in water, glacial acetic acid, ethyl acetate, ethanol, diethyl ether, acetone, chloroform, and benzene. [Pg.316]

A/-(4-Hydroxyphenyl)glycine can be prepared from 4-aminophenol and chloracetic acid (199,200) or by alkaline hydrolysis of the corresponding nitrile with subsequent elimination of ammonia (201). [Pg.316]

The Chemicaly3.bstractIndexis 2,7-naphthalene-disulfonic acid, 4-amino-5-hydroxy-3-[[4 -[(4-hydroxyphenyl)azo] [l,l -biphenyl]-4-yl]azo]-6-(phenylazo)-, disodium salt. [Pg.430]

Reportedly, OjoCdiaHylbispheaol A is an attractive comonomer for bismaleimides because the corresponding copolymer is tough and temperature resistant (41). Toughness, however, is a function of the BMI—diaHylbisphenol A ratio employed. In one study optimized toughness properties were achieved when BMI and diaHylbisphenol were employed at a close to 2 1 molar ratio (42). In Table 9, the mechanical properties of BMI—bis(3-allyl-4-hydroxyphenyl)-7 -diisopropylbenzene resias are provided, showiag optimized properties for the 60/40 BMI—diaHylbisphenol composition. The 0,(9 diaHylbisphenol A is commercially available under the trademark Matrimide 5292. Another bisaHylphenyl compound is available from SheH Chemical Company/Technochemie under the trademark COMPIMIDE 121. [Pg.27]

Table 9. Mechanical Properties of BMI—bis(3-allyl-4-hydroxyphenyl)-/ -diisopropylbenzene Blends ... Table 9. Mechanical Properties of BMI—bis(3-allyl-4-hydroxyphenyl)-/ -diisopropylbenzene Blends ...
The most common commercial polycarbonate [24936-68-3] is prepared from 2,2-bis (4-hydroxyphenyl)propane, that is, bisphenol A [80-05-7] and has the general stmcture ... [Pg.37]

Polyarylether Ketones. The aromatic polyether ketones are tme thermoplastics. Although several are commercially available, two resins in particular, poly ether ether ketone [31694-16-3] (PEEK) from ICI and poly ether ketone ketone (PEKK) from Du Pont, have received most of the attention. PEEK was first synthesized in 1981 (20) and has been well studied it is the subject of numerous papers because of its potential use in high performance aircraft. Tough, semicrystalline PEEK is prepared by the condensation of bis(4-fiuorophenyl) ketone with the potassium salt of bis(4-hydroxyphenyl) ketone in a diaryl sulfone solvent, such as diphenyl sulfone. The choice of solvent is critical other solvents, such as Hquid HE, promote the reaction but lead to premature low molecular-weight crystals, which do not exhibit sufficient toughness (21). [Pg.38]

Tetrakis (4-hydroxyphenyl)ethane is prepared by reaction of glyoxal with phenol in the presence of HCl. The tetraglycidyl ether [27043-37-4] (4), mp ca 80°C, possesses a theoretical epoxide functionaUty of four with an epoxy equivalent weight of 185—208 (4). [Pg.364]


See other pages where 4-hydroxyphenyl is mentioned: [Pg.410]    [Pg.4]    [Pg.112]    [Pg.112]    [Pg.112]    [Pg.112]    [Pg.112]    [Pg.112]    [Pg.112]    [Pg.112]    [Pg.500]    [Pg.501]    [Pg.615]    [Pg.620]    [Pg.696]    [Pg.1025]    [Pg.332]    [Pg.464]    [Pg.464]    [Pg.464]    [Pg.61]    [Pg.67]    [Pg.313]    [Pg.316]    [Pg.166]    [Pg.241]    [Pg.23]    [Pg.327]    [Pg.356]    [Pg.25]    [Pg.518]    [Pg.249]    [Pg.135]    [Pg.265]   
See also in sourсe #XX -- [ Pg.305 , Pg.306 , Pg.308 , Pg.321 ]

See also in sourсe #XX -- [ Pg.305 , Pg.306 , Pg.308 , Pg.321 ]




SEARCH



0-Hydroxyphenyl phenyl ether

2- Hydroxyphenyl sulfide

2- chloro-4-hydroxyphenyl

2-hydroxyphenyl ureas

3- Hydroxyphenyl acids

3- Hydroxyphenyl methyl sulfide

3- Nitro-4-hydroxyphenyl arsonic acid

3- hydroxyphenyl acetic acid

3-Methoxy-4-hydroxyphenyl acids

3-methoxy-4-hydroxyphenyl glycol

4- Hydroxyphenyl-pyruvic

4-Hydroxyphenyl pyruvate dioxygenase

4-Hydroxyphenyl structures

4-hydroxyphenyl 1,10-phenanthroline

4-hydroxyphenyl azide

4-hydroxyphenyl benzimidazole

4-hydroxyphenyl complex with

4-hydroxyphenyl dimethyl sulfoxide

4-hydroxyphenyl dimethylformamide

4-hydroxyphenyl imidazole

4-hydroxyphenyl pyridine

4-hydroxyphenyl triethylamine

5- Hydroxyphenyl-1,2,4-triazine 4-oxides

5-Hydroxyphenyl-4-hydroxy-4,5-dihydro1,2,4-triazines

Acetic hydroxyphenyl-,

Benzyl 2-hydroxyphenyl ketone

Bis(2-(2-hydroxyphenyl)-2-oxazoline)oxorhenium(V) Trifluoromethanesulfonate, OTf

Bis(4-hydroxyphenyl)propane

Bis-(4-hydroxyphenyl)-methane

Bis-(4-hydroxyphenyl)-sulfone

Bis[4-hydroxyphenyl

Carbenes, hydroxyphenyl

D-a-Amino-4-hydroxyphenyl acetic

Diformyl-5-hydroxyphenyl) acetamide

Ester mit Arbutin (4-Hydroxyphenyl-P-D-glucopyranosid)

Hydroxy-hydroxyphenyl-phenyl-heptanone

Hydroxyphenyl benzene sulfonate

Hydroxyphenyl benzothiazole

Hydroxyphenyl benzotriazole

Hydroxyphenyl glycine

Hydroxyphenyl methacrylate

Hydroxyphenyl propionic acid

Hydroxyphenyl) -4-methyloxazole

Hydroxyphenyl)-2-oxazoline (Hhoz)

Hydroxyphenyl)Silanes with Different Types of Bioactivity

Hydroxyphenyl)ethane

Hydroxyphenyl-2-nitroethane

Hydroxyphenyl-3-butanone

Hydroxyphenyl-lactic acid

Hydroxyphenyl-pyranoanthocyanins

Hydroxyphenyl-valeric acid

O-Hydroxyphenyl methyl ketone

P- Hydroxyphenyl pyruvic acid

P-Hydroxyphenyl acetic acid

P-Hydroxyphenyl cyclohexyl ketone

P-Hydroxyphenyl pyruvate

P-Hydroxyphenyl-2-oxazoline

P-hydroxyphenyl unit

Polyethers hydroxyphenyl terminated

Pyruvic acid, -hydroxyphenyl

Significant Examples of Electropolymerized Films from Aminophenyl-, Hydroxyphenyl- and Vinyl-Substituted Porphyrins

© 2024 chempedia.info