2- 2’-hydroxy-5 -methyl phenyl

Analog entsteht aus Benzaldehyd und Buten-(2)-al 2-Hydroxy-4-methyl-5-phenyl-te-trahydrofuran (21% d.Th. Kp0>6 108—114°). 

Hydroxy-4-methyl-5-phenyl-l-azaquinone, from 3-hydro,xy-... 

Phenyl-glykol6 4-Phenyl-butandiol-( 1,4)7 4-(4-Methyl-phenyl)-butandiol-(l. 4)1 Phenyl- (2-hydroxy-methyl-phenyl)-melhanol1 (2-Hydroxy methyl-phenyl)-(4-melhyl-phenyl)-methanol7... 

I- Topanol (1,1,3-tri ter-butyl hydroxy methyl phenyl)butane) and Nonox DLTDP (di laurylthiodipropionate) 0.1 wt% in solution II- Santonox-R (4,4 -thio-bis-(6-terbutyl... 

R H5C6 N COOH H R - CH2-Cl 1. 6NHa Ruckfl. 18hB 2. Eindampfen (-+ HCI-Salz) 3. H20 RuckH. 12 h 2-(4-Hydroxy-methyl-phenyl) -dl -glycin-Hydrochlorid 82 171-173 (Zers.) 1... 

The compound formed is a mixed aromatic alcohol and ketone, i.e. (hydroxy-methyl-phenyl) phenyl ketone, and is known as benzoin. This compound should properly be considered in the class of hydroxy ketones, which we shall take up a little later, but, because of its relation to benzaldehyde, it may also be mentioned here. 

Agaritine (L-glutaminic acid 5- A( -[4-(hydroxy-methyl)-phenyl]hydrazide)). A compound from the cultivated mushroom Agaricus bisporus and related species. ... 

Although isoxazoles are comparatively weak electron donors, complexes with numerous metal ions, notable metal(II) ions, have been reported. The ligands include isoxazole and its methyl, phenyl, amino and hydroxy derivatives. They are listed with references in Table 5. 

Chroman-4-one, 3-hydroxy-2-phenyl-configuration, 3, 631 Chroman-4-one, 2-iodo- H NMR, 3, 583 Chroman-4-one, 2-isopropyl- H NMR, 3, 583 Chroman-4-one, 3-methyl- H NMR, 3, 583 synthesis, 3, 852 Chroman-4-one, 5-methyl-synthesis, 3, 855 Chroman-4-one, 7-methyl-synthesis, 3, 855... 

Imidazole, 4-formyl-5-hydroxy-l-phenyl-mesoionic, 5, 372 Imidazole, 2-formyl-1-methyl-mass spectra, S, 360 Imidazole, 2-formyl-l,4,5-trimethyl-... 

Indazole, 5,5-dimethyl-3-trifluoromethyl-4,5-dihydro-trichomonacidal activity, 5, 291 Indazole, 2-ethoxycarbonyl-reactions, 5, 269 Indazole, 3-fluoro-synthesis, S, 263 Indazole, 1-germyl-synthesis, 5, 236 Indazole, 1-glycosyl-synthesis, 5, 289 Indazole, 2-glycosyl-synthesis, 5, 289 Indazole, halo-reactions, S, 266 Indazole, 2-hydroxy-methylation, 5, 269 Indazole, 3-hydroxy-reactions, S, 264 Indazole, 6-hydroxy-diazo coupling, 5, 86 Indazole, hydroxyphenyl-synthesis, S, 288 Indazole, 3-iodo-synthesis, S, 241 Indazole, l-isopropyl-3-phenyl-reduction, 5, 243 Indazole, 3-mercapto-1 -substituted tautomerism, 5, 265 Indazole, methoxy-... 

Indole, 3-hydroxymethyl-2-phenyl-stability, 4, 272 Indole, I-hydroxy-2-phenyl-synthesis, 4, 363 Indole, 2-iodo-synthesis, 4, 216 Indole, 3-iodo-reaetions, 4, 307 synthesis, 4, 216 Indole, 2-iodo-l-methyl-reaetions, 4, 307 Indole, 2-lithio-synthesis, 4, 308 Indole, 3-lithio-synthesis, 4, 308 Indole, 2-mereapto-tautomerism, 4, 38, 199 Indole, 3-mercapto-tautomerism, 4, 38, 199 Indole, 3-methoxy-synthesis, 4, 367 Indole, 5-methoxy-oxidation, 4, 248 Indole, 7-methoxy-2,3-dimethyl-aeetylation, 4, 219 benzoylation, 4, 219 Indole, 5-methoxy-l-methyl-reduetion, 4, 256 Indole, 5-methoxy-l-methyl-3-(2-dimethylaminoethyl)-reaetions... 

Pyridine, 3-hydroxy-4-methyl-5-phenyl-diazo coupling, 2, 206 Pyridine, 3-hydroxy-2-phenyl-synthesis... 

Hydroxy-5-methyl-phenyl)benztriazole (Tinuvin P, Ciba-Geigy)... 

Step G 4-fOrtho-(2, 3 -Dihydroxypropyloxycarbonyl)-Phenyl]-Amino-8-Trifluoromethyl-quinoHne Acetonide — 100 cc of toluene were added to 80 cc of 2,2-dimethyl-4-hydroxy-methyl-1,3-dioxolane and the toluene was distilled off under reduced pressure to eliminate the water present. To the anhydrous 2,2-dimethyl-4-hydroxymethyl-1,3-dioxolane thus obtained, 0.25 gram of an oily 50% suspension of sodium hydride and then 21.3 grams of 4-... 

According to British Patent 1,022,645 3.4 g of 3-acetoxy-7-chloro-1-methyl-5-phenyl-1,3-dihy-dro-2H-1,4-benzodiazepin-2-one suspended in 80 ml alcohol was treated with 6 ml of 4 N NaOH. After Complete solution had taken place, a solid precipitated this solid was redissolyed by the addition of 80 ml of water. The solution was acidified with acetic acid to give white crystals which were recrystallized from alcohol to yield 7-chloro-3-hydroxy-5-phenyl-1-methvl-1,3-dihydro-2H-1,4-benzodiazepin-2-one, MP 119° to 121°C. 

Dioxo-4,8-diphenyl-l,3,5,7-tetraaza-bicyclof3.3.0]octan laBt sich durch Lithium-alanat in5-Hydroxy-3- phenyl-1,2,4- triazolidin (14% d.Th.), N-Methyl- benzylamin auf-spalten4 ... 

Einen analogen Anwendungsbereich haben Kalium-tributyl-(2)- und Kalium-triiso-propyloxy-hydrido-borat5 (s. Tab. 28, S. 334) sowie Bis-[3-methyl-butyl-(2)]-boran6 (s. Tab. 24, 27, 28, S. 329, 330, 334). Mit letzterem erhalt man z. B. aus 2-Oxo-l-phenyl-cy-clopentan 73% d.Th. 2-Hydroxy-1-phenyl-cyclopentan6. 

Analog erhalt man die Gemische2 von trans- und cis-4-Hydroxy-l-methyl- (91% bzw. 9%) sowie trans- und cis-4-Hydroxy-l-phenyl-cyclohexan (97,7 bis 98,1% bzw. 

H-henzotriazol 2-(4-Chlor-phenyl)-,, . 2-(4-Methoxy-phenyl)-.. . 2-(4-Methyl-phenyl)-.. . 2-(2-Hydroxy-5-methyl-phenyl)-.. . ... 

Methyl-phenyIthio)-(4-nitro-phenyl)- 700 (2-Nitro-phcnyl)-(2-hydroxy-5-methyl-phenyl)- 693 (2-Nitro-phenyl)-(4-methoxy-phenyl)- 693 (2-Nitro-phenyl)-(4-methyl-phenyl)- 693 Phenyl-(4-amino-phenyl)- 568 Ph en yl-(4-formyl-phenyl) -... 

N-Diphenylmethylen- 374 N-Diphenylmethylen-O-aminocarbonyl- 612 N-[l,3-Diphenyl-propyl-(2) - 374 N-[l,3-Diphenyl-propyliden-(2)]- 374, 377, 380 N-(4-Halogen-phenyI)- 683 N-Heptyl- 375 N-Heptyl-N-acetyl- 376 N-Heptyliden- 375 N-Hcptyliden-O-acetyl- 376 0-(2-Hydroxy-athyl)-N-athoxycarbonyl- 133 N-(4-Hydroxy-phenyl)- 683 0-(2-Hydroxy-l-phenyl-athyI)-N-athoxycarbonyI-aus 0-(ci-AthoxycarbonyI-benzyl)-N-athoxycar-bonyl-hydroxylamin und Lithiumalanat 133 N-Isopropyl- 682 N-Isopropylidcn- 613 N-Methyl- 133, 682 O-Methyl-N-bcnzyliden- 377 O-Methyl-N-benzyliden- 375 0-Methyl-N-(4-chlor-benzyl)- 375 0-Methyl-N-(4-chlor-benzyliden)- 375 N-Methy -N,0-diacetyI- 682 N-(4-Methyl-phenyl)- 683 0-McthyI-N-( 1 -phenyl-athyliden)- 375 N-(4-Methylthio-phenyl)- 684 N-(4-Nitro-benzyl)- 374 N-[4-Nitro-benzyliden - 374, 377 N-(2-Nitro-phenyl)- 562 N-(4-Nitro-phenyl)- 682 N-Nitroso-N-cyclohexyl- 697 N-Octyl- 374 N-Octyl-(2)-N-acetyl- 376 N-Octyliden- 374 N-0ctyliden-(2)-0-acctyl- 376 N-(Pentafluor-phenyl)-0,N-diacetyl- 697 N-Phenyl- 474, 481, 682, 783 N-Phenylacetyl-O-benzoyl- 265 N-(l-Phenyl-athyl)- 374 N-(l-Phenyl-athyl)-N-acetyl- 376 N-(l-Phenyl-athyliden)-374, 613 N-( l-Phenyl-athyliden)-0-acetyl- 376 N-[ 1 -Phenyl-buten-( 1 )-yl-(3)-iden]- 582 N-f4-Phenyl-butyl-(2)-iden]- 581 N-Phcnyl-N,0-diacetyl- 682 N-(4-Phenylthio-phenyl)- 684 N-Propyl-N-cyclohexyl- 376 N-Propyl-N-isopropyl- 376 O-Sulfonyl- 481 N-(4-Sulfonyl-phenyI)- 683 N-(2-Vinyl-phenyl)- 698... 

Bis-[ ( benzo-1,3-oxazol) -yl-(2)-thio]- 343 Bis-[1,4- (bzw. 3,4]-dihydro-naphthy[-(2)-oxy]- 588 Bis-[dimethylamino]- 345 Bis-[4-dimethyIamino-phenyl]- 346 Bis-[4-hydroxy-phenyl]-(2-carboxy-phenyl)- 167 Bis-[4-methoxy-phenyl]-dideutero- 346 Bis-[4-methyl-phenyl]-Bis-f 2-methyl-thiiranyl-(2)]- 570 Bis-[naphthyl-(2)-oxy]- 588 Bis-[naphthyl-(2)-thio]-... 

Hydroxy-2-phenyl-athyl)-benzyI- 633 (2-Hydroxy-2-phenyl-athyl)-phenyI- 667 [1-Hydroxy-l -phenyl-propyl-(2)J-phenyl- 633 Methyl-(2-tert.-butyl-phenyl)- 632 Methyl-(2-methyl-phenyl)- 632 Methyl-naphthyl- 663 Naphthyl-benzyl- 633 fi-Oxo- 634... 

AthyI-(4-amino-phcnyl)- 684 Athyl-benzyl- 500 Bis-[4-brom-phenyI]- 572 Bis-[4-chlor-phenyl]- 488 Bis-[4-hydroxy-phenyl]- 572 Bis-14-methoxy-phenyl]- 572 Bis-[4-methyl-phenyl]- 572 Bis-[4-nitro-phenyl]- 572 a-Brom- 534f. 

Acetyl-phenyl- 635 4-Amino-3,5-dimethyl-phenyl- 102 2-Amino-4-hydroxy-phenyl- 692 4-Amino-phenyl- 685 4-Benzylamino-phenyl- 102 2,4-Dinitro-phenyl- 692 4-(2-Hydroxy-benzylamino)-phenyl- 102 2-(2-Methyl-butanoyl)-phenyl- 635 4-Methoxy-2,6-dimethyl-phenyl-102 (Nitro-phenyl)- 635 2-Nitro-phenyl- 680, 692 4-Nitro-phenyl- 685... 

H ydroxy-5 -methyl-1 -(phenylthio-methyl )-2-iso-propyl- 635 2-Hydroxy-l-oxo- 297 2-Hydroxy-l-phenyl- 335... 

Methyl- -6-fluor-3-hydroxy-3-phenyl- 361 1-Methyl- -3-(4-fluor-phenyl)- 561 1-Methyl- -6-fluor-3-phenyl- 561 1-Methyl- -3-hydroxy-3-(4-fluor-phenyl)- 567 1-Methyl- -6-hydroxy-3-(4-fIuor-phenyl)- 561 1-Methyl- -6-hydroxy-3-phenyl- 561 1-Methyl- -3-(4-hydroxy-phenyl)- 561 1-Methyl- -3-hydroxy-3-phenyl- 561 1-Methyl- -3-phenyl- 561... 

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