1-Hexano

Synthesize 1-hexano) (1-hydroxyhexane) from acetylene and an alkyl halide. [Pg.277]

Catalyst Y i e1d(no1/mo 1 1-hexano) 2 FePcCt-- hexano i 8u)4,FePc) 3 hexano... [Pg.341]

Hexanoic acid 102 FALSE FALSE FALSE FALSE... [Pg.342]

E-l Dehydration of 2-Methy1 eye 1 hexano 1 Gas Chromatography 93 acetone raethyIcyclo-hexanol... [Pg.224]

Primary alcohols afforded the corresponding carboxylic acids via further oxidation of the aldehyde intermediate, e.g. 1-hexanol afforded 1-hexanoic acid in 95% yield. It is important to note, however, that this was achieved without the requirement of one equivalent of base to neutralize the carboxylic acid product (which is the case with supported noble metal catalysts). In contrast, when 1 mol% TEMPO (4 equivalents per Pd) was added, the aldehyde was obtained in high yield, e.g. 1-hexanol afforded 1-hexanal in 97% yield. Under cosolvent conditions using water/ethylene carbonate, Pd-neocuproine was found to be even more active (Fig. 4.65) [174]. This system is exceptional because of its activity (TOF 500h-1 could be reached for 2-octanol) and functional group tolerance, such as C=C bonds, C = C bonds, halides, a-carbonyls, ethers, amines etc. Thereby this system is expected to have a broad synthetic utility. [Pg.177]

Fig. 12 Symmetry-unique SC orbitals for (a) tris(bicyclo[2.1.1]hexano)benzene and (b) tris(benzocyclobutadieno)benzene. [Pg.344]

Synonyms Caproic acid 1-Hexanoic acid Source Ghaziaskar, H. S. Nikravesh, M. Fluid Phase Equil. (2003), 206(1-2), 215-221. [Pg.403]

Fig. 16 Heterogeneous catalysis of the esterification of benzyl alcohol with 1-hexanoic acid using a cross-linked Hn-phase sulfonic acid resin formed by amide H-bond-assisted LLC phase formation...

EINECS 205-251-1 Hexanoic acid, 2-ethyl-, zinc salt Octoate Z Zinc 2-ethylhexoate Zinc bis(2-ethyl-hexanoate). Rubber activator used in soluble cure systems in place of stearic acid and partial replacement of zinc oxide for natural and synthetic rubbers. Vanderbilt R.T. Co. Inc. [Pg.678]

Hexanoic acid, 2-ethyl-, zirconium salt 1940 246-841-9 Dinonyinaphthalenesulphonic acid 1446... [Pg.711]

Formic, gyoxylic, oxalic, 2-hydroxy-wo-butyric, maleic, succinic, malic, 1-hexanoic, malonic acid C1-C5 monocarboxylic acids... [Pg.465]

Hexanoic acid caproic acid 172a 174b, 603, 3370... [Pg.1156]

Hexanoic acid, ethyl ester ethyl caproate H3C-(CH2)4-C00-C2H5 V-3... [Pg.1635]

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