Hexanoic acid 6-bromo

Hexadiene, 55,109 Hexanoic acid, 55, 27 28 Hexanoic acid, 2-bromo-, 55,30 Hexanoic acid, 3-oxo ethyl ester [Acetic... 

Ethyl 2-bromohexanoate Hexanoic acid, 2-bromo-, ethyl ester. ( )- (10) (63927-44-6) Potassium fluoride (8,9) (7789-23-3)... 

Methyl 6-bromohexanoate Hexanoic acid, 6-bromo-, methyl ester... 

DL-Norleucine (2-aminohexanoic acid). Use 65 g (0.33 mol) of 2-bromo-hexanoic acid (Expt 5.164) and 400 ml of concentrated ammonia. Ensure that the bung is securely wired to the reaction bottle and allow the latter to stand in a warm place (50-55 °C) for 30 hours. Filter the amino acid at the pump and keep the filtrate (A) separately. Wash the amino acid well with methanol to remove the ammonium bromide present. Concentrate the filtrate (A) almost to dryness and add 150 ml of methanol. A second crop of amino acid contaminated with ammonium bromide is thus obtained wash it with methanol and recrystallise from hot water, thus affording a further 6 g of pure dl-norleucine. The total yield is 28 g -(65%) the decomposition point is about 325 °C. 

Bromo octene-1 2,2-Dimethyl-7-bromo-heptanoic acid 2-Methyl-2-ethyl-6-bromo-hexanoic acid ... 

The target molecule of the next generation seems an unacceptably complex derivative of n-hexanoic acid. However, the six position of one bromine atom suggests a-bromo lactone TM 8.9b. This intermediate is available on selective... 

Syntheses of the a-bromo derivatives of isovaleric,552 4-methylvaleric,553 hexanoic,554 and dodecanoic acid,555 described in detail in Organic Syntheses, are examples of the bromination of medium- and long chain fatty acids. 

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