Gas chromatography-flame photometric

Each sample was fortified with chlorpyrifos, as a reference standard, to determine the recovery during each extraction. Three portions of solvent were used, and the combined extract for each sample was dried with sodium sulfate. Analyses employed gas chromatography/flame photometric detection. Limits of detection for vegetation and animal tissues were 0.2 and 0.007 pg respectively. Recoveries from fortified samples were 82%. Diazoxon occurrence was infrequenf and at trace concentrations. 

Sass S, Parker GA. 1980. Structure-response relationship of gas chromatography-flame photometric detection to some organophosphorus compounds. J Chromatogr 189(3) 331-349. 

GC/FPD-P = gas chromatography/flame photometric detector-phosphorus mode... 

M De Paoli, TM Barbina, R Mondini, A Pezzoni, A Valentino. Determination of organophosphorus pesticides in fruits by on-line size-exclusion chromatography-liquid chromatography-gas chromatography-flame photometric detection. J Chromatogr 626 145-150, 1992. 

Berijani, S., Y. Assadi, M. Anbia, M.-R. Milani Hosseini, and E. Aghaee. 2006. Dispersive liquid-liquid microextraction combined with gas chromatography-flame photometric detection Very simple, rapid and sensitive method for the determination of organophosphorus pesticides in water. J. Chromatogr. A 1123 1-9. 

Matthias et al. [216] have described a comprehensive method for the determination of aquatic butyltin and butylmethyltin species at ultratrace levels using simultaneous sodium borohydride hydridisation, extraction with gas chromatography-flame photometric detection and gas chromatography-mass spectrometric detection. The detection limits for a lOOmL sample were 7ng L 1 of tin for tetrabutyltin and tributyltin, 3ng L 1 of tin for dibutyltin and 22ng L 1 tin for monobutyltin. For 800mL samples detection limits were l-2ng L 1 tin for tri- and tetrabutyltin and below lng L 1 tin for dibutyltin. The technique was applied to the detection of biodegradation products of tributyltin in non saline waters. 

M. B. De La Calle-Guntinas, C. Brunori, R. Scerbo, S. Chiavarini, P. Quevauviller, F. Adams, R. Morabito, Determination of selenomethionine in wheat samples comparison of gas chromatography-microwave-induced plasma atomic emission spectrometry, gas chromatography-flame photometric detection and gas chromatography-mass spectrometry, J. Anal. Atom. Spectrom., 12 (1997), 1041-1046. 

Jiemin, L., Ning, L., Meijuan, W., Guibin, J. Determination of volatile sulfur compounds in beverage and coffee samples by purge-and-trap on-line coupling with a gas chromatography-flame photometric detector. Microchim. Acta 148, 43 7 (2004)... 

AAS = atomic absorption spectrophotometry EPA = Environmental Protection Agency GC/ECD = gas chromatography/electron capture detector GC/FPD = gas chromatography/flame photometric detector GC/HECD = gas chromatography/ Hall s electrolytic conductivity detector GC/MS = gas chromatography/mass spectrometry GC/PID = gas chromatography/photoionization detector ILS = isotopically labelled standard NR = not reported SCD = Sievers chemiluminescence detector... 

Leek, C. and Bagander, L. E., Determination of reduced sulfur compounds in aqueous solutions using gas chromatography flame photometric detection. Anal. Chem., 60, 1680-1683, 1988. 

Gui-Bin j, Qun-Fang Z and Bin H (2000) Speciation of organotin compounds, total tin, and major trace metal elements in poisoned human organs by gas chromatography-flame photometric detector and inductively coupled plasma mass spectrometry. Environ Sci Technol 34 2697-2702. 

Matthias CL, Bellama JM, Olson GJ, and Brinckkman EE (1986) Comprehensive method for the determination of aquatic butyl tin and butylmethyl tin species at ultratrace levels using simultaneous hybridization/extraction with gas chromatography-flame photometric detection. Environmental Science and Technology 20 609-615. 

It was necessary to develop three different portable modules to achieve on-site field analysis capability. The first module consisted of pre-cleaned and sealed sample collection equipment, providing the capability to obtain any type of sample. The second module allowed for complete chemical work-up of the collected samples to prepare them for instrumental analysis. A third module contained analytical instrumentation necessary for chemical identification. The instrumentation included a gas chromatography-flame photometric detection (GC/FPD) to prescreen samples for phosphorus- and/or sulfur-bonded organic compounds. In addition, a gas chromatograph-mass spectrometer (GC/MS) was employed for positive compound identification. 

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