Fuel cells mechanism

M. Quintus et al., Chemical membrane degradation in automotive fuel cell -Mechanisms and mitigation, 2nd Annual International Symposium on Fuel Cell Durability Performance, Miami Beach, FL,7-8 Dec 2006... 

J. O M. BockrisandS. Srinivasan,Nature 215 397 (1967). Only possible to explain high efficiency of metabolism if energy conversion has fuel cell mechanism. 

J. O M. Bockris, F. Gutmann, andM. A. Habib, J. Biol. Phys. 13 31 (1985). A fuel cell mechanism in biological energy conversion. 

Nucliir Battery Electrolysis t 1 Battery Fuel cell Mechanical... 

Li, Q., Chen, W., Wang, Y., Liu, S., and Jia, J. Parameter identification for PEM fuel cell mechanism model based on effective informed adaptive particle swarm optimization. IEEE Transactions on Industrial Electronics, 58(6), 2410-2419, June 2011. 

A fuel cell is equivalent to a generator it converts a fuel s chemical energy directly into electricity. The main difference between these energy conversion devices is that the fuel cell acccomplishes this directly, "without the two additional intermediate steps, heat release and mechanical motion. 

In general, a fuel cell converts gaseous hydrogen and oxygen into water, electricity (and, inevitably, some heat) via the following mechanism, shown in Figure 2 ... 

Over a number of years, fuel cells have promised a new way to generate electricity and heat from fossil fuels using ion-exchange mechanisms. Fuel cells are... 

Fuel cells have attracted considerable interest because of their potential for efficient conversion of the energy (AG) from a chemical reaction to electrical energy (AE). This efficiency is achieved by directly converting chemical energy to electricity. Conventional systems burn fuel in an engine and convert the resulting mechanical output to electrical power. Potential applications include stationary multi-megawatt power plants, battery replacements for personal electronics, and even fuel-cell-powered unmanned autonomous vehicles (UAVs). 

The tape-casting method makes possible the fabrication of films in the region of several hundred micrometers thick. The mechanical strength allows the use of such a solid electrolyte as the structural element for devices such as the high-temperature solid oxide fuel cell in which zirconia-based solid electrolytes are employed both as electrolyte and as mechanical separator of the electrodes. 

Other possible applications of smart elastomers are in the area of polymer engine which can produce maximum power density (4 W/g) and output both in terms of electrical and mechanical power without any noise. These features are superior compared to conventional electrical generator, fuel cell, and conventional IC engine. Many DoD applications (e.g., robotics, MAV) require both mechanical and electrical (hybrid) power, and polymer engine can eliminate entire transducer steps and can also save engine parts, weight, and is more efficient. 

Tsipis EV, Kharton VV (2008) Electrode materials and reaction mechanisms in solid oxide fuel cells A brief review I. Performance-determining factors. J Solid State Electrochem 12 1039-1060 II. Electrochemical behavior vs. materials science aspects, ibid 1367-1391... 

Interest in fuel cells has stimulated many investigations into the detailed mechanisms of the electrocatalytic oxidation of small organic molecules such as methanol, formaldehyde, formic acid, etc. The major problem using platinum group metals is the rapid build up of a strongly adsorbed species which efficiently poisons the electrodes. 

Solid mixed ionic-electronic conductors (MIECs) exhibit both ionic and electronic (electron-hole) conductivity. Naturally, in any material there are in principle nonzero electronic and ionic conductivities (a i, a,). It is customary to limit the use of the term MIEC to those materials in which a, and 0, 1 do not differ by more than two orders of magnitude. It is also customary to use the term MIEC if a, and Ogi are not too low (o, a i 10 S/cm). Obviously, there are no strict rules. There are processes where the minority carriers play an important role despite the fact that 0,70 1 exceeds those limits and a, aj,i< 10 S/cm. In MIECs, ion transport normally occurs via interstitial sites or by hopping into a vacant site or a more complex combination based on interstitial and vacant sites, and electronic (electron/hole) conductivity occurs via delocalized states in the conduction/valence band or via localized states by a thermally assisted hopping mechanism. With respect to their properties, MIECs have found wide applications in solid oxide fuel cells, batteries, smart windows, selective membranes, sensors, catalysis, and so on. 

Adsorbed CO on a metal surface is one of the simplest adsorbates and has attracted significant interest within the areas of fundamental surface science, catalysis, and electrochemistry. An understanding of the oxidation mechanism of adsorbed CO is important to design and develop electrocatalysts for fuel cells [69-73] and the surface dynamics of adsorbed CO on electrode surfaces in electrolyte solutions is, therefore, very important. 

Paradoxically, all these significant recent contributions to the theory of the ORR, together with most recent experimental efforts to characterize the ORR at a fuel cell cathode catalyst, have not led at aU to a consensus on either the mechanism of the ORR at Pt catalysts in acid electrolytes or even on how to properly determine this mechanism with available experimental tools. To elucidate the present mismatch of central pieces in the ORR puzzle, one can start from the identification of the slow step in the ORR sequence. With the 02-to-HOOads-to-HOads route appearing from recent DFT calculations to be the likely mechanism for the ORR at a Pt metal catalyst surface in acid electrolyte, the first electron and proton transfer to dioxygen, according to the reaction... 

The potential that develops in an electrochemical system such as a fuel cell can also act to significantly influence the energies, kinetics, pathways, and reaction mechanisms. The double-reference potential DFT method [Cao et al., 2005] described earlier was used to follow the influence of an external surface potential on the reaction... 

Jacob T. 2006a. The mechanism of forming H2O from H2 and O2 over a Pt catalyst via direct oxygen reduction. Fuel Cells 6 159-181. 

One of the critical issues with regard to low temperamre fuel cells is the gradual loss of performance due to the degradation of the cathode catalyst layer under the harsh operating conditions, which mainly consist of two aspects electrochemical surface area (ECA) loss of the carbon-supported Pt nanoparticles and corrosion of the carbon support itself. Extensive studies of cathode catalyst layer degradation in phosphoric acid fuel cells (PAECs) have shown that ECA loss is mainly caused by three mechanisms ... 

Ferreira PJ, Shao-Hom Y. 2007. Formation mechanism of Pt single-crystal nanoparticles in proton exchange membrane fuel cells. Electrochem Solid State Lett 10 B60-B63. 

Igarashi H, Fujino T, Zhu Y, Uchida H, Watanabe M. 2001. CO tolerance of Pt alloy electrocatalysts for polymer electrolyte fuel cells and the detoxification mechanism. Phys Chem Chem Phys 3 306-314. 

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