Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Water reaction with formaldehyde

The initial step is the protonation of the aldehyde—e.g. formaldehyde—at the carbonyl oxygen. The hydroxycarbenium ion 6 is thus formed as reactive species, which reacts as electrophile with the carbon-carbon double bond of the olefinic substrate by formation of a carbenium ion species 7. A subsequent loss of a proton from 7 leads to formation of an allylic alcohol 4, while reaction with water, followed by loss of a proton, leads to formation of a 1,3-diol 3 " ... [Pg.233]

Phenol was originally recovered during the coking of coal, essentially being a by-product. Eventually, commercial routes were developed based on benzene (from coal or petroleum) for example, sulfonation of benzene to ben-zenesulfonic acid followed by reaction with water to phenol plus regenerated sulfuric acid. Phenol is used to make plastics (phenol-formaldehyde and epoxy resins) and textile fibers (nylon). Phenol is also used in solution as a general disinfectant for cleaning toilets, stables, floors, drains, etc. and is used both internally and externally as a disinfectant for animals. [Pg.87]

The last decade has seen quite remarkable advances in our knowledge of the structure and properties of the proanthocyanidins. Viscosity measurements were made of solutions of procyanidins isolated from Theobroma cacao and Chaenomeles speciosa with number-average degrees of polymerization of 6.1 and 11.8, respectively, in water and 1% sodium hydroxide at 25 °C. Procyanidins are apparently completely crosslinked by formaldehyde up to a chain length of 6 units, but few units are crosslinked in polymeric procyanidins. The second order rate constants observed for the formaldehyde reaction with catechin or epicatechin are approximately six times higher than that observed for the C. speciosa polymer. [Pg.172]

Positive Photoresists. Positive resists are entirely different from negative resists. For the purposes of this discussion we restrict ourselves to visible-light-sensitive materials. Typically, these materials are mixtures of low-molecular-weight phenol-formaldehyde polymers and derivatives of naphtho-1,2-quinone diazide, the photosensitive component. The former is soluble in aqueous alkali, but the presence of the latter, a hydrophobic species, inhibits attack of this developer on the film. On irradiation the "sensitizer" is converted to a ketene, which, after reaction with water, forms a base-soluble carboxylic acid. Thus the irradiated part of the film is rendered soluble in the developer and it can be removed selectively. The important feature of this system is that the unirradiated areas are not swollen by the developer and the resolution of this material is quite high. It is possible to prepare gratings having several... [Pg.267]

Conventional positive photoresists consist of a matrix resin and a photoactive compound. The matrix resin is a cresol-formaldehyde novolac resin (structure 3.1) that is soluble in aqueous base solution, and the photoactive compound is a substituted diazonaphthoquinone (structure 3.2) that functions as a dissolution inhibitor for the matrix resin. As outlined in Scheme 3.1 (20), the photoactive compound undergoes a structural transformation upon UV radiation, known as WolflFrearrangement, foUowed by reaction with water... [Pg.119]

Many chemical reactions occur in both directions such that the products are able to re-form the reactants. For instance, in rainfall chemistry, we account for the hydrolysis (i.e. reaction with water) of aqueous formaldehyde (HCHO) to methylene glycol (H2C(OH)2) according to the equation ... [Pg.37]

Methoxide ions serve as a convenient intermediate for the formation of HCHO by thermal decomposition or for the formation of CH3OH by reaction with water. Sleight and co-workers [Ref.20] have convincingly demonstrated that methoxide ions are intermediates in the partial oxidation of methanol to formaldehyde over M0O3 catalysts. In the partial oxidation of CH4 over Mo/Si02 catalysts we suggested that formaldehyde was formed by the direct decomposition of methoxide ions [Ref.l] and the subsequent work of Kahn and Somorjai [Ref.2] on this catalyst provided experimental evidence. [Pg.364]

CHEMICAL PROPERTIES noncombustible solid reacts vigorously with acids and hot water hydrolyzes in hot acid solution elevated temperatures cause a highly exothermic reaction with water dehydrates liquid or solid amides to nitriles liberates ammonia at elevated temperatures and forms imidodisulfonates forms addition products with formaldehyde and aldehydes readily oxidized by bromine and chlorine has flame retardant properties because heat decomposition produces non-inflammable gases decomposes at 200°C (392°F) at 760 mmHg FP (N/A) LFL/UFL(N/A) AT (N/A). [Pg.406]

Aldehydes may be partly protected from further oxidation either by reaction with water to form hydrates (ge/w-diols), a reaction that is highly favored for formaldehyde but less so for higher aldehydes ... [Pg.243]

Reaction of Formaldehyde Vapor with Water-Wetted Wool... [Pg.281]

Tetra-(chloromethyl)-phosphonium chloride (5 g) in 20 mL water was treated with 8 g sodium bicarbonate. The solution became milky and gave a strong formaldehyde reaction with fusion reagent. The phosphine was shaken out with carbon bisulfide, dried over sodium sulfate, and distilled under diminished pressure b.p. 100°C (7 mmHg). While heated at atmospheric pressure, tri-(chloromethyl)phosphine decomposes. It is a colorless, mobile liquid with a powerful, benumbing odor and with slight solubility in water. [Pg.596]

As shown decades ago, formaldehyde also is obtained via a nonelectrochemical reaction at Pt surfaces ([25, 143] and references therein). In acid solution, formaldehyde reacts with water to form the gem-diol H2C(OH)2 [134]. Using a sensitive fluorescence assay, Korzeniewski and Childers [144] followed the formation of gem-diol during the oxidation of methanol out of a 15 mM CH3OH/O.IM HCIO4 solution at smooth platinum for different methanol oxidation potentials. Above 500 mV RHE, a strong drop of the conversion of methanol to the gem-diol is observed. [Pg.508]

Removal of toxic carbon monoxide molecules is a typical depollution reaction, of interest in catalytic exhausts. Furthermore, the reaction with water is of industrial importance in producing clean fuels (hydrogen gas) in a sustainable process., whereas that with hydrogen, via hydride attack and addition of the //+ counter-ion produces formaldehyde. Formaldehyde, i.e., H2CO is a valuable molecule for organic synthesis and solvation. [Pg.91]

If boiled with water an aqueous solution is obtained which, owing to depolymerisation, gives the reactions for formaldehyde. [Pg.344]

In a 500 ml. three-necked flask, fitted with a reflux condenser and mechanical stirrer, place 121 g. (126-5 ml.) of dimethylaniline, 45 g. of 40 per cent, formaldehyde solution and 0 -5 g. of sulphanilic acid. Heat the mixture under reflux with vigorous stirring for 8 hours. No visible change in the reaction mixture occurs. After 8 hours, remove a test portion of the pale yellow emulsion with a pipette or dropper and allow it to cool. The oil should solidify completely and upon boiling it should not smell appreciably of dimethylaniline if this is not the case, heat for a longer period. When the reaction is complete, steam distil (Fig. II, 41, i) the mixture until no more formaldehyde and dimethylaniline passes over only a few drops of dimethylaniline should distil. As soon as the distillate is free from dimethylaniline, pour the residue into excess of cold water when the base immediately solidifies. Decant the water and wash the crystalline solid thoroughly with water to remove the residual formaldehyde. Finally melt the solid under water and allow it to solidify. A hard yellowish-white crystalline cake of crude base, m,p. 80-90°, is obtained in almost quantitative yield. RecrystaUise from 250 ml. of alcohol the recovery of pure pp -tetramethyldiaminodiphenylmethane, m.p. 89-90°, is about 90 per cent. [Pg.987]

At ordinary temperatures, formaldehyde gas is readily soluble in water, alcohols, and other polar solvents. Its heat of solution in water and the lower ahphatic alcohols is approximately 63 kJ/mol (15 kcal/mol). The reaction of unhydrated formaldehyde with water is very fast the first-order rate constant... [Pg.491]


See other pages where Water reaction with formaldehyde is mentioned: [Pg.58]    [Pg.105]    [Pg.47]    [Pg.193]    [Pg.144]    [Pg.58]    [Pg.58]    [Pg.144]    [Pg.144]    [Pg.75]    [Pg.58]    [Pg.333]    [Pg.696]    [Pg.956]    [Pg.703]    [Pg.144]    [Pg.307]    [Pg.227]    [Pg.283]    [Pg.286]    [Pg.134]    [Pg.267]    [Pg.187]    [Pg.608]    [Pg.97]    [Pg.549]    [Pg.121]   


SEARCH



Formaldehyde Water

Formaldehyde reaction

Reaction with formaldehyde

Reaction with water

© 2024 chempedia.info