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Experimental design blocks

The generic features of these approaches are known from experience in anionic polymerization. However, radical polymerization brings some issues and some advantages. Combinations of strategies (a-d) are also known. Following star formation and with appropriate experimental design to ensure dormant chain end functionality is retained, the arms may be chain extended to give star block copolymers (321). In other cases the dormant functionality can be retained in the core in a manner that allows synthesis of mikto-arm stars (324). [Pg.549]

The experimental design was a randomized complete block with eleven treatments, two soybean varieties and five blocks (reps). The experiment was conducted six times at two week intervals, starting four weeks after the weeds were planted in the pipes. [Pg.237]

Statistical experimental design is characterized by the three basic principles Replication, Randomization and Blocking (block division, planned grouping). Latin square design is especially useful to separate nonrandom variations from random effects which interfere with the former. An example may be the identification of (slightly) different samples, e.g. sorts of wine, by various testers and at several days. To separate the day-to-day and/or tester-to-tester (laboratory-to-laboratory) variations from that of the wine sorts, an m x m Latin square design may be used. In case of m = 3 all three wine samples (a, b, c) are tested be three testers at three days, e.g. in the way represented in Table 5.8 ... [Pg.134]

In this chapter we explore factorial-based experimental designs in more detail. We will show how these designs can be used in their full factorial form how factorial designs can be taken apart into blocks to minimize the effect of (or, if desired, to estimate the effect of) an additional factor and how only a portion of the full factorial design (a fractional replicate) can be used to screen many potentially useful factors in a very small number of experiments. Finally, we will illustrate the use of a Latin square design, a special type of fractionalized design. [Pg.317]

The appropriate analysis of data obtained from an experiment should be determined by the experimental design used to obtain those data. The fundamental characteristic of split-plot designs is that there are experimental units of different sizes and consequently multiple sources of variation. The analysis needs to take account of this structure and include multiple error terms and to test the significance of effects and interactions against the appropriate error term. This has been illustrated above with the three experimental arrangements for split-plot and strip-block designs. [Pg.70]

Block in experimental design, a group of items under treatment or observation. [Pg.108]

Blocking - [AMIDES, FATTY ACID] (Vol 2) -m experimental design [DESIGN OF EXPERIMENTS] (Vol 7) -in PVAc [VINYL POLYMERS - VINYL ACETATE POLYMERS] (Vol 24)... [Pg.119]

Figure 1.1 Block diagram illustrating modification of experimental design using feedback from previous experiments. Figure 1.1 Block diagram illustrating modification of experimental design using feedback from previous experiments.
A parallel setup is generally recommended, in which a different NMR tube is used for each measurement temperature (Table D3.1.1). However, when the amount of sample is limited, it may be necessary to use a serial rather than parallel experimental design. In a serial measurement, after measuring a sample at the first (lowest) temperature, it is transferred to the next warmest tempering block, held at the measurement temperature for the appropriate incubation time, and then remeasured. The process is repeated until the entire temperature range has been covered. Note that the solid fat content of a given sample is a function of thermal history, so serial and parallel measurements may give dissimilar results. [Pg.569]

Another useful experimental design for minimizing the effects of two types of inhomogeneity is the Youden square design. Latin squares must have the same number of levels for both of the blocking factors and the treatment factor Youden squares must have the same number of levels for the treatment factor and one of the blocking factors, but the number of levels for the other blocking factor can be... [Pg.250]

There are two competing and equivalent nomenclature systems encountered in the chemical literature. The description of data in terms of ways is derived from the statistical literature. Here a way is constituted by each independent, nontrivial factor that is manipulated with the data collection system. To continue with the example of excitation-emission matrix fluorescence spectra, the three-way data is constructed by manipulating the excitation-way, emission-way, and the sample-way for multiple samples. Implicit in this definition is a fully blocked experimental design where the collected data forms a cube with no missing values. Equivalently, hyphenated data is often referred to in terms of orders as derived from the mathematical literature. In tensor notation, a scalar is a zeroth-order tensor, a vector is first order, a matrix is second order, a cube is third order, etc. Hence, the collection of excitation-emission data discussed previously would form a third-order tensor. However, it should be mentioned that the way-based and order-based nomenclature are not directly interchangeable. By convention, order notation is based on the structure of the data collected from each sample. Analysis of collected excitation-emission fluorescence, forming a second-order tensor of data per sample, is referred to as second-order analysis, as compared with the three-way analysis just described. In this chapter, the way-based notation will be arbitrarily adopted to be consistent with previous work. [Pg.478]

Calibration involves connecting one (or more) sets of variables together. Usually one set (often called a block ) is a series of physical measurements, such as some spectra or molecular descriptors and the other contains one or more parameter such as the concentrations of a number of compounds or biological activity. Can we predict the concentration of a compound in a mixture spectrum or the properties of a material from its known structural parameters Calibration provides the answer. In its simplest form, calibration is simply a form of regression as discussed in Chapter 3, in the context of experimental design. [Pg.271]

We will refer to physical measurements of die form in Table 5.1 as the A block and those in Table 5.2 as the c block. One area of confusion is that users of different techniques in chemometrics tend to employ incompatible notation. In the area of experimental design it is usual to call the measured response v e.g. the absorbance in a spectrum, and the concentration or any related parameter V. In traditional multivariate calibration this notation is swapped around. For die purpose of a coherent text it would be confusing to use two opposite notations however, some compatibility widi die established literature is desirable. Figure 5.1 illustrates the notation used in this text. [Pg.273]

Homonuclear or heteronuclear Hartmann-Hahn mixing periods are versatile experimental building blocks that form the basis of a large number of combination experiments (see Section XIII). In practice, the actual multiple-pulse sequence that creates Hartmann-Hahn mixing conditions can usually be treated as a black box with characteristic properties. In this section, design principles and practical approaches for the development of Hartmann-Hahn mixing sequences are discussed. [Pg.139]


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Blocking experimental design

Experimental Design Chart for Block-Between Method

Experimental Design Randomised Blocks

Experimental design

Experimental design designs

Experimental design randomized complete block

Incomplete block design, experimental

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