Mixing conditions

The statement of the mixing condition is equivalent to the followhig if Q and R are arbitrary regions in. S, and an ensemble is initially distributed imifomily over Q, then the fraction of members of the ensemble with phase points in R at time t will approach a limit as t —> co, and this limit equals the fraction of area of. S occupied by... 

Factors such as reaction temperature, excess of oxygen, water addition, addition of other minor reactants, eg, AlCl to promote the formation of mtile, mixing conditions inside the reactor, and many others influence the quaUty of Ti02 pigment. In general, titanium white pigments produced by the chloride process exhibit better lightness than those produced by the sulfate process. 

The constant may depend on process variables such as temperature, rate of agitation or circulation, presence of impurities, and other variables. If sufficient data are available, such quantities may be separated from the constant by adding more terms ia a power-law correlation. The term is specific to the Operating equipment and generally is not transferrable from one equipment scale to another. The system-specific constants i and j are obtainable from experimental data and may be used ia scaleup, although j may vary considerably with mixing conditions. Illustration of the use of data from a commercial crystallizer to obtain the kinetic parameters i, andy is available (61). 

In moving catalyst basket reactors, the flow regime is ill-defined and the contact between catalyst and gas can be poor even if well-mixed conditions for the fluid phase are achieved. Perhaps the most successful representative of this category is the Carberry reactor (1964, 1966). Even in this model only a single layer of catalyst can be charged in the cruciform catalyst basket because the fluid flows in a radial direction outward and... 

Oxygen concentration is an especially important parameter to metals exposed to aqueous environments. Temperature and temperature gradients should also be reproduced as closely as possible. Concentration gradients in solutions also should be reproduced closely. Careful attention should be given to any movement of the corrosive medium. Mixing conditions should be reproduced as closely as possible. 

Adding a recirculating loop to the transport reactor, a well-mixed condition is achieved provided the recirculation rate is large with... 

Consider any two gas streams A and B which, when combined, produce a mixed condition C. 

The reactor has been successfully used in the case of forced precipitation of copper and calcium oxalates (Jongen etal., 1996 Vacassy etal., 1998 Donnet etal., 1999), calcium carbonate (Vacassy etal., 1998) and mixed yttrium-barium oxalates (Jongen etal., 1999). This process is also well adapted for studying the effects of the mixing conditions on the chemical selectivity in precipitation (Donnet etal., 2000). When using forced precipitation, the mixing step is of key importance (Schenk etal., 2001), since it affects the initial supersaturation level and hence the nucleation kinetics. A typical micromixer is shown in Figure 8.35. 

Both operating conditions (viz. precipitant dosage rate) and mixing conditions (viz. precipitant dilution and vessel size) affect the crystai size distribution... 

The scale-up exponent, n, is given for typical mixing conditions in Figure 5-32. 

When two samples of air are brought together the condition of the mixture may be arrived at arithmetically by adding the heat flow of each and dividing by the total mass flow and similarly for the moisture flow. Alternatively, plot the condition of each onto a psychrometric chart. The mixed condition lies on a straight line between the two in a position proportional to the two quantities. 

Mixed conditioning has also been used. In this, one part of the circuit (usually the low-pressure system) is dosed conventionally, e.g. with hydrazine/ammonia, whilst the high-pressure system is subjected to oxygenated conditions. 

The above-described laws of filler distribution in heterogeneous mixtures of polymers are true when the particle size is significantly less than the size of the polymer zones in such mixtures (1 to 10 p). So, powders of graphite and molibdenum (Ss = = 2 m2/g) are distributed equally uniformly in all the studied mixtures of polymers irrespective of the mixing conditions for in this case the particle size is comparable with the size of the polymer zones. 

Advantages. Polarization measurements permit continuous binding analysis with subsecond resolution if required. When applied in stop-flow mixing conditions the technique has the best time resolution of the methods presently available. 

FIGURE 16.2 Mild-mixing conditions do not discriminate between peptizers (P-44 and R-11) and the control compound. While QDI-containing compounds show significant viscosity reduction. 

Goodrich heat buildup shows some discrimination between the QDI-containmg compounds and the others under both mild and oxidative mixing conditions. Figure 16.4 shows the delta temperature... 

The dump temperature of the compound was varied by changing the mixer s rotor speed and fill factor while keeping the other mixing conditions and the mixing time constant. Under the assumption that the final dump temperature is the main parameter influencing the degree of the sUanization reaction, the effect of the presence of ZnO on the dynamic and mechanical properties of the compound was investigated. ZnO was either added on the two-roll mill or in the mixer. 

In our previous paper [6], the authors have demonstrated that production of fine silica powder is possible by phase hydrolpis of tetramethoxysilane fTEMS). In this communication, we report the effect of the shape of reactor and operational condition, especially mixing condition on conversion of the reaction and properties especially diameter of produced silica fines. 

Shapes are different, so mixing conditions differ, the more so because different types of... 

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