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Experimental calibration

The state of research on the two classes of acetylenic compounds described in this article, the cyclo[ ]carbons and tetraethynylethene derivatives, differs drastically. The synthesis of bulk quantities of a cyclocarbon remains a fascinating challenge in view of the expected instability of these compounds. These compounds would represent a fourth allotropic form of carbon, in addition to diamond, graphite, and the fullerenes. The full spectral characterization of macroscopic quantities of cyclo-C should provide a unique experimental calibration for the power of theoretical predictions dealing with the electronic and structural properties of conjugated n-chromophores of substantial size and number of heavy atoms. We believe that access to bulk cyclocarbon quantities will eventually be accomplished by controlled thermal or photochemical cycloreversion reactions of structurally defined, stable precursor molecules similar to those described in this review. [Pg.73]

An added benefit of the direct SEC-[n] calibration approach is that a new independent way of determining K and a values, using only broad MW standards, has also resulted. As few as three standards (or four, if all are narrow MWD) are needed to obtain both MW and [x]] calibration curves for a particular polymer-solvent system by using the broad-standard, linear calibration approach. From the experimental calibration constants of the two calibration curves, one can calculate K and a directly as described later. [Pg.92]

For evaluation of multisignal measurements, e.g. in OES and MS, more than one signal per analyte can be evaluated simultaneously by means of multiple and multivariate calibration. The fundamentals of experimental calibration and the relating models are given in Chap. 6. [Pg.62]

Depending on the type of relationships between the measured quantity and the measurand (analytical quantity) it can be distinguished (Danzer and Currie [1998]) between calibrations based on absolute measurements (one calibration is valid for all1 on the basis of the simple proportion y = b x, where the sensitivity factor b is a fundamental quantity see Sect. 2.4 Hula-nicki [1995] IUPAC Orange Book [1997, 2000]), definitive measurements (b is given either by a fundamental quantity complemented by an empirical factor or a well-known empirical (transferable) constant like molar absorption coefficient and Nernst factor), and experimental calibration. [Pg.150]

In the simplest case, experimental calibration can be carried out by direct reference measurements where the sensitivity factor b is given by the relation of measured value to concentration of a reference material (RM), b = yRvi/xRv,. Direct reference calibration is frequently used in NAA and X-ray analytical techniques (XRF, EPMA, TXRF). [Pg.150]

Precision. The precision of the calibration is characterized by the confidence interval cnffyf of the estimated y values at position x, according to Eq. (6.30). In contrast, the precision of analysis is expressed by the prediction intervals prd(y ) and prd(x,), respectively, according to Eqs. (6.32) and (6.33). The precision of analytical results on the basis of experimental calibration is closely related to the adequacy of the calibration model. [Pg.168]

In case of experimental calibration, the uncertainty of both the blank and the calibration coefficient, U (JBL, fi), have to be consider, e.g. according to... [Pg.229]

Statistical interval, e.g., of a mean, x, prdfx) = x Axprd, that express the uncertainty of analytical values which are predicted on the basis of experimental calibration. Pis are applied for significance tests and to establish quantities for limit values (LD, LQ). [Pg.318]

In addition, very few observations are pristine and basic measurements such as angular deviation of a needle on a display, linear expansion of a fluid, voltages on an electronic device, only represent analogs of the observation to be made. These observations are themselves dependent on a model of the measurement process attached to the particular device. For instance, we may assume that the deviation of a needle on a display connected to a resistance is proportional to the number of charged particles received by the resistance. The model of the measurement is usually well constrained and the analyst should be in control of the deterministic part through calibration, working curves, assessment of non-linearity, etc. If the physics of the measurement is correctly understood, the residual deviations from the experimental calibration may be considered as random deviates. Their assessment is an integral part of the measurement protocol and the moments of these random deviations should be known to the analyst and incorporated in the model. [Pg.248]

All other factors are constants. The angle 9 is the projection angle between bond vectors and is the sole unknown in Eq. 1, and can be readily and precisely determined by measurement of the cross-correlated dipolar relaxation rate. It should be emphasized that 9 is measured directly, without the need of experimental calibration as in the Karplus curve for J-coupling constants for example. [Pg.3]

Ferry J. M. and Spear F. S. (1978). Experimental calibration of the partitioning of Fe and Mg between biotite and garnet. Contrib. Mineral Petrol, 66 113-117. [Pg.828]

Powenceby M. L, Wall V. J. and O Neill H. St. C. (1987). Fe-Mn partitioning between garnet and ilmenite Experimental calibration and applications. Contrib. Mineral Petrol, 97 116-126. [Pg.849]

Figure 10. Predicted and experimental calibration curves for a column set consisting of one lOOA and one lO A Ultrastyragel column (see legend). Figure 10. Predicted and experimental calibration curves for a column set consisting of one lOOA and one lO A Ultrastyragel column (see legend).
In general, experimental calibrations of isotope geothermometers have been performed between 250 and 800°C. The upper temperature limit is usually determined by the stability of the mineral being studied or by limitations of the experimental apparatus, whereas the lower temperature limit is determined by the decreasing rate of exchange. [Pg.22]

In summary, as discussed by Vennemann and O Neil (1996), discrepancies between published experimental calibrations in individual mineral-water systems are difficult to resolve, which limits the application of D/H fractionations in mineral-water systems to estimate 5D-values of coexisting fluids. [Pg.41]

Bermin J, Vance D, Archer C, Statham PJ (2006) The determination of the isotopic composition of Cu and Zn in seawater. Chem Geol 226 280-297 Berndt ME, Seal RR, Shanks WC, Seyfried WE (1996) Hydrogen isotope systematics of phase separation in submarine hydrothermal systems experimental calibration and theoretical models. [Pg.232]

Liebscher A, Meixner A, Romer R, Heinrich W (2005) Liquid-vapor fractionation of boron and boron isotopes experimental calibration at 400°C/23 Mpa to 450°C/42Mpa. Geochim Cosmochim Acta 69 5693-5704... [Pg.256]

SchilBler JA, Schoenberg R, Behrens H, von Blanckenburg F (2007) The experimental calibration of iron isotope fractionation factor between pyrrhotite and peralkahne rhyolitic melt, Geochim Cosmochim Acta 71 417 33... [Pg.269]

Shackleton NJ, Hall MA, Line J, Gang S (1983) Carbon isotope data in core V19-30 confirm reduced carbon dioxide concentration in the ice age atmosphere. Nature 306 319-322 Shahar A, Young ED, Manning CE (2008) Equihbrium high-temperature Fe isotope fractionation between fayalite and magnetite an experimental calibration. Earth Planet Sci Lett 268 ... [Pg.270]

Fig. 5. Experimental calibration of a 15 ms E-BURP-1 around the optimum amplitude value on a DMX300. (Top) Excerpt of the one-dimensional spectrum of BPTI. (Bottom) Same region centered around 7 ppm excited by a 15 ms E-BURP-1 with amplitudes increasing from left to right by 1 dB steps. The optimum is located at the intermediate value (determined by smaller amplitude steps, typically of 0.1 dB). Fig. 5. Experimental calibration of a 15 ms E-BURP-1 around the optimum amplitude value on a DMX300. (Top) Excerpt of the one-dimensional spectrum of BPTI. (Bottom) Same region centered around 7 ppm excited by a 15 ms E-BURP-1 with amplitudes increasing from left to right by 1 dB steps. The optimum is located at the intermediate value (determined by smaller amplitude steps, typically of 0.1 dB).
FIGURE 11.62 Experimental calibration curves for a commercial single-particle counter and two types of calibration aerosols dioctyl phthalate (DOP) and coal dust (adapted from Whitby and Willeke, 1979). [Pg.614]

Horvath, H., Experimental Calibration for Aerosol Light Absorption Measurements Using the Integrating Plate Method— Summary of the Data, Aerosol Sci., 28, 1149-1161 (1997). [Pg.645]

The advantage of the technique is that the particle size may be determined with the sample in a controlled atmosphere and at a temperature different from 300 K, i.e., in situ particle size measurement, and measurement of changes in particle size may be possible. The problem, however, is that the quantitative relation between the Mossbauer parameters and particle size is rather complex and in some cases not theoretically available. Therefore, the application of the Mossbauer effect to particle size measurement is often facilitated through an experimental calibration of the Mossbauer parameters to particle size for the particular catalyst system of interest, i.e., the measurement of the parameters for a set of samples of known particle size as determined by other experimental methods. This point will become clearer below, as the effects of particle size on the Mossbauer parameters are discussed. [Pg.180]

This internal pressure effect may actually be quite general in Mbssbauer effect studies of small particles, as discussed by Schroeer et al. for the recoil-free fraction (156) and the isomer shift (157). In addition, Schroeer (152) has summarized a number of origins for Mossbauer parameters being particle size dependent. Thus, from the above discussion, it seems apparent that a priori particle size determination using the recoil-free fraction, quadrupole splitting, or isomer shift is not possible for an arbitrary catalytic system. However, the "experimental calibration of these parameters, which not only facilitates particle size measurement, may also provide valuable information about the chemical state (e.g., electronic, defect, stress) of the small particles. This point will be illustrated later. [Pg.182]

The actual solution for both transient and steady-state response of any zero-flux-boundary sensor can be obtained by solving (2.26) through (2.33) for the appropriate boundary and initial conditions. Fitting of the experimental calibration curves (Fig. 2.10) and of the time response curves (Fig. 2.11) to the calculated ones, validates the proposed model. [Pg.37]

The verification of the model is again performed by fitting the experimental calibration (Fig. 2.15) and time response (Fig. 2.16) curves. [Pg.40]

The second group consists of algorithms associated with the pesticide concentration quantification. In this case, the initial data is the processed sensor response for an unknown pesticide concentration and the parameters of the calibration curve (which is derived from preliminary experimental calibration measurements for a range of standard pesticide concentrations) or alternatively, a set of sensor responses obtained by addition of known amounts of pesticide to the analysed sample. This group of algorithms allows the automation of the pesticide quantification, thereby enabling the use of the instrumentation by unskilled personal. This removes the sensing platform from specialised laboratories to the realm of the end-users. [Pg.324]

White RMP, Dennis PF, Atkinson TC (1999) Experimental calibration and field investigation bof the oxygen isotopic fractionation between biogenic aragonite and water. Rapid Comm Mass Spec 13 1242-1247... [Pg.153]


See other pages where Experimental calibration is mentioned: [Pg.188]    [Pg.81]    [Pg.55]    [Pg.150]    [Pg.151]    [Pg.328]    [Pg.183]    [Pg.363]    [Pg.15]    [Pg.92]    [Pg.302]    [Pg.182]    [Pg.22]    [Pg.22]    [Pg.93]    [Pg.523]    [Pg.180]    [Pg.181]    [Pg.185]    [Pg.186]    [Pg.700]   
See also in sourсe #XX -- [ Pg.124 ]

See also in sourсe #XX -- [ Pg.124 ]




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