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Ethylene chlorohydrin 2-chloro

Hydrolysis to Glycols. Ethylene chlorohydrin and propylene chlorohydrin may be hydrolyzed ia the presence of such bases as alkaU metal bicarbonates sodium hydroxide, and sodium carbonate (31—33). In water at 97°C, l-chloro-2-propanol forms acid, acetone, and propylene glycol [57-55-6] simultaneously the kinetics of production are first order ia each case, and the specific rate constants are nearly equal. The relative rates of solvolysis of... [Pg.73]

Oxidation. Monochloroacetic acid [79-11-8] may be synthesized by the reaction of ethylene chlorohydrin with nitric acid [7697-37-2]. Yields of greater than 90% are reported (41). >Beta-chlorolactic acid (3-chloro-2-hydroxypropanoic acid) [1713-85-5] is produced by the reaction of nitric acid with glycerol monochlorohydrin (42). Periodic acid [10450-60-9] and glycerol monochlorohydfin gives chloroacetaldehyde [107-20-0] ia 50% yield (43). [Pg.73]

The merchant market for chi orohydrin s is small, primarily for specialty appHcations. Ethylene chlorohydrin is sold ia the United States by BASF Corp., Parsippany, N.J., available ia 230 kg net lined steel dmms. Glycerol monochlorohydrin (3-chloro-l,2-propanediol) is available from Dixie Chemical Co., Houston, Tex., in lined steel dmms (227.3 kg net) from Raschig Corp., Richmond, Va. and from Henley Chemicals, Inc., Montvale, N.J., ia steel dmms (240 kg net). Glycerol dichi orohydrin (l,3-dichloro-2-propanol) is not currentiy being produced for the U.S. merchant market but has been available ia the past at a selling price of 5—6/kg. [Pg.75]

Chloro-1 -nitropropane Chloroacetaldehyde a-Chloroacetophenone Chlorobenzene (monochlorobenzene) o-Chlorobenzylidine malononitrile Chlorobromomethane Chlorodiphenyl (42% chlorine) Chlorodiphenyl (54% chlorine) 2-Chloroethanol (ethylene chlorohydrin) Chloroform... [Pg.366]

The manufacture of a related compound is first described. 28.1 parts of p-chloro-benzhy-dryl bromide are heated to boiling, under reflux and with stirring, with 50 parts of ethylene chlorohydrin and 5.3 parts of calcined sodium carbonate. The reaction product is extracted with ether and the ethereal solution washed with water and dilute hydrochloric acid. The residue from the solution in ether boils at 134° to 137°C under 0.2 mm pressure and is p-chloro-benzhydryl-(/3-chloroethyl) ether. [Pg.375]

Chloro-2,3-epoxypropane, see Epichlorohydrin Chloroethane, see Ethyl chloride Chloroethanol, see Ethylene chlorohydrin Chloromethane, see Methyl chloride Chloronaphthalene 1.19 5.6 132 >558... [Pg.120]

Chloro,2,3,-Epoxypropane, see Epichlorohydrin 2- Chloroethanol, see Ethylene chlorohydrin Chloroethylene, see Vinyl chloride Chloroform (trichloromethane) 13.0... [Pg.237]

Chloro-l-ethanal, see Chloroacetaldehyde 2-Chloroethanol, see Ethylene chlorohydrin... [Pg.1472]

Ethylene Chlorohydrin. See Chloroethanol or Chloro Ethyl Alcohol in Vol 3, p C254. Its Nitrite, Nitrate, 2 Nitro- and 2-Nitro-niixaterderivs are described on p C255... [Pg.107]

The solvents more generally used are oil of turpentine, pinewood oil, methyl, ethyl or amyl alcohol, amyl acetate, acetone, ether, carbon disulphide, carbon tetrachloride, chloro-derivatives of ethane and ethylene, chlorohydrins, light mineral oils, light oils from tar, from resin or from shale, and camphor oil. [Pg.313]

The monomers may be prepared by the reaction of the 5-(2H-benzo-triazole-2-yl)-2,2, 4,4 -tetrahydroxybenzophenone and its chloro and meth-oxy derivatives with allyl bromide, acryloyl chloride, methacryloyl chloride, glycidyl acrylate, and ethylene chlorohydrin. °... [Pg.312]

Chloro-1-(3-ethoxy4-nitrophenoxy)-4-(trifluoromethyl) benzene. See Ox luorfen 2-Chloroethyl alcohol p-Chloroethyl alcohol. See Ethylene chlorohydrin 2-Chloroethylamine hydrochloride CAS 870-24-6 EINECS/ELINCS 212-793-2 Synonyms 2-Aminoethyl chloride hydrochloride p-Chloroethylamine hydrochloride 2-Chloroethylammonium chloride... [Pg.889]

Ethylchlorohydrin. See Ethylene chlorohydrin Ethyl 4-chloro-2-oxo-3(2H)-benzothiazoleacetate. See Benazol in-ethyl Ethyl cinnamate... [Pg.1698]

Room temperature trifluoroethanol, trichloroethanol, phenols, chloral hydrate, formic acid, chloro-acetic acid, HF, HCl, methanol, H2SO4, phosphoric add, benzyl alcohol, ethylene chlorohydrin, 1,3 chloropropanol, 2-butene-l,4,diol., diethylene glycol, acetic acid, formamide, DMSO... [Pg.191]

Chloro, 2, 3-epoxypropane See Epichlorohydrin. 2- Chloroethanol See Ethylene chlorohydrin. Chloroethylene See Vinyl chloride. Chloroform (Trichloromethane) 67-66-3 (C)50 (C)240 ... [Pg.76]

Numerous ethers of cellulose, starch, and bacterial dextran are of established or potential industrial importance. (See also Chapter XII.) Treatment of the polysaccharides with alkali and methyl chloride, ethyl chloride, benzyl chloride, ethylene oxide (or ethylene chlorohydrin), sodium chloro-acetate, and allyl bromide gives, respectively, the methyl, ethyl, benzyl, hydroxy ethyl, carboxy methyl, and allyl ethers. The cellulose derivatives... [Pg.368]

J. McCann, V. Simmon, D. Streitwieser, and B. N. Ames, Mutagenicity of chloroacetal-dehyde, a possible metabolic product of 1,2-dichloroethane (ethylene dichloride), chloro-ethanol (ethylene chlorohydrin), vinyl chloride, and cyclophosphamide, Proc. Natl. Acad. Sci. U.S.A. 72,3190-3193 (1975). [Pg.467]

Chloro-l,3-Propanediol Ethylene Chlorohydrin Glycerol Chlorohydrin Soda Ash Sodium Carbonate... [Pg.3486]

Formation of Cyclic Carbonates. In the absence of water, chlorohydrins such as 2-chloroethanol and l-chloro-2-propanol react with an alkah carbonate or bicarbonate to produce cycHc carbonates such as ethylene carbonate [96-49-1] and propylene carbonate [108-32-7] ia yields of up to 80%... [Pg.73]

The Carbide and Carbon Co began large scale manuf of EtnO thru ethylene chloro-hydrin in 1925 and by the direct oxidation of ethylene in 1937. Dow entered the field in 1939 Si 1941 Jefferson and Wyandotte in 1941 and Mathieson Chem Corp in 1951. These four Co s used the chlorohydrin method. US consumption, which was in 1939 108 million pounds, increased in 1949 to 354 million Several laboratory methods of prepn are described in Ref 17, pp 75—7. In one of them hydroxide is added gradually to a soln of 2-chloroethyI acetate heated to a temp betwn 40 150°C. An excess of unreacted base is avoided. The reaction proceeds as follows ... [Pg.156]

B) Examination of the Solvents insoluble in Water. These may be carbon disulphide, chloroform, carbon tetrachloride, a chloro-derivative of ethane or ethylene, a chlorohydrin, amyl alcohol, amyl acetate, ether, benzene or a homologue, oil of turpentine, pinewood oil, light mineral oil, resin oil, tar oil, shale oil, or camphor oil. [Pg.316]

Aiyl-substituted ethylene oxides have also been prepared. The simplest of these is styrene oxide, which is prepared by the alkali treatment of the iodohydrin made by the action of iodine, water, and mercuric oxide on styrene (51%). Aryl chlorohydrins resulting from the action of chloro-acetone and aromatic Grignard reagents, C,Hj (CHj)nMgX, have been converted by alkali or sodium ethoxide to oxides of the type... [Pg.578]


See other pages where Ethylene chlorohydrin 2-chloro is mentioned: [Pg.66]    [Pg.85]    [Pg.11]    [Pg.223]    [Pg.259]    [Pg.956]    [Pg.958]    [Pg.272]    [Pg.1077]    [Pg.1079]    [Pg.1238]    [Pg.589]    [Pg.314]    [Pg.58]   


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