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Glycerol chlorohydrin

HVP products prepared by hydrolysis with HCl contain varying amounts of glycerol chlorohydrins, such as 3-chloro-l,2-propanediol [96-24-2] and l,3-dichloro-2-propanol [96-23-1J, depending on reaction conditions and Hpid contents of the starting material (135). As a result of their toxicides, regulating agencies in many countnes have restncted the contents of these compounds in food. [Pg.470]

Glutaronitrile, 3-hydroxy-, 46, 48 Glycerol chlorohydrin, 46, 24 Glycine (-butyl ester, 45, 47 conversion to acetamidoacetone, 45,1 Glyoxal, phenyl-, 48,109 Glyoxals from esters and the potassium salt of dimethyl sulfoxide, 48, 112... [Pg.75]

The original preparation of y-crotonolactone by Lespieau involved a five-step sequence from epichlorohydrin and sodium cyanide. A recent detailed study of this procedure reported an overall yield of 25% for the lactone. Glattfeld used a shorter route from glycerol chlorohydrin and sodium cyanide hydrolysis and distillation of the intermediate dihydroxy acid yielded y-cro-tonolactone in 23% yield and -hydroxy-y-butyrolactone in 28% yield. The formation of y-crotonolactone in 15% yield has also been reported from pyrolysis of 2,5-diacetoxy-2,5-dihydrofuran at 480-500 . ... [Pg.13]

Glycerol chlorohydrin (1) reacts with lithium fluoride at 140-16(L C in the presence of light to give the corresponding fluorohydrin 2 in moderate yield.2... [Pg.548]

SYNS a-CHLORHYDRlN CHLORODEOXY-GLYCEROL 1-CHLORO-2.3-DIHYDROXYPROPANE 3-CHLORO-1.2-DIHYDROXYPROPANE a-CHLOROHYDRIN l-CHLOROPROPANE-2,3-DIOL I-CHLORO-23-PROPANEDIOL 3-CHLOROPROPANE-1,2-DIOL 3-CHLORO-1.2-PROPANEDIOL 3-CHLOROPROPYLENE GYLCOL Q P, 3 -DIHYDROXY-ISOPROPYL CHLORIDE 2,3-DIHYDROXYPROPYL CHLORIDE EPIBLOC GLYCERIN-a-MONOCHLOR-HYDRIN GLYCEROL CHLOROHYDRIN GLYCEROL-a-CHLOROHYDRIN GLYCEROL-a-MONOCHLOROHYDRIN (DOT) GLYCERYL-o-CHLOROHYDRIN MONOCHLORHYDRIN MONOCHLOROHYDRIN a-MONOCHLOROHYDRIN D U-5897... [Pg.311]

Among the industrially important chlorohydrins are ethylene, propylene, and glycerol chlorohydrins. The methods of preparing... [Pg.286]

Smdies on rats indicated that high exposure levels to glycerol chlorohydrin can give rise to thyroid tumors. [Pg.290]

Analogous to the synthesis of l,4-benzodioxepin-5-ones, the benzoxathiepinones (166) were prepared by the reaction of ethyl 2-thiobenzoates with chlorohydrin and glycerol chlorohydrin and cyclization of intermediate (165) (Scheme 17) <75BSF277>. The sodium borohydride reduction of bienzoxathiepinone (167) has also been studied <82NJC149>. [Pg.286]

Chloropropylene glycol 1-Choropropane-2,3-diol p,P -Dihydroxyisopropyl chloride 2,3-Dihydroxypropyl chloride Glycerin-a-monochlorhydrin Glycerol chlorohydrin Glycerol-a-monochlorohydrin 1,2-Propanediol, 3-chloro-Classification Nonaromatic alcohol Empirical C3H7CIO2 Formula CICH2CHOHCH2 Properties Colorless or pale yel. liq. sol. in water, DMSO, 95% ethanol, acetone, ether, polar soivs. immisc. with oils m.w. 110.54 sp.gr. 1.326 (18/15 C) vapor pressure 3.75 mm Hg (25 C) m.p. -40 C b.p. 213 C (dec.) flash pt. 58 C ref. index 1.4809 (20 C)... [Pg.1911]

C3H7CIO2 96-24-2. alpha.-Glycerol chlorohydrin see 3-Chloropropan-l,2-diol... [Pg.50]

Pearson, A.M., Young, R.B. Muscle and meat biochemistry. Academic Press San Diego, CA. 1989 Piasecki, A., Ruge, A., Marquardt, H. Malignant transformation of mouse M2-fibroblasts by glycerol chlorohydrines contained in protein hydrolysates and commercial food. Arzneim.-Forsch./Drug. Res. 40, 1054 (1990)... [Pg.615]

Shahidi, R Flavor of meat tmd meat products. Blackie Academic Professiontil, London, 1994 Silhankova, L., Smid, R, Cema, M., Davidek, J., Velisek, J. Mutagenicity of glycerol chlorohydrines and of their esters with higher fatty acids present in protein hydrolysates. Mutation Resetirch 103,11 (1982)... [Pg.615]

Ethylhexyl Alcohol 104-76-7 Glycerol Chlorohydrin 497-04-1 Hydrogen Cyanate 420-05-3... [Pg.3476]

Chloro-l,3-Propanediol Ethylene Chlorohydrin Glycerol Chlorohydrin Soda Ash Sodium Carbonate... [Pg.3486]

Glycerol Chlorohydrin glycerol monochlorohydrin 100 25 >30 6 Resistant -0.3-2 85-115 Solef Solvay Polymers Specimen Solef 1008, 1010 and 1012, 2 mm thick test pieces... [Pg.323]

See other pages where Glycerol chlorohydrin is mentioned: [Pg.66]    [Pg.1706]    [Pg.526]    [Pg.996]    [Pg.1902]    [Pg.707]    [Pg.963]    [Pg.520]    [Pg.3386]    [Pg.3403]    [Pg.3410]    [Pg.1606]    [Pg.1616]    [Pg.1620]    [Pg.1662]    [Pg.256]   
See also in sourсe #XX -- [ Pg.24 , Pg.46 ]

See also in sourсe #XX -- [ Pg.24 , Pg.46 ]

See also in sourсe #XX -- [ Pg.24 , Pg.46 ]

See also in sourсe #XX -- [ Pg.24 , Pg.46 ]

See also in sourсe #XX -- [ Pg.24 , Pg.46 ]



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