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A-Glycerol Monochlorohydrin

To 500 cc. of absolute alcohol (Note i) in a i-l. flask fitted with a reflux condenser is added gradually 46 g. (2 moles) of sodium in thin slices (Note 2) at such a rate that the mixture boils steadily. When all the sodium has been added, the mixture is heated on the steam bath until the few remaining pieces of sodium barely react. Pure commercial molten phenol is now added gradually through the condenser until all of the sodium has reacted, and then the remainder of 188 g. (2 moles) of phenol is added. This is followed by the addition of 221 g. (2 moles) of redistilled glycerol a-monochlorohydrin (Org. Syn. 2, 33) in small portions, the rather vigorous reaction being allowed to complete itself before each subsequent addition. [Pg.48]

Glutaraldehyde, gl6 Glycerol dichlorohydrin, d264 Glycerol a-monochlorohydrin, c227 Glyceryl triacetate, p200... [Pg.231]

Glycerol a-monochlorohydrin, c212 Glyceryl triacetate, p201 Glyceryl tris(laurate), g20... [Pg.257]

SYNS a-CHLORHYDRlN CHLORODEOXY-GLYCEROL 1-CHLORO-2.3-DIHYDROXYPROPANE 3-CHLORO-1.2-DIHYDROXYPROPANE a-CHLOROHYDRIN l-CHLOROPROPANE-2,3-DIOL I-CHLORO-23-PROPANEDIOL 3-CHLOROPROPANE-1,2-DIOL 3-CHLORO-1.2-PROPANEDIOL 3-CHLOROPROPYLENE GYLCOL Q P, 3 -DIHYDROXY-ISOPROPYL CHLORIDE 2,3-DIHYDROXYPROPYL CHLORIDE EPIBLOC GLYCERIN-a-MONOCHLOR-HYDRIN GLYCEROL CHLOROHYDRIN GLYCEROL-a-CHLOROHYDRIN GLYCEROL-a-MONOCHLOROHYDRIN (DOT) GLYCERYL-o-CHLOROHYDRIN MONOCHLORHYDRIN MONOCHLOROHYDRIN a-MONOCHLOROHYDRIN D U-5897... [Pg.311]

GLYCEROL ESTER of WOOD ROSIN see GGA875 GLYCEROL-LACTO PALMITATE see GGA900 GLYCEROL-a-MONOCHLOROHYDRIN (DOT) see CDT750... [Pg.1706]

O-Chlorohydrin. 3-Chtoro-1,2-propanediol 3-chloto-1,2-dihydroxypropare a-monOchlOrohydrin 3,3 -dihydroxyisopropyl chloride glycerol a-monochlorohydrin J-cbk>ropropylene glycol Epibloc. CjHjClOp mo] wt 110.54. C 32.59%, H 6.38%, Cl 32.08%, O 28.95%. CHjCI-CHOHCHjOH. Prepd from glycerol and HCI gas Conant, Quayle, Org. Syn. coll. vol. I, 294 (1941). [Pg.331]

Glycerol a-monochlorohydrin is a highly toxic, teratogenic, and carcinogenic compound. It is also an eye irritant. [Pg.290]

Glycerol a-monochlorohydrin is noncombustible flash point >100°C (212°F). The fire hazard is very low. It can decompose at high temperature, liberating toxic HCl gas. [Pg.290]

Chloropropylene glycol 1-Choropropane-2,3-diol p,P -Dihydroxyisopropyl chloride 2,3-Dihydroxypropyl chloride Glycerin-a-monochlorhydrin Glycerol chlorohydrin Glycerol-a-monochlorohydrin 1,2-Propanediol, 3-chloro-Classification Nonaromatic alcohol Empirical C3H7CIO2 Formula CICH2CHOHCH2 Properties Colorless or pale yel. liq. sol. in water, DMSO, 95% ethanol, acetone, ether, polar soivs. immisc. with oils m.w. 110.54 sp.gr. 1.326 (18/15 C) vapor pressure 3.75 mm Hg (25 C) m.p. -40 C b.p. 213 C (dec.) flash pt. 58 C ref. index 1.4809 (20 C)... [Pg.1911]

See other pages where A-Glycerol Monochlorohydrin is mentioned: [Pg.192]    [Pg.268]    [Pg.135]    [Pg.268]    [Pg.72]    [Pg.73]    [Pg.52]    [Pg.268]    [Pg.122]    [Pg.1306]    [Pg.1306]    [Pg.55]    [Pg.33]    [Pg.35]    [Pg.268]    [Pg.218]    [Pg.268]    [Pg.290]    [Pg.290]    [Pg.979]    [Pg.1021]    [Pg.1902]   
See also in sourсe #XX -- [ Pg.2 , Pg.6 , Pg.33 , Pg.48 ]

See also in sourсe #XX -- [ Pg.2 , Pg.6 , Pg.33 , Pg.48 ]

See also in sourсe #XX -- [ Pg.2 , Pg.6 , Pg.9 , Pg.33 , Pg.48 , Pg.92 ]



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