Ethers multifunctional

A large number of compositions containing poly(vinyl alkyl ethers), multifunctional acrylates and benzophenone were irradiated and examined for their pressure-sensitive adhesive properties. Among the components which were found to confer useful properties on the films were the methyl, ethyl, and isobutyl poly(vinyl alkyl ethers) and the multifunctional acrylate derivatives of neopentyl glycol, pentaerythritol, certain epoxidized oils and an aliphatic polyurethane (9). For our present discussion, however, we will focus on the behavior of the poly(vinyl ethyl ether) (PVEE/neopentyl glycol diacrylate (NPGDA) system. 

Polyoxylalkyl ether, multifunctional acrylates and optionally monoacrylates cured by UV or EB. 

Due to their multifunctional properties ether carboxylic acids have been described as very useful surfactants for metalworking fluids [66]. Especially in... 

For use in lubrication oils Ca salts of isostearyl ether carboxylic acids are described as multifunctional additives to achieve a good water tolerance of the oil and good antiwear characteristics [182]. 

Para-t-butylphenyl glycidyl ether BPGE had a similar viscosity and C/O ratio as those of NA and had the best properties of the photocurable epoxies that were surveyed, but this monomer dewetted from Si substrates immediately after spin coating and formed a puddle at the substrate center. Other monofunctional epoxies exhibited the same behavior. Mixtures of BPGE with multifunctional aromatic epoxies wetted Si substrates and could be used as planarizing layers. 

Trifluorostyrene-based monomers and fheir derivatives are known to exhibit dimerization preferentially over polymerization in confrasf to fhe hydrocarbon analogue slyrene. Eord, DesMarfeau, and Smifh, Smifh and Babb,i i and Smith et al. have advantageously used this behavior to produce 6 (where E can be a large number of differenf spacer groups buf also typically be sulfonamide-based) via cyclopolymerization of multifunctional monomers bearing at least two trifluorovinyl ether units. The polymers themselves have perfluorocyclobutane (PFCB) rings as part of the main chain. 

Concerning the synthesis of graft copolymers, Jedlinski et al. have prepared poly(MMA-g-(3BL) copolymers via anionic grafting of 3BL from a modified PMMA backbone [85]. PMMA chains were partially saponified by potassium hydroxide and complexed by 18C6 crown ether so as to act as multifunctional mac-... 

Calculations for a branched advancement synthesis are defined to permit development of well-characterized functionality in the product molecules. In this study, the difunctional epoxy resin monomer used is the diglycidyl ether of bisphenol A, Epon 828, and the multifunctional epoxy phenol novolac resin used is DEN 438. Let ... 

Multifunctional dithiolene ligands have been used to prepare binuclear as well as polymeric complexes. Some examples of this type of complex were already mentioned above (25 and 41) and involve the ligands benzenetetrathiol (51) or its alkyl ethers,78 the tetrathiosquaric acid (52), ethylenetetrathiol (53) and tetrathiooxalic acid (54) and its Se analog. The two-electron difference in oxidation state between (53) and (54) is much the same as that discussed for the parent dithiolene ligand. Crystallographic results (see Section 16.5.3.1) point out the equivalence of the latter two ligands. 

Mathias, L.J., Warren, R.M. and Huang, S., tert-Butyl a-(hydroxymethyl)acrylateand its ether dimer multifunctional monomers giving polymers with easily cleaved ester groups, Macromolecules, 1991, 24, 2036. 

Compound 114b can be regarded as multifunctional molecular cable with the central electron conducting phthalocyanine surrounded by the ion channels formed by the crown ethers and isolated by the alkyl chains. 

The photoinitiated addition of a multifunctional thiol to a difunctional monomer or oligomer gives a crosslinked polymer. The most widely used multifunctional thiol is pentaerythritol tetramercaptopropionate. Ene-monomers can be styrene, acrylates, vinyl ethers, allylic oligomers, etc. For example ... 

Fig. 2.5. Polycyclic polyamines and macrocyclic polyamines (crown ethers) as multifunctional oil additives...

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