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Electric-Sector Section

Ion beam passing collision through magnetic roll sector by-pass [Pg.158]

Hybrid Magnetic-Sector Time-of-Flight (Sector/TOF) Instruments [Pg.159]

Alternatively, ions of any one selected m/z value can be chosen by holding the magnetic field steady at the correct strength required to pass only the desired ions any other ions are lost to the walls of the instrument. The selected ions pass through the gas cell and are detected in the singlepoint ion collector. If there is a pressure of a neutral gas such as argon or helium in the gas cell, then ion-molecule collisions occur, with decomposition of some of the selected incident ions. This is the MS/MS mode. However, without the orthogonal TOF section, since there is no further separation by m/z value, the new ions produced in the gas cell would not be separated into individual m/z values before they reached the detector. Before the MS/MS mode can be used, the instrument must be operated in its hybrid state, as discussed below. [Pg.159]

This small section of the beam contains a representative selection of the ions in the original ion beam, but now the ions have all been started off down the TOF flight tube at the same instant (the [Pg.159]


In general terms, the main function of the magnetic/electric-sector section of the hybrid is to be able to resolve m/z values differing by only a few parts per million. Such accuracy allows highly accurate measurement of m/z values and therefore affords excellent elemental compositions of ions if these are molecular ions, the resulting compositions are in fact molecular formulae, which is the usual MS mode. Apart from accurate mass measurement, full mass spectra can also be obtained. The high-resolution separation of ions also allows ions having only small mass differences to be carefully selected for MS/MS studies. [Pg.157]

When the supply to the electricity and transportation sectors is jointly taken into consideration, one is led to conclude that the energy supply diversity is best served by allowing green electricity to maximally penetrate the electricity sector and simultaneously swing the deployment of NG and coal to instead serve the transportation sector. (Note that there may well be synergies between hydrogen fuel production and clean power production. These will be briefly touched upon in Section 15.6 for coal below.) The extent to which one thereby accommodates the objective of C02 emissions reduction depends on the mode of hydrogen production and distribution, and the extent to which it enables carbon capture and sequestration. To a discussion thereof we now turn. [Pg.340]

Meanwhile, proposals to introduce uniform allocation to all new entrants in the electricity sector (on a per kW or per kWh basis), without reference to whether or not they qualify as installations under the current EU ETS Directive, would seem to be inconsistent with the Directive in its present form. The combination of Article 3(e) and Annex I of the Directive require installations to perform certain activities if they are to be covered by the Directive, and in the energy sector this only relates to combustion installations with a rated thermal output exceeding 20 MW . Amendment of these provisions would require legislation (see Section 4.2.3). Such uniform allocation to new entrants could alleviate some of the difficulties of selectivity created by free allocation under the present regime, as it would not reserve the pass-through of opportunity costs to installations covered by the EU ETS. However, careful attention would need to be paid to the proportionality of such allocation in order to satisfy State aid rules (see Section 3.3.2.1). [Pg.125]

Besides a magnetic field, an electric sector field also influences the trajectory of the ions. An electric sector field analyzer as a section of the cylindrical condenser consists of two cylindrical... [Pg.81]

Thus, CO2 emissions cap-and-trading was already a well-known instrument, at least for electricity producers, and had also been discussed for a number of years outside the electricity sector. This fact is likely to have contributed to the smooth implementation of the emissions trading directive in Denmark (see the next section). [Pg.109]

Pultrusion can be used to fabricate a wide range of solid and hollow structures with constant cross-sections (Mazumdar, 2009). In the beginning, around 1976, pultrusion products were more for the recreational, sporting and electrical sectors. As new players entered the market, the quantity and innovation of the applications increased. During the period 1976-1981, the number of corrosion resistant products by pultrusion went up at such a rapid rate that by 1981, these were at second place behind the electrical market (Meyer, 1985). [Pg.383]

Hybrid instruments include the BEqQ spectrometer (magnetic sector, B electric sector, E RF-only quadrupole, q quadrupole mass analyzer, Q) and the BTOF (magnetic sector, B TOF analyzer, TOF) spectrometer. The QqTOF spectrometer is similar to the triple quadrupole (QqQ) instrument except that the final quadrupole mass analyzer is replaced with a TOF analyzer. In another variant, the Qq section can be replaced by a quadrupole ion trap to yield an ion-trap-TOF instrument. [Pg.296]

Through the use of sequential electric (electrostatic) and magnetic fields (sectors) and various correcting lenses, the ion beam leaving the ion source can be adjusted so that it arrives at the collector in focus and with a rectangular cross-section aligned with the collector slits. For the use of crossed electromagnetic fields. Chapter 25 ( Quadrupole Ion Optics ) should be consulted. [Pg.181]


See other pages where Electric-Sector Section is mentioned: [Pg.158]    [Pg.38]    [Pg.64]    [Pg.348]    [Pg.81]    [Pg.82]    [Pg.131]    [Pg.153]    [Pg.731]    [Pg.82]    [Pg.131]    [Pg.153]    [Pg.158]    [Pg.576]    [Pg.731]    [Pg.732]    [Pg.246]    [Pg.259]    [Pg.99]    [Pg.215]    [Pg.921]    [Pg.159]    [Pg.160]    [Pg.2357]    [Pg.67]    [Pg.168]    [Pg.499]    [Pg.3]    [Pg.246]    [Pg.248]    [Pg.84]    [Pg.437]    [Pg.49]    [Pg.67]    [Pg.221]    [Pg.37]    [Pg.17]    [Pg.437]    [Pg.2112]    [Pg.81]   


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