Effluent entrained flow

Many similar types of gasifier process effluents and coal tar have been studied from a variety of coal gasifiers. The composition of organic extracts of scrubber water particulate matter from a high pressure, entrained flow gasifier has been reported... 

After the SO converter has stabilized, the 6—7% SO gas stream can be further diluted with dry air, I, to provide the SO reaction gas at a prescribed concentration, ca 4 vol % for LAB sulfonation and ca 2.5% for alcohol ethoxylate sulfation. The molten sulfur is accurately measured and controlled by mass flow meters. The organic feedstock is also accurately controlled by mass flow meters and a variable speed-driven gear pump. The high velocity SO reaction gas and organic feedstock are introduced into the top of the sulfonation reactor,, in cocurrent downward flow where the reaction product and gas are separated in a cyclone separator, K, then pumped to a cooler, L, and circulated back into a quench cooling reservoir at the base of the reactor, unique to Chemithon concentric reactor systems. The gas stream from the cyclone separator, M, is sent to an electrostatic precipitator (ESP), N, which removes entrained acidic organics, and then sent to the packed tower, H, where SO2 and any SO traces are adsorbed in a dilute NaOH solution and finally vented, O. Even a 99% conversion of SO2 to SO contributes ca 500 ppm SO2 to the effluent gas. 

A salient feature of the fluidized bed reactor is that it operates at nearly constant temperature and is, therefore, easy to control. Also, there is no opportunity for hot spots (a condition where a small increase in the wall temperature causes the temperature in a certain region of the reactor to increase rapidly, resulting in uncontrollable reactions) to develop as in the case of the fixed bed reactor. However, the fluidized bed is not as flexible as the fixed bed in adding or removing heat. The loss of catalyst due to carryover with the gas stream from the reactor and regenerator may cause problems. In this case, particle attrition reduces their size to such an extent where they are no longer fluidized, but instead flow with the gas stream. If this occurs, cyclone separators placed in the effluent lines from the reactor and the regenerator can recover the fine particles. These cyclones remove the majority of the entrained equilibrium size catalyst particles and smaller fines. The catalyst fines are attrition products caused by... 

A variant on the fluidized bed is the riser reactor. In this reactor the flow velocity is so high that the solids are entrained in the flowing fluid and move with nearly the same velocity as the fluid. The solids are then separated trom the effluent gases at the top of the reactor by a cyclone, and the solids are returned to the reactor as shown in Figure 7-4. The FCC reactor is an example where the catalyst is carried into the regenerator, where carbon is burned off and the catalyst is heated before returning to the reactor. 

As organic and aqueous phases are macroscopically separated by the membrane, HFM offer several hydrodynamic advantages over other contactors, such as the absence of flooding and entrainment, or the reduction of feed consumption (160, 161). The flowsheets tested in HFM were similar to those developed for centrifugal contactor tests. Computer codes based on equilibrium (162) and kinetics data, diffusion coefficients (in both phases and in the membrane pores), and a hydrodynamic description of the module, were established to calculate transient and steady-state effluent concentrations. It was demonstrated that, by selecting appropriate flow rates (as mass transfer is mainly controlled by diffusion), very high DFs (DI A 11 = 20,000 and DFrm = 830) could be achieved. Am(III) and Cm(III) back-extraction efficiency was up to 99.87%. 

The discharge of solids from the bed is sometimes via a downcomer or vertical pipe immersed in the bed near the base and through to a conveyor of a similar type to that used at the solids inlet point. Another method is to allow the solids to flow over a weir at the top of the bed and pass down a pipe passing through the reactor wall. In certain cases, it is possible to entrain enough of the solids continually in the effluent gas stream and then to disentrain them again away from the bed. 

Caustic or water will often be found in the hydrocarbon leaving a settler. This problem is called carry-over. The entrained liquid will show up downstream. At the first place that the flow rate of the settler effluent slows to a few feet per minute, caustic or water will drop out. 

The effluent from the last reactor is cooled and sent to a separator, from which hydrogen-rich gas is removed and recycled to the reactors. The liquid product flows to a stabilizer column, where entrained gases are removed, before going to the gasoline blender or aromatics plant. 

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