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Direct products, some properties

Let us examine the direct product of a representation with itself. Let the two different sets of functions Fx,F2,...,Fm and Fl,F2,...,Fm each form a basis for the same representation TF of some point group. If we consider the symmetry properties of the m2 functions... [Pg.477]

While we have chosen to proceed here by reducing representations for the full group D3h, it would have been simpler to take advantage of the fact that D3h is the direct product of C3u and C where the plane in the latter is perpendicular to the principal axis of the former. The behaviour of any atomic basis functions with respect to the C3 subgroup is trivial to determine, and there are only two classes of non-trivial operations in C3v. In more general cases, it is often worthwhile to look for such simplifications. It is seldom useful, for instance, to employ the full character table for a group that contains the inversion, or a unique horizontal plane, since the symmetry with respect to these operations can be determined by inspection. With these observations and the transformation properties of spherical harmonics given in the Supplementary Notes, it should be possible to determine the symmetries spanned by sets of atomic basis functions for any molecular system. Finally, with access to the appropriate literature the labour can be eliminated entirely for some cases, since... [Pg.110]

The set ( bj) therefore closes. The other necessary group properties are readily proved and so G is a group. Direct product (DP) without further qualification implies the outer direct product. Notice that binary composition is defined for each group (e.g. A and B) individually, but that, in general, a multiplication rule between elements of different groups does not necessarily exist unless it is specifically stated to do so. However, if the elements of A and B obey the same multiplication rule (as would be true, for example, if they were both groups of symmetry operators) then the product at bj is defined. Suppose we try to take (a,-, bj) as a, bj. This imposes some additional restrictions on the DP, namely that... [Pg.15]

Appendix A. Composite indices. Some properties of direct (Kronecker) products. 284... [Pg.228]

APPENDIX A. COMPOSITE INDICES. SOME PROPERTIES OF DIRECT (KRONECKER) PRODUCTS... [Pg.284]

Efficient fire protection is also based on the consideration of product or scenario-specific hazards, which may lead to very specific materials development goals. Examples are the combination of impacts, such as vandalism and ignition source for seats in railway vehicles, or a preceding shock wave before the fire impact in navy applications. Some more product-specific phenomena of such kind are related directly to material properties, such as building up an increased risk for pool fires through burning thermoplastic plastics or dripping foams, and thus have become topics in the development of some flame-retarded materials.103... [Pg.405]

Continuous methods do not require a separation step prior to detection. For assays using this method, the substrate and product must differ in some property such that either one may be measured directly in the incubation solution. For example, the activity of an enzyme catalyzes the conversion of 4-nitrophenyl phosphate (4NP), a colorless compound, to 4-nitrophenol, which is yellow and has an absorption maximum at 510 nm. Since the substrate does not absorb in this region of the spectrum, the reaction can be carried out... [Pg.3]

As a result of the graphical analysis that is used in this experiment, you need not determine the absolute quantity of product formed as you did in part A, but only some property that is directly proportional to that absolute quantity. For an exothermic reaction the amount of heat liberated is directly proportional to the number of moles (and thus the quantity) of product formed. Moreover, if the reaction is carried out in an insulated container that eliminates heat flow from the solution to the surroundings, all of the heat will be used to cause a rise in temperature of the solution. A styrofoam cup approximates such conditions. Therefore, the temperature rise is directly proportional to the quantity of product formed, and the... [Pg.429]

Polyimide materials can be used as unfilled base polymers or have graphite, PTFE and molybdenum disulphide added to further enhance the low frictional properties and can be used to replace metal and ceramic parts. Material is available as moulded stock shapes, e.g. rod, rings and plate, which can be machined to the final dimensionally accurate product. Some grades can be processed by compression moulding while other grades can be processed to produce a finished product by direct forming. [Pg.245]

This article outlines some of the features and components of wood composites, describes some major wood composite products and properties, and describes some future directions in the wood composites industry. For additional information the reader is referred to some recent reviews (1-7). [Pg.9263]

The first step in a polymer analysis is to identify the specific type of polymer in a given sample. This may be complicated in a formulated sample by the presence of additives. Infrared spectroscopy will usually provide information on both the base polymer(s) and the additive(s) present. The second step, if possible, is to determine details of the chemical and physical characteristics, which define the quality and properties of the polymer. The chemical properties that can be determined are stereo specificity, any irregularities in the addition of monomer (such as 1,2- versus 1,4-addition and head-to-head versus head-to-tail addition), chain branching, any residual unsaturation, and the relative eoncentration of monomers in the case of copolymers. Other important characteristics include specific additives in a formulated product, and the physical properties, which include molecular weight, molecular-weight dispersion, crystallinity, and chain orientation. Some properties such as molecular weight and molecular-weight dispersion are not determined directly by infrared and Raman spectroscopy, except in some special cases. [Pg.208]

Induced cells contain a mechanism for concentrating inducers within the cells, and this mechanism appears to play a part in the induction process. The formation of enzyme depends on the continued presence of inducer. The rate of enzyme synthesis with adequate amoimts of inducer is proportional to the growth of the bacteria. When the inducer is removed (by suspending the centrifuged bacteria in fresh medium), enzyme synthesis stops abruptly. The enzyme already formed, however, is stable, and persists unchanged for many generations. Sulfur-labeled amino acids have been used to demonstrate that the induced enzyme is formed directly from free amino acids, and that proteins already in the bacteria do not contribute amino acids to the new enzyme. In the absence of the inducer, the adaptive enzyme retains its label. Some properties of inducers were found in a study of penicillinase production by BadUus cereusJ With this system it was shown that in a brief exposure a small amount of penicillin is specifically bound within the cells, and is not hydrolyzed, but stimulates the production of several equivalents of penicillinase. [Pg.393]


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See also in sourсe #XX -- [ Pg.284 ]




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