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Differences, successive

Without substantial artistic talent, depicting organic reaction mechanisms on surfaces is difficult. Over the years, a variety of methods have been invented and used with differing successes. Frequently used is an asterisk, an M, or sometimes the symbol of the metal catalyst to designate a surface catalytic... [Pg.19]

Important insights have been developed using approximate methods that were not highly precise quantitatively, and excellent high-level methods for solving the Schrodinger equation have been developed, but the methods still have used approximations. A Nobel Prize in 1998 went to John Pople and Walter Kohn for their different successful approaches to this problem. Earlier methods used many... [Pg.81]

The SEM has proved to be an invaluable instrument in its application to forensic evidence materials. Several widely different successful applications of the SEM-EDA instrumentation to actual criminal cases have been presented. [Pg.78]

That the three ordinary valencies of phosphorus in compounds of the type POX3 or PQR3 do not act in one plane, but are distributed in space symmetrically with respect to one another, was demonstrated by Caven,1 who replaced chlorine atoms in the trichloride one at a time taut in different succession by various groups such as RNH— or RO—, forming, for example, the anilino-, p-toluidino- and then the P toluidino-anilino chloride. [Pg.56]

The common combination of an RI with a UV detector can only be applied if at least one of the monomers of the complex polymer absorbs a suitable wavelength, and if the UV spectra of both components are sufficiently different. Successful applications of this setup are the analysis of mixtures of polystyrene (PS) with PMMA, polybutadiene (PB), poly(vinyl chloride) or poly(butyl methacrylate). The RI detector provides the total elution profile, whereas the UV detector... [Pg.12]

A strategically different successful synthesis of the related alkaloids isolycoriddine [cf. (34 C-la—C-4a double bond)] and and isonarciclasine (39) has been described (Scheme 4). Coupling of the diazotized anthranilate (35) with p-benzoquinone... [Pg.172]

In addition to the acetate aldol problem, stereoselective aldol additions of substituted enolates to yield 1,2-anti- or f/treo-selective adducts has remained as a persistent gap in asymmetric aldol methodology. A number of innovative solutions have been documented recently that provide ready access to such products. The different successful approaches to anri-selective propionate aldol adducts stem from the design of novel auxiliaries coupled to the study of metal and base effects on the reaction stereochemistry. The newest class of auxiliaries are derived from A-arylsulfonyl amides prepared from readily available optically active vicinal amino alcohols, such as cw-l-aminoindan-2-ol and norephedrine. [Pg.229]

Catalyst development is a process of evolution. Although cases differ, successful process implementation follows a series of logical steps. Each has welUdefined objectives that require talents from established branches of science and engineering. Commercialization may involve many passes through these steps, but every proven catalyst development has, in some fashion, progressed in this manner. In this chapter we examine elements of catalyst development and offer guidelines for success. [Pg.41]

Other tools have been designed to store correspondences and reuse them later [Madhavan et al. 2005], This is called a reuse strategy in matchers such as COMA++ [Aumueller et al. 2005] or Quickmig [Drumm et al. 2007]. Actually, these tools are able to derive new correspondences when different successive matching processes involve the same schema. This feature is specifically useful when one of the schemas has been modified. [Pg.298]

Oxidation with two different successive stirring speeds 1 1012 not detectable 4 10 0... [Pg.390]

Another concern with packed-bed reactors is reproducibility. There are two parts to reproducibility can multiple packed-bed reactors be made reproducibly and what is the stability of the reactor The first question concerning reproducibility can be answered as follows. The art of packing a column is at times difficult and each individual analyst will have different success. However, all packed-bed reactors can be calibrated in the FIA system. A variation in the performance level between reactors of less than 10% is acceptable. The second reproducibility question concerns the loss in reactivity due to reagent degradation or saturation of the reactive sites. In the ideal case the reactivity of the column should not change with respect to time, thereby producing a reproducible signal for the same concentration of analyte. This is a more difficult problem. Ideally, the analyst should find the reactor conditions that will minimize loss of activity. In practice, especially with enzymes, this condition will not be met. Frequent calibrations will be needed to insure the most accurate results. [Pg.519]

Apparent mean square radius of Brownian block copolymers The linear block copolymers are made of different successive subchains a — 1,2,. . . and so on. For the Brownian case, Benoit and Wippler16 obtained an expression of °ka2pp(x) in terms of rather simple contrast parameters. Their result can be recovered as follows. First, let us write (7.3.46) in the form... [Pg.283]

Because different classes of hydrocarbons partition differently, successive equilibrations remove alkanes, alkenes, and cycloalkanes, leaving only aromatic hydrocarbons in solution. Variations in the way different classes of hydrocarbons partition are shown graphically in Figure 2. The original solution was formulated in tap water to give approximately the same peak heights in the first equilibration for benzene, cyclohexane, and n-hexane. The results also show a small peak for cyclopentane, an impurity in the cyclohexane. [Pg.203]

The active intellectual powers of man in different times are not so much the cause of the different successes of their labours, as the peculiar nature of the means and artificial resources in their possessions. [Pg.405]

Figure 22.6. PL spectra of a non-size-selected sample after different successive treatments after passivation in air for two months (thick solid curve), after exposure to HF vapor for 40 min (grey thin and dotted curves), after reexposure to air for 1 h (black thin and dashed curves), and after continued exposure to air for 2 d (dash-dotted curve). The sketch in the upper part of the figure illustrates the effect of the various treatments on the core and oxide shell of the nanoparticles (schematic). Figure 22.6. PL spectra of a non-size-selected sample after different successive treatments after passivation in air for two months (thick solid curve), after exposure to HF vapor for 40 min (grey thin and dotted curves), after reexposure to air for 1 h (black thin and dashed curves), and after continued exposure to air for 2 d (dash-dotted curve). The sketch in the upper part of the figure illustrates the effect of the various treatments on the core and oxide shell of the nanoparticles (schematic).
Every firm values different success factors the only way to know the specific factors a particular company esteems is to speak with someone who works for this company. However, in this chapter, we identify some generic success factors from different companies that are key in a fast-paced, competitive business environment. The best interviewing strategy is to talk about the academic and work experiences that pertain to these generic success factors. As you tell the stories, the company success factors will stand out, showing the interviewer that you are a viable candidate for the job. [Pg.68]

As mentioned above, suitable orthogonal solvents had to be identified for the different, successive fabrication steps of functional devices based on nanostructured conjugated polymer films. [Pg.145]

This chapter focused on examples of supply chains and their underl dng supply chain architecture, using a Four C conceptual framework. The Four Cs refer to chain structure and ownership, capacity, coordination, and competitiveness. The supply chain audit permits an understanding of current choices and an approach to evaluate alternate choices for supply chain architecture. The goal of this chapter was to explain the Four C choices made in different successful supply chain contexts. [Pg.30]

The reaction of dextran with epichlorohydrin results in a cross-linked gelatinous product that is used as a molecular sieve for separation and purification of biochemically important macromolecules like proteins, polysaccharides or nucleic acids. Its commercial name Sephadex is derived from SEparation PHArmacia DEXtran and stands for many different successful products including further derivatized materials such as carboxy-methyl, diethylaminoethyl, diethyl(2-hydroxypropyl)-aminoethyl, and sulfo-propyl Sephadex . [Pg.290]


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See also in sourсe #XX -- [ Pg.423 , Pg.424 ]

See also in sourсe #XX -- [ Pg.427 , Pg.428 ]




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Successive Irreversible Reactions of Different Orders

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