Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Development inward

In frog nerve the steady-state current increased with [VT] but not its rate of development (Rando 1989). Likewise, in the more classical approach of suddenly applying alkaloid to the depolarized frog nerve, the time constant (several seconds) of the slowly developing inward current depended only weakly on [VT] (Ulbricht 1972a). These results are presented in more detail below (Sect. 2.4). [Pg.10]

We now consider the two possible directions of development (inward and outward) and for each of them, the rate-determining step can be a reaction step at the internal interface or the external interface or diffusion through the layer of the formed solid. Therefore, we have six possibilities. [Pg.330]

The kinetic curve in the case of the wire is still a line thus, it is necessary to examine how it varies according to time the areas of the internal and external interfaces. We have two possibilities for the direction of development inward development and outward development. In the case of inward development, the area of the internal interface decreases. To know the evolution of the area of the external interface, it is necessary to examine the expansion coefficient in pseudo-steady state mode (see section 7.4.4) ... [Pg.737]

More advanced insulations are also under development. These insulations, sometimes called superinsulations, have R that exceed 20 fthh-°F/Btu-m. This can be accomplished with encapsulated fine powders in an evacuated space. Superinsulations have been used commercially in the walls of refrigerators and freezers. The encapsulating film, which is usually plastic film, metallized film, or a combination, provides a barrier to the inward diffusion of air and water that would result in loss of the vacuum. The effective life of such insulations depends on the effectiveness of the encapsulating material. A number of powders, including silica, milled perlite, and calcium silicate powder, have been used as filler in evacuated superinsulations. In general, the smaller the particle size, the more effective and durable the insulation packet. Evacuated multilayer reflective insulations have been used in space applications in past years. [Pg.677]

In the case of alloys having one constituent considerably more reactive to oxygen than the others, conditions of temperature, pressure and atmosphere may be selected in which the reactive element is preferentially oxidised. Price and Thomas used this technique to develop films of the oxides of beryllium, aluminium, etc. on silver-base alloys, and thereby to confer improved tarnish resistance on these alloys. If conditions are so selected that the inward diffusion of oxygen is faster than outward diffusion of the reactive element, the oxide will be formed as small dispersed particles beneath the surface of the alloy. The phenomenon is known as internal oxidation and is of quite common occurrence, usually in association with a continuous surface layer of oxides of the major constituents of the alloy. [Pg.953]

The transmembrane potential derived from a concentration gradient is calculable by means of the Nemst equation. If K+ were the only permeable ion then the membrane potential would be given by Eq. 1. With an ion activity (concentration) gradient for K+ of 10 1 from one side to the other of the membrane at 20 °C, the membrane potential that develops on addition of Valinomycin approaches a limiting value of 58 mV87). This is what is calculated from Eq. 1 and indicates that cation over anion selectivity is essentially total. As the conformation of Valinomycin in nonpolar solvents in the absence of cation is similar to that of the cation complex 105), it is quite understandable that anions have no location for interaction. One could with the Valinomycin structure construct a conformation in which a polar core were formed with six peptide N—H moieties directed inward in place of the C—O moieties but... [Pg.211]

Topley and Hume [453], in a study of the dehydration of CaC03 6 H20, assumed the rapid initial formation of (on average) a single nucleus on the surface of each particle of reactant, represented as a sphere of radius a. In the absence of preferential surface development, the reaction interface penetrates the reactant at equal rates in all inward directions (kG = dr/df) and the volume of material reacted at time t is that volume of a sphere, having its centre at the site of surface nucleation and of radius kGt, which falls within the reactant. The fractional reaction, the zone of interpenetrating spheres, at time t is... [Pg.63]

The discussed effects, such as evaporation and adsorptive saturation, are prevented by placing a counter plate at a distance of one or a few millimeters from the chromatographic layer. The development with such a reduced vapor phase in the so-called sandwich chambers (S-chambers) can improve the separation. The glass-backed 20 X 20 cm plate forms one wall of the chamber with the adsorbent facing inward. A glass plate with spacers, called counter plates, is clamped to this plate and forms the other wall of the chamber (Figure 5.31, left [32]). [Pg.128]

The lag-phase measurement at 234 nm of the development of conjugated dienes on copper-stimulated LDL oxidation is used to define the oxidation resistance of different LDL samples (Esterbauer et al., 1992). During the lag phase, the antioxidants in LDL (vitamin E, carotenoids, ubiquinol-10) are consumed in a distinct sequence with a-tocopherol as the first followed by 7-tocopherol, thereafter the carotenoids cryptoxanthin, lycopene and finally /3-carotene. a-Tocopherol is the most prominent antioxidant of LDL (6.4 1.8 mol/mol LDL), whereas the concentration of the others 7-tocopherol, /3-carotene, lycopene, cryptoxanthin, zea-xanthin, lutein and phytofluene is only 1/10 to 1/300 of a-tocopherol. Since the tocopherols reside in the outer layer of the LDL molecule, protecting the monolayer of phospholipids and the carotenoids are in the inner core protecting the cholesterylesters, and the progression of oxidation is likely to occur from the aqueous interface inwards, it seems reasonable to assign to a-tocopherol the rank of the front-line antioxidant. In vivo, the LDL will also interact with the plasma water-soluble antioxidants in the circulation, not in the artery wall, as mentioned above. [Pg.47]

The plicae circulares, or circular folds, form internal rings around the circumference of the small intestine that are found along the length of the small intestine. They are formed from inward foldings of the mucosal and submucosal layers of the intestinal wall. The plicae circulares are particularly well developed in the duodenum and jejunum and increase the absorptive surface area of the mucosa about threefold. Each plica is covered with millions of smaller projections of mucosa referred to as villi. Two types of epithelial cells cover the villi ... [Pg.299]

Due to the lack of increase in stabilizing re-re interactions at the reaction stage where the destabilizing four-electron repulsive interactions increase steadily, the inward bending of alkyne moieites in unstrained enediynes leads to continuously developing reactant destabilization without any compensation from the increased C1-C6 bonding. Only in the 9-membered enediyne the decrease in the C1-C6 distance results in an immediate increase in the extent of C1-C6 cr-bond formation. [Pg.14]

As society advances, its values depend on what is produced and those sources of production. However, as the means to acquire products becomes easier, values turn inward to the general societal welfare and our environment. Uncontrolled fire can devastate our assets and production sources, and this relates to the societal costs of fire prevention and loss restoration. The effects of fire on people and the environment become social issues that depend on the political ideology and economics that prevail in the state. Thus, attention to fire prevention and control depend on its perceived damage potential and our social values in the state. While these issues have faced all cultures, perhaps the twentieth century ultimately provided the basis for addressing fire with proper science in the midst of significant social and technological advances, especially among the developed countries. [Pg.2]

I m extremely sensitive to stress and other people s emotional energy. It s like I have radar. I think that s part of my problem. I was always sensitive as a child, but I didn t realize how sensitive. Right now it s a detriment because I turn it inward and can t turn it off. But it s a gift that I m trying to develop in a positive direction. [Pg.85]


See other pages where Development inward is mentioned: [Pg.41]    [Pg.29]    [Pg.41]    [Pg.29]    [Pg.395]    [Pg.96]    [Pg.100]    [Pg.91]    [Pg.116]    [Pg.512]    [Pg.141]    [Pg.270]    [Pg.35]    [Pg.36]    [Pg.993]    [Pg.1054]    [Pg.122]    [Pg.131]    [Pg.250]    [Pg.233]    [Pg.30]    [Pg.25]    [Pg.26]    [Pg.195]    [Pg.58]    [Pg.347]    [Pg.33]    [Pg.196]    [Pg.373]    [Pg.198]    [Pg.120]    [Pg.20]    [Pg.151]    [Pg.357]    [Pg.408]    [Pg.309]    [Pg.438]    [Pg.320]    [Pg.198]    [Pg.172]   
See also in sourсe #XX -- [ Pg.312 , Pg.315 , Pg.340 , Pg.350 , Pg.354 , Pg.355 , Pg.358 , Pg.360 , Pg.362 , Pg.371 , Pg.373 , Pg.396 , Pg.464 , Pg.484 , Pg.485 , Pg.517 , Pg.555 , Pg.592 ]




SEARCH



Inward

© 2024 chempedia.info