Designed synthesis framework

This review highlights recent studies of synthetic, covalently linked multicomponent molecular devices which mimic aspects of photosynthetic electron transfer. After an introduction to the topic, some of the salient features of natural bacterial photosynthetic reaction centers are described. Elementary electron transfer theory is briefly discussed in order to provide a framework for the discussion which follows. Early work with covalently linked photosynthetic models is then mentioned, with references to recent reviews. The bulk of the discussion concerns current progress with various triad (three-part) molecules. Finally, some even more complex multicomponent molecules are examined. The discussion will endeavor to point out aspects of photoinitiated electron transfer which are unique to the multicomponent species, and some of the considerations important to the design, synthesis and photochemical study of such molecules. 

Ma, B., Zhang, D., Gao, S., Jin, T., Yan, C., and Xu, G. (2000) From cubane to supercubane the design synthesis and structure of a three-dimensional open framework based on a LneOe cluster. Angewandte Chemie International Edition, 39, 3644-3646. 

In the previous chapter, we briefly outlined our 2.5-D layout synthesis framework. In this chapter, the 2.5-D layout tools are applied on floorplan level designs. We will introduce our floorplanning algorithms along with the design case studies in this chapter. 

A. Winokur, and K. A. Gary, J. Med. Chem., 38, 2866 (1995). Peptide Mimetics of Thyrotropin-Releasing Hormone Based on a Cyclohexane Framework Design, Synthesis, and Cognition-Enhancing Properties. 

El-Kaderi HM, Hunt JR, Medoza-Cortes JL, Cote AP, Taylor RE, O Keeffe M, YagM OM (2007) Designed synthesis of 3D covalent organic frameworks. Science 316 268-272... 

Knapp and Doherty present the economic optimum design of an acetone-methanol separation using water as the extractive solvent. The design used in this chapter is based on their work. Kossack et al. presented a systematic synthesis framework for extractive distillation systems and the acetone-methanol system was considered. 

We use the environment shown in Figure 6 as a representative synthesis framework to show the utility of BIF. The figure is organized into three columns the synthesis tasks on the left, the user interface on the right, and different design views of the intermediate representation in the middle the state table, the unit list, the connectivity list, and the symbol list. 

A synthesis framework. The core of the system is the synthesis framework [Lan91], which acts both as a central data-structure and as a unified design representation at all levels. Methods for design transformation are an integral part of this framework. Although tuned to real-time signal... 

The outline of this paper is as follows. In Section 2, the architectural styles which are currently supported by the CATHEDRAL environment are described. Section 3 focuses on the synthesis framework, which is the core of the synthesis system. The different synthesis tasks and their composition in a synthesis script are discussed in Section 4. Finally, in Section 5, our approach is evaluated on a realistic design from the domain of digital audio. 

The core of the CATHEDRAL environment is the synthesis framework [Lan91]. In view of the flexible composition of specialised synthesis scripts and the implementation of many specific synthesis tools, the key issues of this framework are design representation and design transformation ... 

Barbera, G., Vaca, A., Teixidor, F. et al. 2008. Designed synthesis of new ort/jo-carhorane derivatives From mono- to polysubstituted frameworks. Inorg. Chem., 47, 7309-16. 

Against the trend of using more complicated and expensive organic SDAs to produce new zeolite framework types, the CDM approach was initially proposed as a cheaper alternative for the designed synthesis of zeolites. The concept of CDM approach was first developed... 

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