Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Danger deposition

Carbon disulphide should never be used if any alternative solvent is available, as it has a dangerously low flash-point, and its vapours form exceedingly explosive mixtures with air. Ether as a solvent for recrystallisation is much safer than carbon disulphide, but again should be avoided whenever possible, partly on account of the danger of fires, and partly because the filtered solution tends to creep up the walls of the containing vessel and there deposit solid matter by complete evaporation instead of preferential crystallisation. [Pg.15]

In addition to the formation of scale or corrosion of metal within boilers, auxiliary equipment is also susceptible to similar damage. Attempts to prevent scale formation within a boiler can lead to makeup line deposits if the treatment chemicals are improperly ehosen. Thus, the addition of normal phosphates to an unsoftened feed water ean eause a dangerous eondition by elogging the makeup line with preeipitated calcium phosphate. Deposits in the form of calcium or magnesium stearate deposits, otherwise known as "bathtub ring" can be readily seen, and are caused by the eombination of ealcium or magnesium with negative ions of soap stearates. [Pg.377]

Deposit formation, due either to crud (suspended matter-mostly metallic oxides) transported into the boiler or to the products of corrosion in situ, is undesirable as, in many parts of the system, quite apart from the risk of overheating which they present, deposits are able to participate in a mechanism for concentrating solutes to unacceptably high corrosive levels, and are particularly dangerous in high-pressure plant (see Section 4.5). [Pg.844]

Another complication had to be matched when the zinc electrode was made reversible in a battery with unstirred electrolyte or an electrolyte gel, dendritic growth of the electrolytically deposited metal takes place. The formation of dendrites cannot be fully suppressed by the use of current collectors with large surface areas (grids, wire fabrics). However, by using improved separators combined in multi layer arrangements, the danger of short-circuiting is reduced. [Pg.203]

The public loved leaded fuel for its pep, not its efficiency. Interest in fuel conservation faded when new oil deposits were discovered. Reassured about lead s dangers, Americans reveled in unprecedented personal mobility and used tetraethyl lead to expand their reliance on automobiles. Surprisingly, Midgley did not think his discovery would increase passenger car ownership. Nevertheless, tetraethyl lead and the engine improvements it permitted helped form America s car-dependent society. Fuel-efficient cars and public transportation were no longer top priorities. [Pg.95]

The Li-Ion system was developed to eliminate problems of lithium metal deposition. On charge, lithium metal electrodes deposit moss-like or dendrite-like metallic lithium on the surface of the metal anode. Once such metallic lithium is deposited, the battery is vulnerable to internal shorting, which may cause dangerous thermal run away. The use of carbonaceous material as the anode active material can completely prevent such dangerous phenomenon. Carbon materials can intercalate lithium into their structure (up to LiCe). The intercalation reaction is very reversible and the intercalated carbons have a potential about 50mV from the lithium metal potential. As a result, no lithium metal is found in the Li-Ion cell. The electrochemical reactions at the surface insert the lithium atoms formed at the electrode surface directly into the carbon anode matrix (Li insertion). There is no lithium metal, only lithium ions in the cell (this is the reason why Li-Ion batteries are named). Therefore, carbonaceous material is the key material for Li-Ion batteries. Carbonaceous anode materials are the key to their ever-increasing capacity. No other proposed anode material has proven to perform as well. The carbon materials have demonstrated lower initial irreversible capacities, higher cycle-ability and faster mobility of Li in the solid phase. [Pg.179]

Cadmium occurs naturally as sulfide co-deposited with zinc, copper, and lead sulfides. It is produced as a by-product in above-mentioned metal processing. Similar to lead and mercury, this heavy metal has no known biological functions in living organisms, and accordingly its accumulation in food and water leads to undesirable consequences to biota. Cadmium toxicology is related to dangerous influence to CNS and excretion systems, firstly, on kidney. [Pg.223]

Silver solutions used in photography can become explosive under a variety of conditions. Ammoniacal silver nitrate solutions, on storage, heating or evaporation eventually deposit silver nitride ( fulminating silver ). Silver nitrate and ethanol may give silver fulminate, and in contact with azides or hydrazine, silver azide. These are all dangerously sensitive explosives and detonators [1], Addition of ammonia solution to silver containing solutions does not directly produce explosive precipitates, but these are formed at pH values above 12.9, produced by addition of alkali, or by dissolution of silver oxide in ammonia [2]. [Pg.385]

This mixture of ammoniacal silver oxide and sodium hydroxide solution is potentially dangerous, because if kept for a few horns it deposits an explosive precipitate. This danger was described by Tollens in 1882 but is not generally known now. Prepare the reagent just before use, in the tube to be used for the test, and discard... [Pg.407]

Another danger is the waste mercury that has been deposited by industries and agricultural chemicals in the lakes and oceans of the world. Several decades ago most of the nations of the world approved an international ban on dumping mercury into our waterways and oceans. The problem is that smaller ocean plants and animals consume mercury. Larger flsh consume... [Pg.170]

But how is it that these objects simultaneously accumulate and shed matter How can a star form by losing mass It is thought that the solution to this paradox lies in the wind. Material deposited on the star from the encircling disk dangerously increases the speed of rotation. A centrifugal barrier then... [Pg.124]


See other pages where Danger deposition is mentioned: [Pg.268]    [Pg.106]    [Pg.253]    [Pg.130]    [Pg.422]    [Pg.221]    [Pg.178]    [Pg.1308]    [Pg.1364]    [Pg.372]    [Pg.537]    [Pg.1032]    [Pg.272]    [Pg.337]    [Pg.361]    [Pg.795]    [Pg.282]    [Pg.229]    [Pg.735]    [Pg.128]    [Pg.67]    [Pg.128]    [Pg.42]    [Pg.246]    [Pg.231]    [Pg.759]    [Pg.45]    [Pg.453]    [Pg.133]    [Pg.300]    [Pg.328]    [Pg.87]    [Pg.65]    [Pg.164]    [Pg.261]    [Pg.52]    [Pg.44]    [Pg.98]   
See also in sourсe #XX -- [ Pg.188 , Pg.190 ]




SEARCH



Dangerous

Dangers

© 2024 chempedia.info