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Cross section model

In principle, the reaction cross section not only depends on the relative translational energy, but also on individual reactant and product quantum states. Its sole dependence on E in the simplified effective expression (equation (A3.4.82)) already implies unspecified averages over reactant states and sums over product states. For practical purposes it is therefore appropriate to consider simplified models for tire energy dependence of the effective reaction cross section. They often fonn the basis for the interpretation of the temperature dependence of thennal cross sections. Figure A3.4.5 illustrates several cross section models. [Pg.776]

The hyperbolic cross section model can be generalized fiirther by introducing a fiinction/(A ) (AE = E - Eq) to describe the reaction cross section above a tln-eshold ... [Pg.778]

Figure 16. Appearance curve of Na+ from CID of Na+N-methylacetamide. The calculated curve (solid line), fitted using experimental points from 1.4-4.0 eV, corresponds to n = 1.25 and E0 = 1.69 eV (38.9 kcal/mol). The cross section model in equation 50 is used. From Klassen, J. S. Anderson, S. G. Blades, A. T. Kebarle, P. J. Phys. Chem. 1996, 100,14218, with permission. Figure 16. Appearance curve of Na+ from CID of Na+N-methylacetamide. The calculated curve (solid line), fitted using experimental points from 1.4-4.0 eV, corresponds to n = 1.25 and E0 = 1.69 eV (38.9 kcal/mol). The cross section model in equation 50 is used. From Klassen, J. S. Anderson, S. G. Blades, A. T. Kebarle, P. J. Phys. Chem. 1996, 100,14218, with permission.
FIGURE 7-2 Cross-sectional model of part of a conducting airway in the respiratory tract, showing a gas phase and a liquid-tissue phase subdivided into mucus and serous-fluid, tissues, and blood layers. Derived in part from McTilton et al. ... [Pg.302]

Fig. 4. A model for the possible relationship between crystalline and disordered regions within a collagen fibril. The cross-sectional model of a 50-nm diameter fibril shows regions of crystallinity interfaced by grain boundaries. The individual crystalline unit cells are shown and the gap region is represented by a darker color. The axial projection of a single microfibrillar unit is also shown. Based on die structures developed by Hulmes et al. (1995) and adapted with permission from Hulmes et al (2002). Fig. 4. A model for the possible relationship between crystalline and disordered regions within a collagen fibril. The cross-sectional model of a 50-nm diameter fibril shows regions of crystallinity interfaced by grain boundaries. The individual crystalline unit cells are shown and the gap region is represented by a darker color. The axial projection of a single microfibrillar unit is also shown. Based on die structures developed by Hulmes et al. (1995) and adapted with permission from Hulmes et al (2002).
Y. Edura, N. Morishima, Cold and thermal neutron scattering in liquid water cross-section model and dynamics of water molecules, Nucl. Instrum. Methods, Sect. A 534, 531-543 (2004)... [Pg.200]

Comparison of the molecular length of CAB (ca. 38 A) and the characteristic lengths calculated from SAS data (vide ante) indicate that molecular pairs are involved in the columns of the solid state while, in gels, association of swollen columns might be involved. Micrographs of freeze-fractured and etched CAB gels (Fig. 17) show a 3-D network of fibrous bundles. The dimensions of the rectangular cross sections of the nontwisted fibers in dodecane, 209 x 104 A. and the twisted ones in 1-octanol, 263 x 82 A [481, correspond approximately to the cross-sectional areas determined by SANS in which a circular cross section model was employed. [Pg.328]

Figure 13. A composite of three drawings Model of tonofilament assembly (13A) based on the ribosome model (13B) (Ref. 79), tne distribution of radioactive amino acid uptake shown by silver grains (13C) (Ref. 74), and the cross section model (13D) Ref. (70). Second and fifth layers (dotted in 13D) are omitted from 13A. The triangles in 13D locate three possible layers of tripeptide chains. Figure 13. A composite of three drawings Model of tonofilament assembly (13A) based on the ribosome model (13B) (Ref. 79), tne distribution of radioactive amino acid uptake shown by silver grains (13C) (Ref. 74), and the cross section model (13D) Ref. (70). Second and fifth layers (dotted in 13D) are omitted from 13A. The triangles in 13D locate three possible layers of tripeptide chains.
Figure 3.3 3D and cross-sectional models of SDS micelles with a statistical conformation of hydrocarbon chains of 60 molecules. (SDS = sodium dodecyl sulfate). [Pg.25]

Hastie, John W., and National Institute of Standards and Technology (U.S.). A Predictive Ionization Cross Section Model for Inorganic Molecules. NISTIR, 6768. Gaithersburg, Md. U.S. Dept, of Commerce, Technology Administration, National Institute of Standards and Technology, 2001. [Pg.297]

Our first task is to evaluate the validity of the conventional concept about the mobility control requirement using a simulation approach. This model uses the UTCHEM-9.0 simulator (2000). The dimensions of the two-dimensional XZ cross-section model are 300 ft x 1 ft x 10 ft. One injection well and one production well are at the two extreme ends in the X direction, and they are fully penetrated. The injection velocity is 1 ft/day the initial water saturation and oil saturation are 0.5. The displacing fluid is a polymer solution. The purpose of using the polymer solutuion in the model is to change the viscosity of the displacing fluid. Therefore, polymer adsorption, shear dilution effect, and so on are not included in the model. To simplify the problem, it is assumed that the oil and water densities are the same that the capillary pressure is not included that the relative permeabilities of water and oil are straight lines with the connate water saturation and residual oil saturation equal to 0 and that the water and oil viscosity is 1 mPa s. Under these assumptions and conditions, we can know the fluid mobilities at any saturation. The model uses an isotropic permeability of 10 mD. [Pg.82]

In chapter three, the theoretical background to all the potential macro-factors that could contribute to road accidents was presented. The relationship between each factor and the probability that road accidents may occur on the national level was conducted. One special criterion to select suitable indicators was used. This has enabled me to determine the key macro-performance indicators in road safety. It has become clear that the chosen indicators must be easy, available, measurable, and comparable worldwide. Moreover, these indicators must be able to indicate/monitor the country s progress over time in road safety and allow international comparisons. The obtained set of indicators was listed and summarised in Table 3.2. The next step was to understand and explain the main published macroscopic studies and models that are used in describing and comparing the road safety development internationally. I have divided the reviewed models into cross-sectional models (time-independent models) and (time-dependent models). A starting point in this direction was to investigate Smeed s equation, particularly in the relation between motorisation and fatality rates. Several models for... [Pg.85]

Figure 5. A cross-sectional model of the honeycomb-structured films containing amphiphilic co-polymer (green part) located in the pores (top) and a CLSM image of the honeycomb-structured film of PS and amphiphilic co-polymer 2 (bottom, yellow bar indicates 5.0 pm). The green fluorescence in the CLSM image indicates that the amphiphilic co-polymer 2 was located on inner side of the hole and the pillar part of honeycomb-structured films. Figure 5. A cross-sectional model of the honeycomb-structured films containing amphiphilic co-polymer (green part) located in the pores (top) and a CLSM image of the honeycomb-structured film of PS and amphiphilic co-polymer 2 (bottom, yellow bar indicates 5.0 pm). The green fluorescence in the CLSM image indicates that the amphiphilic co-polymer 2 was located on inner side of the hole and the pillar part of honeycomb-structured films.
With the forensic actinide measurements as input, and the assumption of a simple cross-section model, the isotopic composition of the starting material could be computationally reconstructed. The results were = 90%, = 9%, and =1%. The material had heen... [Pg.2887]

Fig. 25.6 Fibre technique, uniaxial constitutive models (Maekawa et al. 2003), and cross section modeling of RC column iile... Fig. 25.6 Fibre technique, uniaxial constitutive models (Maekawa et al. 2003), and cross section modeling of RC column iile...
Figure 10 (a) Cross-section model of an individual SWNT in a cylindrical sodium dodecyl sulfate (SDS) micelle. Structures of... [Pg.3525]

P. V. Barr, J. K. Brimacombe, and A. P. Watkinson. "A heat-transfer model for the rotary kiln Part II. Development of the cross-section model," Met. Trans. B, 20, 403-419, 1989. [Pg.203]

A quasi-three-dimensional bed model is envisioned as one that comprises both an axial model (one-dimensional) and a cross sectional model (two-dimensional). The former is used to independently determine the one-dimensional axial temperature profiles for the freeboard gas and the bulk bed. It is implicitly assumed that the details of the energy redistribution that occurs within the bed do not significantly influence heat transfer between the bed and the freeboard. As part of the procedure for calculating these axial temperature profiles, the... [Pg.216]

Figure 8.10 Mesh generation for cross sectional modeling. Figure 8.10 Mesh generation for cross sectional modeling.
Fig. 5 (a) Cross-sectional model of nanoporous carbide-derived carbon-based actuator, (b) Simplified notation of electrical double-layer formation inside porous CDC during charging, (c) Bending displacement of actuator under applied voltage, (d, e) SEM images of cross section of actuators with polymer-supported and gold-foil-modified CDC electrodes (Reproduced from Torop et al. 2012)... [Pg.449]

The 2D cross sectional model of the thoracic aorta was developed using Comsol 3.5a. FEM models were developed for normal vessels and vessels with 50% and 90% plaque deposition. [Pg.411]

FIG. 6 — TWO-DIMENSIONAL, CROSS-SECTIONAL MODEL FOR WATERFLOOD AND POLYMER FLOOD. [Pg.256]

Over time, increasingly sophisticated modifications to the Langevin capture cross-section model have... [Pg.955]

Seismic Anaiysis of Steei-Concrete Composite Buildings Numerical Modeling, Fig. 16 Cross-sectional model under negative bending... [Pg.2661]


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