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Critical thermal stress, parameter

The parameter G provides a dimensionless measure of the critical thermal stress, divided by the amount of released heat during the reaction. Two solutions exist vdien G Gc <°0.64. In the limit G -> 0, one solution has a low velocity v D d T) / Q t) and another one has a fast velocity... [Pg.162]

Considering a ciuve integral of the thermal-stress-induced elastie energy density, the critical particle radii related to crack formations in ideal-brittle partiele and matrix, funetions describing crack shapes in a plane perpendicular to a direction of the erack formation in the particle and the matrix, and consequently particle and matrix crack dimensions are derived along with the condition concerning a direction of the partiele and matrix eraek formation. The former parameters for v = 0 are derived using a spherical cell model for the spherical cell radius, Rc >. [Pg.256]

These authors envisaged the critical step in the yield process as being the nucleation under stress of small disc-sheared regions (analogous to dislocation loops) that form with the aid of thermal fluctuations. The model explains quantitatively the variation of the yield stress with temperature, strain rate and hydrostatic pressure, using only two parameters, the shear modulus of the material and the Burgers vector of the shared region which is a constant related to the molecular dimensions of the polymer. [Pg.56]

When a material obeys linear elastic fracture mechanics, its tendency to undergo crack initiation or propagation as a result of mechanical stress can be assessed in terms of fracture toughness parameters, such as (critical stress intensity factor) or Gj, (strain energy release rate). Analogous parameters can be used with thermally induced cracking. [Pg.119]

The various functional groups on the CNT surface permit coupling with the polymer matrix. A strong interface between the coupled CNT/polymer creates an efficient stress transfer. As mentioned previously, stress transfer is a critical parameter for controlling the mechanical properties of a composite. However, the covalent treatment of CNT reduces the electrical and thermal properties of CNT and these reductions affect the properties of nanocomposites [42-57]. [Pg.32]

Fig. 7 illustrates Chapman s treatment of the mechanics of this composite system. The system is treated as a set of zones consisting of fibril and matrix elements. Originally, this was introduced as a way of simplifying the analysis, but, the later identification of the links through IF protein tails makes it a more realistic model than continuous coupling of fibrils and matrix. Up to 2% extension, most of the tension is taken by the fibrils, but, when the critical stress is reached, the IF in one zone, which will be selected due to statistical variability or random thermal vibration, opens from a to P form. Stress, which reduces to the equilibrium value in the IF, is transferred to the associated matrix. Between 2% and 30% extension, zones continue to open. Above 30%, all zones have opened and further extension increases the stress on the matrix. In recovery, there is no critical phenomenon, so that all zones contract uniformly until the initial extension curve is joined. The predicted stress-strain curve is shown by the thick line marked with aiTows in Fig. 6b. With an appropriate. set of input parameters, for most of which there is independent support, the predicted response agrees well with the experimental curves in Fig. 6a. The main difference is that there is a finite slope in the yield region, but this is explained by variability along the fibre. The C/H model can be extended to cover other aspects of the tensile properties of wool, such as the influence of humidity, time dependence and setting. Fig. 7 illustrates Chapman s treatment of the mechanics of this composite system. The system is treated as a set of zones consisting of fibril and matrix elements. Originally, this was introduced as a way of simplifying the analysis, but, the later identification of the links through IF protein tails makes it a more realistic model than continuous coupling of fibrils and matrix. Up to 2% extension, most of the tension is taken by the fibrils, but, when the critical stress is reached, the IF in one zone, which will be selected due to statistical variability or random thermal vibration, opens from a to P form. Stress, which reduces to the equilibrium value in the IF, is transferred to the associated matrix. Between 2% and 30% extension, zones continue to open. Above 30%, all zones have opened and further extension increases the stress on the matrix. In recovery, there is no critical phenomenon, so that all zones contract uniformly until the initial extension curve is joined. The predicted stress-strain curve is shown by the thick line marked with aiTows in Fig. 6b. With an appropriate. set of input parameters, for most of which there is independent support, the predicted response agrees well with the experimental curves in Fig. 6a. The main difference is that there is a finite slope in the yield region, but this is explained by variability along the fibre. The C/H model can be extended to cover other aspects of the tensile properties of wool, such as the influence of humidity, time dependence and setting.
The critical process parameters are the ratio of the rates of decomposition of the organometalhc component and the polymerization of the corresponding monomer, and the sedimentational resistance of metal dispersions formed in the monomer. Apparently, this also holds true for sohdifying systems. For example, colloidal Pb is incorporated into thermally generated epoxy-thiocol resin at the moment of its formation by thermolysis. In this case, internal stresses existing in solidified systems should be considered. ... [Pg.134]

Hot-wire anemometers have traditionally been applied in the fields of experimental fluid mechanics and aerospace engineering. Despite the possibilities to measure real-time physical parameters such as temperature, velocity, flow rates, and shear stress, the spatial resolution is limited to the device dimension. The advent of MicroElectroMe-chanical system (MEMS) and nano-scale thermal sensors has revolutionized the spatial and temporal resolution critical to gain entry into micro-fluidics, micro-circulation, biomedical sciences, and cardiovascular medicine. These micro/nano devices are fabricated with the Semiconductor-... [Pg.1274]


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