Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Control theory constraints

It turns out that there is another branch of mathematics, closely related to tire calculus of variations, although historically the two fields grew up somewhat separately, known as optimal control theory (OCT). Although the boundary between these two fields is somewhat blurred, in practice one may view optimal control theory as the application of the calculus of variations to problems with differential equation constraints. OCT is used in chemical, electrical, and aeronautical engineering where the differential equation constraints may be chemical kinetic equations, electrical circuit equations, the Navier-Stokes equations for air flow, or Newton s equations. In our case, the differential equation constraint is the TDSE in the presence of the control, which is the electric field interacting with the dipole (pemianent or transition dipole moment) of the molecule [53, 54, 55 and 56]. From the point of view of control theory, this application presents many new features relative to conventional applications perhaps most interesting mathematically is the admission of a complex state variable and a complex control conceptually, the application of control teclmiques to steer the microscopic equations of motion is both a novel and potentially very important new direction. [Pg.268]

In early work in the optimal control theory design of laser helds to achieve desired transformations, the optimal control equations were solved directly, without constraints other than those imposed implicitly by the inclusion of a penalty term on the laser huence [see Eq. (1)]. This inevitably led to laser helds that suddenly increased from very small to large values near the start of the laser pulse. However, physically realistic laser helds should tum-on and -off smoothly. Therefore, during the optimization the held is not allowed to vary freely but is rather expressed in the form [60] ... [Pg.48]

Problem formulations [ 1-3 ] for designing lead-generation library under different constraints belong to a class of combinatorial resource allocation problems, which have been widely studied. They arise in many different applications such as minimum distortion problems in data compression (11), facility location problems (12), optimal quadrature rules and discretization of partial differential equations (13), locational optimization problems in control theory (9), pattern recognition (14), and neural networks... [Pg.75]

The formalism used to calculate the pulse shape that maximizes J is optimal control theory. This formalism can be considered to be an extension of the calculus of variations to the case where the constraints include differential equations. In general, the constraints expressed in the form of differential equations express the restriction that the amplitude must always satisfy the Schrodinger equation. In addition, there can be a variety of other constraints, such as a restriction on the total energy in the pulse or on the shape of the pulse. These constraints are accounted for by the method of Lagrange multipliers, which modify the objective functional (4.6) and thereby permit the calculation of the unconstrained maximum of the modified objective functional. When the only constraints are satisfaction of the Schrodinger equation and limitation of the pulse energy, the modified objective functional can be written in the form... [Pg.231]

We consider, first, whether it is in principle possible to control the quantum dynamics of a many-body system. The goal of such a study is the establishment of an existence theorem, for which purpose it is necessary to distinguish between complete controllability and optimal control of a system. A system is completely controllable if an arbitrary initial state can be transformed, without loss to other states, into an arbitrary final state at some time T. A system is strongly completely controllable if an arbitrary initial state can be transformed, without loss to other states, into an arbitrary final state at a specified time T. Optimal control theory designs a field, subject to specified constraints, that guides the evolution of an initial state of the system to be as close as possible to the desired final state at time T. [Pg.247]

Optimal control theory A method for determining the optimum laser field used to maximize a desired product of a chemical reaction. The optimum field is derived by maximizing the objective function, which is the sum of the expectation value of the target operator at a given time and the cost penalty function for the laser field, under the constraint that quantum states of the reactants satisfy the Schrodinger equation. [Pg.145]

The situation is quite different when inequality constraints are included in the MPC on-line optimization problem. In the sequel, we will refer to inequality constrained MPC simply as constrained MPC. For constrained MPC, no closed-form (explicit) solution can be written. Because different inequahty constraints may be active at each time, a constrained MPC controller is not linear, making the entire closed loop nonlinear. To analyze and design constrained MPC systems requires an approach that is not based on linear control theory. We will present the basic ideas in Section III. We will then present some examples that show the interesting behavior that MPC may demonstrate, and we will subsequently explain how MPC theory can conceptually simplify and practically improve MPC. [Pg.145]

In control theory, open systems are viewed as interrelated components that are kept in a state of dynamic equilibrium by feedback loops of information and control. The plant s overall performance has to be controlled in order to produce the desired product while satisfying cost, safety, and general quality constraints. [Pg.65]

The third concept used in STAMP, along with safety constraints and hierarchical safety control structures, is process models. Process models are an important part of control theory. The four conditions required to control a process are described in chapter 3. The first is a goal, which in STAMP is the safety constraints that must be enforced by each controller in the hierarchical safety control structure. The action condition is implemented in the (downward) control channels and the observability condition is embodied in the (upward) feedback or measuring channels. The final condition is the model condition Any controller—human or automated-needs a model of the process being controlled to control it effectively (figure 4.6). [Pg.87]

The present theory of calorimetry is a result of the authors own work. Its essential feature is the simultaneous application of the relationship and notions specific to heat transfer theory and control theory. The present theory has been used to develop a classification of calorimeters, to discuss selected methods of determining thermal effects and thermokinetics, and to describe the processes proceeding in calorimeters of various types. Calorimeters have been assumed to constitute linear systems. This assumption allowed the principle of superposition to be used to analyze several constraints acting simultaneously in and on the calorimeter. [Pg.177]

A robust mathematical tool is needed to perform an optimisation. We have found that optimal control theory provides such a tool. The system is constrained by the requirement to balance energy, momentum and mass. These constraints must be specified for each particular case. In optimal control terminology there are two classes of variables. The first class are the state variables, for instance the temperature, T z,t), the pressure, p z,t), and the concentrations, Cj z,t), in a tubular reactor. The second class are the control variables, which are determined from the outside. An example is the temperature, T (z,t), on the outside along the tubular reactor. Optimal control theory in this case provides a general method to obtain T (z,t) such that the total entropy production is minimal, given certain constraints. [Pg.488]

Tailoring Laser Pulses with Spectral and Fluence Constraints Using Optimal Control Theory. [Pg.164]

Can one systematically incorporate the constraints on experimental realization of a control scheme and a feedback mechanism into the theory ... [Pg.219]


See other pages where Control theory constraints is mentioned: [Pg.44]    [Pg.82]    [Pg.56]    [Pg.23]    [Pg.591]    [Pg.235]    [Pg.249]    [Pg.209]    [Pg.550]    [Pg.135]    [Pg.187]    [Pg.193]    [Pg.224]    [Pg.102]    [Pg.347]    [Pg.80]    [Pg.540]    [Pg.285]    [Pg.220]    [Pg.576]    [Pg.58]    [Pg.75]    [Pg.77]    [Pg.609]    [Pg.86]    [Pg.63]    [Pg.418]    [Pg.47]    [Pg.297]    [Pg.201]    [Pg.213]    [Pg.33]    [Pg.484]    [Pg.258]   
See also in sourсe #XX -- [ Pg.256 , Pg.266 , Pg.277 , Pg.282 ]




SEARCH



Control theory

Optimal control theory constraint

© 2024 chempedia.info