Continuous monitoring of performance

Provide Continuous Monitoring of Performance is the final safety culture feature in the comprehensive CCPS book Guidelines for Risk Based Process Safety (KBPS) [9], The focus is leading and lagging indicators of a process safety culture (see Fig. 16.7). 

Sensors on the tree allow the control module to transmit data such as tubing head pressure, tubing head temperature, annulus pressure and production choke setting. Data from the downhole gauge is also received by the control module. With current subsea systems more and more data is being recorded and transmitted to the host facility. This allows operations staff to continuously monitor the performance of the subsea system. 

Automated analyzers may be used for continuous monitoring of ambient poUutants and EPA has developed continuous procedures (23) as alternatives to the referenced methods. Eor source sampling, EPA has specified extractive sampling trains and analytical methods for poUutants such as SO2 and SO [7446-11-9] sulfuric acid [7664-93-9] mists, NO, mercury [7439-97-6], beryUium [7440-41-7], vinyl chloride, and VOCs (volatile organic compounds). Some EPA New Source Performance Standards requite continuous monitors on specified sources. 

There are important economic consequences of a process being out of control for example, product waste and customer dissatisfaction. Hence, statistical process control does provide a way to continuously monitor process performance and improve product quahty. A typic process may go out of control due to several reasons, including... 

The safe operation of a chemical process requires continuous monitoring of the operation to stabilize the system, prevent deviations, and optimize system performance. This can be accomplished through the use of instrumentation/control systems, and through human intervention. The human element is discussed in Chapter 6. Proper operation requires a close interaction between the operators and the instrumentation/control system. To a large extent, batch operations have simple control systems and are frequently operated in the manual mode. The instrumentation system is the main source of information about the state of the process. Some of the typical functions of the instrumentation/control system are... 

Because of their role as the link between producing and market areas, interstate natural gas pipelines play a crucial role in balancing supply and demand. To do so, the interstate pipelines continually monitor pipeline performance. These companies rely heavily on computers to gather, analyze and retain information on the performance of their pipelines, and to control the flow of gas in remote sections of the line. 

Continuous monitoring of the third-stage separator performance. If catalyst is showing up downstream, consider using more than the standard 3% flue gas underflow. The blowcase needs more attention than it usually gets. 

Electrodeposition of metals can be performed under different electrochemical modes. In the work mentioned in Ref. [18], it was performed in potentiostatic mode. The potential value for formation of platinum nanoparticles is —25 mV vs. SCE the deposition is performed from 2.5 mM solution of H2[PtCl6] in 50 mM KCl. The size of nanoparticles formed depends on the reduction charge. Continuous monitoring of the charge in potentiostatic mode is provided by different potentiostats, for example, by Autolab-PG-stat (EcoChemie, The Netherlands). Conditions for deposition of other metals should be selected according to their electrochemical properties. 

One of the attractive features of SFE with CO2 as the extracting fluid is the ability to directly couple the extraction method with subsequent analytical methods (both chromatographic and spectroscopic). Various modes of on-line analyses have been reported, and include continuous monitoring of the total SFE effluent by MS [6,7], SFE-GC [8-11], SFE-HPLC [12,13], SFE-SFC [14,15] and SFE-TLC [16]. However, interfacing of SFE with other techniques is not without problems. The required purity of the CO2 for extraction depends entirely on the analytical technique used. In the off-line mode SFE takes place as a separate and isolated process to chromatography extracted solutes are trapped or collected, often in a suitable solvent for later injection on to chromatographic instrumentation. Off-line SFE is inherently simpler to perform, since only the extraction parameters need to be understood, and several analyses can be performed on a single extract. Off-line SFE still dominates over on-line determinations of additives-an... 

An RCRA permit for a hazardous waste combustion unit sets operating requirements that specify allowable ranges for, and requires continuous monitoring of, certain critical parameters that will ensure compliance with the performance standards. Operation within these parameters ensures that combustion is performed in the most protective manner and the performance standards are achieved. These parameters, or operating requirements, may include... 

Monitoring and feeding back the data are important in maintaining the performance of water systems. By applying an automatic continuous monitoring system combined with the method of trend analysis, processes can be maintained in a much more stable state. For example, this can be achieved by applying automatic continuous monitoring of TOC and conductivity of the water system. 

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