Conservation principles for mass

The conservation principle for mass and energy in the absence of external fields and internal sources or sinks is expressed as... 

Application of thermodynamic conservation principles for mass, energy, and momentum and,... 

Three essential elements provide the foundation for continuum mechanics. First, we must have a kinematical framework for mathematically describing the motion of material particles — not molecules, but differential portions of a physical entity, or body. Second, conservation principles for mass, charge, linear and angular momenrnm, and energy serve as fundamental, universal postulates. Various forms of the transport theorem enable translation of conservation principles between recognizable forms for closed and open... 

First principle mathematical models These models solve the basic conservation equations for mass and momentum in their form as... 

The principles and basic equations of continuous models have already been introduced in Section 6.2.2. These are based on the well known conservation laws for mass and energy. The diffusion inside the pores is usually described in these models by the Fickian laws or by the theory of multicomponent diffusion (Stefan-Maxwell). However, these approaches basically apply to the mass transport inside the macropores, where the necessary assumption of a continuous fluid phase essentially holds. In contrast, in the microporous case, where the pore size is close to the range of molecular dimensions, only a few molecules will be present within the cross-section of a pore, a fact which poses some doubt on whether the assumption of a continuous phase will be valid. 

First principle mathematical models These models solve the basic conservation equations for mass and momentum in their form as partial differential equations (PDEs) along with some method of turbulence closure and appropriate initial and boundary conditions. Such models have become more common with the steady increase in computing power and sophistication of numerical algorithms. However, there are many potential problems that must be addressed. In the verification process, the PDEs being solved must adequately represent the physics of the dispersion process especially for processes such as ground-to-cloud heat transfer, phase changes for condensed phases, and chemical reactions. Also, turbulence closure methods (and associated boundary and initial conditions) must be appropriate for the dis-... 

The starting point is a conservation principle for the mass of surfactant within a material surface element that we can denote as Sm(t). In the absence of any sources or sinks, either because of chemical reactions or a flux to or from the surrounding bulk-phase fluids, and, neglecting diffusion temporarily, we may write a surface mass balance in analogy with... 

The basic structure of a conservation or balance equation is independent of the specific quantity that is considered. Therefore, in this subsection, the general form of the conservation principle for a physical quantity is derived from an Eulerian point of view. This principle is then applied to specific conservation quantities such as mass, species, momentum, energy, etc. 

The conservation principle for total mass which can neither be created nor destroyed is (Bennett and Meyers, 1982) ... 

Process simulation Process simulation software is used for the planning and layout of processes in entire systems or plant units. The range of competence of these software systems typically comprises the calculation of procedural basic operations, mainly in chemical and thermal process engineering according to the principle of the conservation equations for mass, matter, momentum and enthalpy in consideration of the principles of thermodynamics. A typical example is the calculation of the matter and heat transmission in rectification columns. Here, the acquisition of correspondingly reliable matter data is often difficult. Therefore, the simulation results are generally accompanied by the respective experimental studies. 

Deterministic air quaUty models describe in a fundamental manner the individual processes that affect the evolution of pollutant concentrations. These models are based on solving the atmospheric diffusion —reaction equation, which is in essence the conservation-of-mass principle for each pollutant species... 

Microscopic Balance Equations Partial differential balance equations express the conservation principles at a point in space. Equations for mass, momentum, totaf energy, and mechanical energy may be found in Whitaker (ibid.). Bird, Stewart, and Lightfoot (Transport Phenomena, Wiley, New York, 1960), and Slattery (Momentum, Heat and Mass Transfer in Continua, 2d ed., Krieger, Huntington, N.Y., 1981), for example. These references also present the equations in other useful coordinate systems besides the cartesian system. The coordinate systems are fixed in inertial reference frames. The two most used equations, for mass and momentum, are presented here. 

The humidity and contaminant transport calculation is based on the previously calculated airflows, applying again the principle of mass conservation for the species under consideration. For each time step, the concentrations are calculated on the basis of the airflows, the source and sink strengths in the zones, and the concentration values at the previous time step. In contrast to the airflow calculation, which is a steady-state calculation at each time step, the contaminant transport calculation is dynamic. Therefore, the accuracy of the concentration results depends on the selected time-step interval. 

Compartmental soil modeling is a new concept and can apply to both modules. For the solute fate module, for example, it consists of the application of the law of pollutant mass conservation to a representative user specified soil element. The mass conservation principle is applied over a specific time step, either to the entire soil matrix or to the subelements of the matrix such as the soil-solids, the soil-moisture and the soil-air. These phases can be assumed in equilibrium at all times thus once the concentration in one phase is known, the concentration in the other phases can be calculated. Single or multiple soil compartments can be considered whereas phases and subcompartments can be interrelated (Figure 2) with transport, transformation and interactive equations. 

As discussed in Chapter 1, the basic principles that apply to the analysis and solution of flow problems include the conservation of mass, energy, and momentum in addition to appropriate transport relations for these conserved quantities. For flow problems, these conservation laws are applied to a system, which is defined as any clearly specified region or volume of fluid with either macroscopic or microscopic dimensions (this is also sometimes referred to as a control volume ), as illustrated in Fig. 5-1. The general conservation law is... 

Up to now we have presented this example without any regard for consistency, i.e. satisfying thermodynamic and conservation principles. This fuel mass flux must exactly equal the mass flux evaporated, which must depend on q and h(g. Furthermore, the concentration at the surface where fuel vapor and liquid coexist must satisfy thermodynamic equilibrium of the saturated state. This latter fact is consistent with the overall approximation that local thermodynamic equilibrium applies during this evaporation process. 

We next have to consider the continuity equation, which students first encounter seriously in introductory chemistry and physics as the principle of mass conservation. For any fluid we require that the total mass flow into some element of volume minus the flow out is equal to the accumulation of mass, and we either write these as integral balances (stoichiometry) or as differential balances on a differential element of volume. 

Deriving the mass-continuity equation begins with a mass-conservation principle and the Reynolds transport theorem. Unlike the channel with chemically inert walls, when surface chemistry is included the mass-conservation law for the system may have a source term,... 

Which of Daltons five postulates accounts for Lavoisier s mass-conservation principle ... 

If the processes just described are assumed to characterize the transfer of mass and energy in a fixed-bed adsorber, the conservation principles may be applied to them to describe the temperature and concentration as a function of time and position. Presenting the equations for a fixed-bed geometry has the advantage of including also equations, as special cases, for transient adsorption in single particles or groups of particles in batch systems. 

Physical Models versus Empirical Models In developing a dynamic process model, there are two distinct approaches that can be taken. The first involves models based on first principles, called physical or first principles models, and the second involves empirical models. The conservation laws of mass, energy, and momentum form the basis for developing physical models. The resulting models typically involve sets of differential and algebraic equations that must be solved simultaneously. Empirical models, by contrast, involve postulating the form of a dynamic model, usually as a transfer function, which is discussed below. This transfer function contains a number of parameters that need to be estimated from data. For the development of both physical and empirical models, the most expensive step normally involves verification of their accuracy in predicting plant behavior. 

The engineering science of transport phenomena as formulated by Bird, Stewart, and Lightfoot (1) deals with the transfer of momentum, energy, and mass, and provides the tools for solving problems involving fluid flow, heat transfer, and diffusion. It is founded on the great principles of conservation of mass, momentum (Newton s second law), and energy (the first law of thermodynamics).1 These conservation principles can be expressed in mathematical equations in either macroscopic form or microscopic form. 

In order to determine the distributions of pressure, velocity, and temperature the principles of conservation of mass, conservation of momentum (Newton s Law) and conservation of energy (first law of Thermodynamics) are applied. These conservation principles represent empirical models of the behavior of the physical world. They do not, of course, always apply, e.g., there can be a conversion of mass into energy in some circumstances, but they are adequate for the analysis of the vast majority of engineering problems. These conservation principles lead to the so-called Continuity, Navier-Stokes and Energy equations respectively. These equations involve, beside the basic variables mentioned above, certain fluid properties, e.g., density, p viscosity, p conductivity, k and specific heat, cp. Therefore, to obtain the solution to the equations, the relations between these properties and the pressure and temperature have to be known. (Non-Newtonian fluids in which p depends on the velocity field are not considered here.) As discussed in the previous chapter, there are, however, many practical problems in which the variation of these properties across the flow field can be ignored, i.e., in which the fluid properties can be assumed to be constant in obtaining fire solution. Such solutions are termed constant... 

As contaminant transport occurs over times much greater than the times over which groundwater flow fluctuates, steady flow is frequently assumed. For steady groundwater flow in three dimensions, the following vector equation, developed based on mass conservation principles, is typically used to model advective/ dispersive transport of a dissolved reactive contaminant (after [53]) ... 

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